Cosmetic or pharmaceutical composition comprising modified polyorganosiloxanes
Cosmetic or pharmaceutical compositions comprising one or more substituted aminopolyorganosiloxanes (S H ) with substituted amino groups which are bonded to silicon atoms of the polysiloxane basic structure via alkylene bridges or mono- or oligo(alkylenamino)alkylene bridges, where the amino groups present in the aminopolyorganosiloxanes (S H ) are substituted at least partially by a radical of the formula (ε) T-CH 2 —CHOH—CH 2 — (ε), in which T is the radical of a surfactant monoalcohol polyglycol ether with emulsifier character, the amino groups present in the aminopolyorganosiloxanes (S H ) are substituted in the average ratio of at least 1.5 radicals of the formula (ε) per Si-bonded aminoalkyl group or amino-mono- or -oligo-(alkylenamino)-alkyl group, and present amino groups are, if appropriate, acylated and/or alkylated and/or benzylated and/or protonated at least partially to give amide groups, are described.
1. A method for protecting and preserving color in colored keratin fibers, wherein the method comprises the step of contacting the colored keratin fibers with a treatment composition comprising at least one substituted aminopolyorganosiloxanes (S H ) with substituted amino groups which are bonded to silicon atoms of a polysiloxane basic structure via alkylene bridges or mono- or oligo(alkylenamino)alkylene bridges, where the amino groups present in the aminopolyorganosiloxanes (S H ) are substituted at least partially by a radical of the formula (ε)
T-CH 2 —CHOH—CH 2 — (ε),
in which T is the radical of a surfactant monoalcohol polyglycol ether with emulsifier character, wherein the monoalcohol polyglycol ether is of the following formula (II)
R 1 —(O—X) q —OH (II)
in which R 1 is an alkylaromatic or aliphatic hydrocarbon radical having 9 to 24 carbon atoms, X is a C2-4 alkylene and q is 4 to 50, where at least 80% of the q alkylenoxy groups are ethylenoxy units, the amino groups present in the aminopolyorganosiloxanes (S H ) being substituted in the average ratio of at least 1.5 radicals of the formula (ε) per Si-bonded aminoalkyl group or amino-mono- or -oligo-(alkylenamino)-alkyl group and optionally present amino groups can be acylated, alkylated, benzylated and/or protonated at least partially.
2. The method of claim 1 , wherein the treatment composition comprises from 0.01 to 10% by weight of the at least one substituted aminopolyorganosiloxanes (S H ), based on the treatment composition.
3. The method of claim 1 , wherein the colored keratin fibers are colored human hair.
4. The method of claim 1 , wherein the substituted aminopolyorganosiloxane (S H ) has an average molecular weight in the range from 15 000 to 2 000 000.
5. The method of claim 1 , wherein the aminopolyorganosiloxane (S H ) has an amine number in the range from 0.05 to 3.
6. The method of claim 1 , wherein the substituted aminopolyorgano-siloxane (S H ) has been obtained by reaction of at least one aminopolyorganosiloxane (s) which comprises primary and/or secondary amino groups which are bonded to silicon atoms of the polysiloxane basic structure via alkylene bridges or mono- or oligo(alkylenamino)alkylene bridges, with at least one alcohol polyglycol ether monoglycidyl ether (H) and, optionally, a subsequent step selected from the group consisting of acylation, alkylation, benzylation, protonation, and mixtures thereof.
7. The method as claimed in claim 1 , wherein the substituted aminopolyorganosiloxane (S H ) has a nitrogen content in the range from 0.03 to 4.2% by weight.
8. The method as claimed in claim 1 , wherein all of the amino groups of the substituted aminopolyorganosiloxane (S H ) are 40 to 100% substituted by radicals of the formula (ε).