Precise control of molecular weight and chain shape control in carbon dioxide/epoxide alternating copolymerization and preparation of low molecular weight poly(alkylene carbonate) thereby
This invention relates to a method of preparing poly(alkylene carbonate) that has a molecular weight and polymer chain structure precisely controlled by adding a chain transfer agent composed of a compound having an alcohol or carboxylic acid functional group upon alternating copolymerization of an epoxide compound and carbon dioxide using a catalyst composed of a trivalent metal complex compound synthesized from a quaternary ammonium salt-containing Salen type ligand, and to a polymer compound prepared thereby. According to this invention, the polymer compound having a star-shaped chain as well as the polymer having a linear chain can be prepared. The low-molecular-weight poly(alkylene carbonate) has an —OH terminal group and can be used alone as a coating agent, etc., and also in mixtures with an isocyanate compound and thus can be easily utilized to prepare polyurethane.
1. A poly(alkylene carbonate) represented by Formula 10 below:
J[L-{CR 81 R 82 —CR 83 R 84 —OC(O)O} d —CR 81 R 82 —CR 83 R 84 —OH] c [Formula 10]
wherein L is —CO 2 —; c is 2; J is para-phenyl meta-phenylene, ortho-phenylene or 2,6-naphthalenediyl; R 81 R 84 are each independently hydrogen; (C 1 -C 10 )alkyl substituted or unsubstituted with halogen or (C 1 -C 20 ) alkoxy; or (C 6 -C 12 )aryl substituted or unsubstituted with halogen or (C 1 -C 20 )alkoxy, R 81 to R 84 being able to be linked with each other to form a ring; and
a value obtained by multiplying d by c is a natural number of 1000 or less.
2. A poly(alkylene carbonate) represented by Formula 10 below:
J[L-{CR 81 R 82 —CR 83 R 84 —OC(O)O} d —CR 81 R 82 —CR 83 R 84 —OH] c [Formula 10]
wherein L is —O—; c is 2; J is —CH 2 CH 2 N(R)CH 2 CH 2 —(R is C1-C20 hydrocarbyl) or —[CH 2 CH(R)O] n CH 2 CH(R)—(n is an integer from 0 to 10; R is hydrogen or methyl): R 81 to R 84 are each independently hydrogen; (C 1 -C l0 )alkyl substituted or unsubstituted with halogen or (C 1 -C 20 )alkoxy; or (C 6 -C 12 )aryl substituted or unsubstituted with halogen or (C 1 -C 20 )alkoxy, R 81 to R 84 being able to be linked with each other to form a ring; and
a value obtained by multiplying d by c is a natural number of 1000 or less.
3. A poly(alkylene carbonate) represented by Formula 10 below:
J[L-{CR 81 R 82 —CR 83 R 84 —OC(O)O} d —CR 81 R 82 —CR 83 R 84 —OH] c [Formula 10]
wherein L is —CO 2 —; c is 3; and J is 1,2,3-propanetriyl, 1,2,3-benzenetriyl 1,2,4-benzenetriyl or 1,3,5-benzenetriyl; R 81 to R 84 are each independently hydrogen (C 1 -C 10 )alkyl substituted or unsubstituted with halogen or (C 1 -C 20 )alkoxy; or (C 6 -C 12 )aryl substituted or unsubstituted with halogen or (C 1 -C 20 )alkoxy, R 81 to R 84 being able to be linked with each other to form a ring; and
a value obtained by multiplying d by c is a natural number of 1000 or less.
4. A poly(alkylene carbonate) represented by Formula 10 below:
J[L-{CR 81 R 82 —CR 83 R 84 —OC(O)O} d —CR 81 R 82 —CR 83 R 84 —OH] c [Formula 10]
wherein L is —CO 2 —; c is 4: J is 1,2,3,4-butanetetrayl or 1,2,4,5-benzenetetray; R 81 to R 84 are each independently hydrogen; (C 1 -C 10 )alkyl substituted or unsubstituted with halogen or (C 1 -C 20 )alkoxy; or (C 6 -C 12 )aryl substituted or unsubstituted with halogen or (C 1 -C 20 ) alkoxy, R 81 to R 84 being able to be linked with each other to form a ring; and
a value obtained by multiplying d by c is a natural number of 1000 or less.