IP Library Granted Patent US 9,873,638
Granted Patent B2
US 9,873,638 · App. 13/962,903 · Granted Jan 23, 2018

Synthetic gypsum fertilizer product and method of making

Inventors: Terrell Dallas Ginn (Milton, KY); Danny Lynn Gray (Marietta, GA)
Assignee: SUL4R-PLUS, LLC
C05D3/00C05D3/02C05G3/0058C05G3/0088G05G3/00
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Quick Facts
Patent No.
US 9,873,638
App. No.
13/962,903
Granted
Jan 23, 2018
Kind
B2
Abstract

Embodiments of the invention are directed to pelletized synthetic gypsum and methods and systems for producing pelletized synthetic gypsum. Synthetic gypsum is combined with a binder composition and pelletized to a desired size. The binder composition may include lignosulfonate. Additives may be included in the pellets such as various plant nutrients and micro-nutrients. An additive may include elemental sulfur. The resulting pellets may have a mean pellet size guide number (SGN) from approximately 150 to approximately 300 and a crush strength from approximately 2 lbf to approximately 12 lbf

Claims (37)

1. A method of producing a fertilizer comprising:

feeding synthetic gypsum to a forming device;

feeding a binder composition comprising lignosulfonate having 18% to 40% solids to the forming device; and

forming the material fed to the forming device to a mean pellet size guide number (SGN) from approximately 100 to approximately 500, wherein the resulting pelletized synthetic gypsum has a crush strength from approximately 2 lbf to approximately 12 lbf.

2. The method of claim 1 , wherein the synthetic gypsum fed to the forming device has a mean particle size of less than 100 microns.

3. The method of claim 1 , wherein the binder composition comprises a water soluble binder.

4. The method of claim 1 , wherein the binder composition also comprises one or more binders selected from the group consisting of brewers condensed solubles, sodium carbonate lignin, cane molasses, beet syrup, beet molasses, desugared beet molasses, whey, starch, starch derivatives, soy solubles with cane molasses, hydrolyzed collagen, amino acid solutions, cellulose derivatives, and cellulose based polymer binders.

5. The method of claim 1 , further comprising feeding an additive to the forming device, wherein the additive is selected from the group consisting of ground calcium carbonate, calcium bentonite, kaolin clays, manganese, zinc, boron, calcium, copper, and elemental sulfur.

6. The method of claim 5 , wherein the additive comprises elemental sulfur.

7. The method of claim 1 , wherein the mean SGN is from approximately 250 to approximately 280.

8. The method of claim 1 , wherein the forming device comprises a pelletizer.

9. The method of claim 1 , wherein the forming device comprises a granulator or an extruder.

10. A fertilizer made by the method of claim 1 .

11. A fertilizer comprising:

pellets, the pellets comprising synthetic gypsum and a binder composition comprising lignosulfonate, wherein the binder composition initially has 18% to 40% solids at the time of contact with the synthetic gypsum, the pellets further comprising mean pellet SGN from approximately 100 to approximately 500, wherein the pellets have a crush strength from approximately 2 to approximately 12 lbf.

12. The fertilizer of claim 11 , wherein the binder composition comprises a water soluble binder.

13. The fertilizer of claim 11 , wherein the binder composition also comprises one or more binders selected from the group consisting of brewers condensed solubles, sodium carbonate lignin, cane molasses, beet syrup, beet molasses, desugared beet molasses, whey, starch, starch derivatives, soy solubles with cane molasses, hydrolyzed collagen, amino acid solutions, cellulose derivatives, and cellulose based polymer binders.

14. The fertilizer of claim 11 , wherein the pellets further comprise an additive, wherein the additive is selected from the group consisting of ground calcium carbonate, calcium bentonite, kaolin clays, manganese, zinc, boron, calcium, copper, and elemental sulfur.

15. The fertilizer of claim 11 , wherein the pellets further comprise an additive comprising elemental sulfur.

16. The fertilizer of claim 11 , wherein the mean SGN is from approximately 250 to approximately 280.

17. A process for producing a fertilizer comprising:

feeding synthetic gypsum to a dryer;

feeding dried synthetic gypsum and a binder composition comprising lignosulfonate having 18% to 40% solids to a mixer;

mixing the material fed to the mixer;

feeding the mixed material to a forming device;

pelletizing the material fed to the forming device;

feeding the pelletized material to a dryer;

drying the pelletized material;

feeding the dried pelletized material to a screener; and

screening the material fed to the screener to a mean pellet size guide number (SGN) from

approximately 100 to approximately 500, wherein the resulting pelletized synthetic gypsum has a crush strength from approximately 2 lbf to approximately 12 lbf.

18. The process of claim 17 , further comprising recycling unders and overs removed during screening to the mixer.

19. The process of claim 17 , wherein the synthetic gypsum fed to the mixer has a mean particle size of less than 100 microns.

20. The process of claim 17 , further comprising feeding an additive to the mixer, wherein the additive is selected from the group consisting of manganese, zinc, boron, calcium, copper, and elemental sulfur.

21. The process of claim 17 , further comprising feeding an additive to the mixer, wherein the additive comprises elemental sulfur.

22. The process of claim 17 , wherein the mean SGN is from approximately 250 to approximately 280.

23. A fertilizer made by the process of claim 17 .

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Oct 25, 2017
From: BANK OF AMERICA, N.A.
To: CHARAH, LLC (FORMERLY KNOWN AS CHARAH, INC.)
Reel/Frame 043951/0314 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 21, 2017
From: CHARAH, LLC
To: SUL4R-PLUS, LLC
Reel/Frame 042768/0542 →
CONVERSION OF ENTITY (INC. TO LLC) AND CHANGE OF NAME Recorded Jan 11, 2017
From: CHARAH, INC.
To: CHARAH, LLC
Reel/Frame 041329/0460 →
SECURITY INTEREST Recorded Jun 30, 2015
From: CHARAH, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 035997/0236 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 5, 2013
From: GINN, TERRELL DALLAS; GRAY, DANNY LYNN
To: CHARAH, INC.
Reel/Frame 031726/0277 →
Continuity (2)
Provisional Application 61681088 · Aug 8, 2012
Related Publication 20150027181A1 · Jan 29, 2015