Synthesis and applications of graphene based nanomaterials
A composition of graphene-based nanomaterials and a method of preparing the composition are provided. A carbon-based precursor is dissolved in water to form a precursor suspension. The precursor suspension is placed onto a substrate, thereby forming a precursor assembly. The precursor assembly is annealed, thereby forming the graphene-based nanomaterials. The graphene-based nanomaterials are crystallographically ordered at least in part and configured to form a plurality of diffraction rings when probed by an incident electron beam. In one aspect, the graphene-based nanomaterials are semiconducting. In one aspect, a method of engineering an energy bandgap of graphene monoxide generally includes providing at least one atomic layer of graphene monoxide having a first energy bandgap, and applying a substantially planar strain is applied to the graphene monoxide, thereby tuning the first energy band gap to a second energy bandgap.
1. A composition of graphene-based nanomaterials, the composition comprising: at least one atomic layer of graphene monoxide, wherein the grapheme monoxide is crystallographically ordered at least in part and configured to form a plurality of diffraction rings when probed by an incident electron beam; and
a nanocrystalline oxide or carbide, wherein the nanocrystalline oxide is a transition metal oxide and wherein the nanocrystalline carbide is a transition metal carbide.
2. The composition of claim 1 , further comprising at least one atomic layer of graphene.
3. The composition of claim 1 , wherein the nanocrystalline oxide is molybdenum oxide.
4. A nanostructure comprising graphene-based nanomaterials according to claim 1 , wherein the nanostructure is configured to support at least one of a metal or metal oxide atom, cluster, and nanocrystal.
5. A gas sensor comprising:
(a) one or more electrodes formed on a substrate and adapted to be operatively connected to a meter to measure an electrical characteristic between the electrodes;
(b) one or more nanostructures in contact with the one or more electrodes; and
(c) one or more nanoparticles deposited on the nanostructures, wherein the nanoparticles include the graphene-based nanomaterials according to claim 1 .
6. An electrochemical cell comprising:
an anode including the graphene-based nanomaterials according to claim 1 ;
a cathode;
a separator; and
an electrolyte.
7. An electronic device comprising:
one or more semiconducting elements including the graphene-based nanomaterials according to claim 1 ; and
one or more junctions positioned between the graphene-based nanomaterials, the junctions including conducting and insulating materials, wherein the graphene-based nanomaterials are associated with a tunable energy bandgap.