IP Library Granted Patent US 9,012,849
Granted Patent B2
US 9,012,849 · App. 13/937,713 · Granted Apr 21, 2015

Direct and quantitative broadband absorptance spectroscopy with multilayer cantilever probes

Inventors: Wei-Chun Hsu (Cambridge, MA); Jonathan Kien-Kwok Tong (Cambridge, MA); Bolin Liao (Cambridge, MA); Brian Burg (Cambridge, MA); Gang Chen (Carlisle, MA)
Assignee: Massachusetts Institute of Technology
G01J3/45G01T1/36G01N21/1702G01N21/171G01N21/3563
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Quick Facts
Patent No.
US 9,012,849
App. No.
13/937,713
Granted
Apr 21, 2015
Kind
B2
Abstract

A system for measuring the absorption spectrum of a sample is provided that includes a broadband light source that produces broadband light defined within a range of an absorptance spectrum. An interferometer modulates the intensity of the broadband light source for a range of modulation frequencies. A bi-layer cantilever probe arm is thermally connected to a sample arm having at most two layers of materials. The broadband light modulated by the interferometer is directed towards the sample and absorbed by the sample and converted into heat, which causes a temperature rise and bending of the bi-layer cantilever probe arm. A detector mechanism measures and records the deflection of the probe arm so as to obtain the absorptance spectrum of the sample.

Claims (32)

1. A system for measuring the absorption spectrum of a sample comprising:

a broadband light source that produces broadband light defined within a range of an absorptance spectrum;

an interferometer that modulates the intensity of the broadband light source for a range of modulation frequencies;

a bi-layer cantilever probe arm that is thermally connected to a sample arm having a plurality layers of materials, the broadband light modulated by the interferometer is directed towards the sample and absorbed by the sample and converted into heat, which causes a temperature rise and bending of the bi-layer cantilever probe arm; and

a detector mechanism that measures and records the deflection of the probe arm so as to obtain the absorptance spectrum of the sample.

2. The system of claim 1 , wherein the probe arm comprises different layers of materials having different thermal expansion coefficients.

3. The system of claim 1 , wherein the detector mechanism measures the deflection of the probe arm by reflecting a laser beam off the probe arm onto a position sensitive detector, and the output voltage is recorded in a data acquisition system.

4. The system of claim 1 , wherein the probe arm is used in background spectrum calibration to correct for variations in the spectral intensity of the light source and atmospheric absorption.

5. The system of claim 1 , wherein the probe arm is used to characterize a beam intensity profile and power incident on the sample.

6. The system of claim 1 , wherein the probe arm is used for power calibration relating an oscillating displacement amplitude on a position sensitive detector to the absorbed power of the sample.

7. The system of claim 1 , wherein the broadband light source comprises plurality of the wavelengths in the x-ray, ultraviolet, visible, infrared, microwaves, or radio waves spectrum.

8. The system of claim 1 , wherein the interferometer comprises a Michelson interferometer, Mach-Zender interferometer, Sagnac interferometer, Bath interferometer, or Fabry-Perot interferometer.

9. The system of claim 1 , wherein the sample arm comprises a plurality of the materials.

10. The system of claim 9 , wherein the materials comprises one or several of the following Si, SiNx, or SiOx.

11. The system of claim 1 , wherein the probe arm comprises at least one dielectric layer and one metal layer.

12. The system of claim 1 , wherein the probe arm comprises at least one semiconducting layer and one metal layer.

13. A method of measuring the absorption spectrum of a sample comprising:

producing broadband light defined within a range of an absorptance spectrum using a broadband light source;

modulating the intensity of the broadband light source for a range of modulation frequencies using an interferometer;

providing a bi-layer cantilever probe arm that is thermally connected to a sample arm having a plurality of layers of materials, the broadband light modulated by the interferometer is directed towards the sample and absorbed by the sample and converted into heat, which causes a temperature rise and bending of the bi-layer cantilever probe arm; and

measuring and recording the deflection of the probe arm so as to obtain the absorptance spectrum of the sample.

14. The method of claim 13 , wherein the probe arm comprises different layers of materials having different thermal expansion coefficients.

15. The method of claim 13 , wherein the detector mechanism measures the deflection of the probe arm by reflecting a laser beam off the probe arm onto a position sensitive detector, and the output voltage is recorded in a data acquisition method.

16. The method of claim 13 , wherein the probe arm is used in background spectrum calibration to correct for variations in the spectral intensity of the light source and atmospheric absorption.

17. The method of claim 13 , wherein the probe arm is used to characterize a beam intensity profile and power incident on the sample.

18. The method of claim 13 , wherein the probe arm is used for power calibration relating an oscillating displacement amplitude on a position sensitive detector to the absorbed power of the sample.

19. The method of claim 13 , wherein the broadband light source comprises plurality of the wavelengths in the x-ray, ultraviolet, visible, infrared, microwaves, or radio waves spectrum.

20. The method of claim 13 , wherein the interferometer comprises a Michelson interferometer, Mach-Zender interferometer, Sagnac interferometer, Bath interferometer, or Fabry-Perot interferometer.

21. The method of claim 13 , wherein the sample arm comprises a plurality of the materials.

22. The method of claim 21 , wherein the materials comprises one or several of the following Si, SiNx, or SiOx.

23. The method of claim 13 , wherein the probe arm comprises at least one dielectric layer and one metal layer.

24. The method of claim 13 , wherein the probe arm comprises at least one semiconducting layer and one metal layer.

Assignments (2)
CONFIRMATORY LICENSE Recorded Aug 11, 2015
From: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 036354/0571 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2013
From: HSU, WEI-CHUN; TONG, JONATHAN KIEN-KWOK; LIAO, BOLIN; BURG, BRIAN; CHEN, GANG
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 031102/0344 →
Continuity (3)
Provisional Application 61669715 · Jul 10, 2012
Provisional Application 61681357 · Aug 9, 2012
Related Publication 20140014841A1 · Jan 16, 2014