Method for preparing insulating varnish
A method for preparing an insulating varnish. The method includes: providing equivalence of an epoxy resin solution having a concentration exceeding 99 wt. % and acetone solution having a concentration of 40 wt. %, adding silane coupling agent-modified hexagonal boron nitride (BN) having a particle size of between 200 and 250 nm to the acetone solution and stirring; mixing the epoxy resin solution and the acetone solution and stirring, and dispersing the resulting mixture; adding to the mixture, low molecular weight polyamide resins as a curing agent, and stirring to uniformly disperse the curing agent; adding n-butane as a lubricant to the mixture and stirring, cooling the mixture to room temperature, adding di-n-butyl phthalate as a diluent to the mixture and stirring; and allowing the mixture to stand in a vacuum drier to remove bubbles to yield the insulating varnish, which is free of bubbles.
1. A method for preparing an insulating varnish, the method comprising the following steps:
a) adding silane coupling agent-modified hexagonal boron nitride (BN) having a particle size of between 200 and 250 nm to acetone to obtain a first solution, stirring the first solution for between 1 and 1.5 h;
b) mixing an epoxy resin and the first solution to obtain a second solution, stirring, and dispersing the second solution using an ultrasonic cleaning machine at a temperature of between 65 and 70° C. for between 2 and 2.5 h, wherein a weight ratio of the epoxy resin to the acetone is 1:1;
c) adding as a curing agent low molecular weight polyamide resin to the second solution to obtain a third solution, and stirring the third solution using a magnetic stirrer to allow the curing agent to be dispersed uniformly, wherein an amount of the curing agent is between 20 and 25 wt. % of the epoxy resin;
d) adding n-butane as a lubricant to the third solution and stirring, cooling to room temperature, then adding di-n-butyl phthalate as a diluent and stirring to obtain a mixture, wherein an amount of the lubricant is between 3 and 5 wt. % of the epoxy resin, and an amount of the diluent is between 10 and 12 wt. % of the epoxy resin; and
e) allowing the mixture to stand in a vacuum drier for removing bubbles to yield the insulating varnish free of bubbles, a temperature of the vacuum drier being controlled at between 20 and 25° C.;
wherein in a), an amount of the silane coupling agent-modified hexagonal boron nitride is between 25 and 30 wt. % of the epoxy resin used in step b).
2. The method of claim 1 , the method further comprising:
a) providing a copperplate sample, burnishing, washing, and degreasing the copperplate sample with acetone;
b) dipping the copperplate sample in the insulating varnish and drip-drying, a thickness of the insulating varnish being controlled at between 0.10 and 0.15 mm; and
c) continuously roasting the copperplate sample coated with the insulating varnish in a high temperature furnace at 60° C. for 1 h, at 120° C. for 1.5 h, and at 150° C. for 2 h, and scraping off a varnish film from the copperplate sample.
3. The method of claim 1 , wherein the silane coupling agent is selected from the group consisting of γ-aminopropyl triethoxysilane (KH550), γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560), γ-methacryloxypropyl trimethoxysilane (KH570), N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (KH792), N-(β-aminoethyl)-γ-aminopropylmethylbimethoxysilane (DL602), and ethenyltrimethoxy (DL171).
4. The method of claim 1 , wherein the epoxy resin has a purity exceeding 99 wt. %.