Heat-insulating material
View Patent ↗A heat-insulating material is provided in which thermal conductivity is controlled not to increase and good insulation properties are held even in a high temperature range. The heat-insulating material is formed of a spinel porous sintered body having a porosity of 65 to 90 vol. % and represented by a chemical formula XAl 2 O 4 (X=Zn, Fe, Mg, Ni, or Mn) which is arranged such that large pores having a diameter of greater than 1000 μm occupy 25 vol. % or less of the total pore volume, fine pores having a diameter of 0.45 μm or less occupy 5 to 40 vol. % of the volume of the pores having a diameter of 1000 μm or less, at least one pore-diameter distribution peak is within a range of 0.14 to 10 μm, and is formed of sintered particles having a calculated average particle diameter of 0.04 to 1 μm.
1. A heat-insulating material formed of a spinel porous sintered body having a porosity of from 65 vol. % to 90 vol. % and represented by a chemical formula XAl 2 O 4 , wherein
X in said chemical formula is selected from the group consisting of Zn, Fe, Mg, Ni, and Mn,
large pores having a pore diameter of greater than 1000 μm occupy 25 vol. % or less of the total volume of pores in the heat-insulating material,
fine pores having a pore diameter of 0.45 μm or less occupy 5 vol. % to 40 vol. % of the volume of the pores having a pore diameter of 1000 μm or less,
at least one pore-diameter distribution peak is within a pore diameter range of from 0.14 μm to 10 μm, and
a calculated average particle diameter of sintered particles is from 0.04 μm to 1 μm.
2. A heat-insulating material as claimed in claim 1 , wherein at least one pore-diameter distribution peak is within a pore-diameter range of 0.14 μm to less than 0.45 μm, and at least one pore-diameter distribution peak is within a pore-diameter range of from 0.45 μm to 10 μm.
3. A heat-insulating material as claimed in claim 1 , wherein at least one pore-diameter distribution peak is within a pore-diameter range of greater than 10 μm to 1000 μm or less.
4. A heat-insulating material as claimed in claim 2 , wherein at least one pore-diameter distribution peak is within a pore-diameter range of greater than 10 μm to 1000 μm or less.
5. A heat-insulating material formed of a porous sintered body made of MgAl 2 O 4 and having a porosity of 73 vol. % or more, wherein
the pores having a pore-diameter of 0.8 μm to less than 10 μm occupy 60 vol. % to less than 80 vol. % of the total volume of pores in the heat-insulating material,
the pores having a pore-diameter of 0.01 μm or more and less than 0.8 μm occupy 10 vol. % to less than 30 vol. % of the total volume of pores in the heat-insulating material, and
thermal conductivity of the heat-insulating material at from 1000° C. to 1500° C. does not exceed 1.5 times the thermal conductivity at from 20° C. to 1000° C.
6. A heat-insulating material as claimed in claim 5 , wherein the thermal conductivity at from 1000° C. to 1500° C. is 0.3 W/m·K or less.
7. A heat-insulating material as claimed in claim 5 , wherein the thermal conductivity at from 1000° C. to 1500° C. is 0.26 W/m·K or less.
8. A heat-insulating material as claimed in claim 6 , wherein the thermal conductivity at from 1000° C. to 1500° C. does not exceed 1.2 times the thermal conductivity at from 20° C. to 1000° C.
9. A heat-insulating material as claimed in claim 7 , wherein the thermal conductivity at from 1000° C. to 1500° C. does not exceed 1.2 times the thermal conductivity at from 20° C. to 1000° C.
10. A heat-insulating material as claimed in claim 5 , wherein volumetric specific heat of the heat-insulating material is 1.2 J/cm 3 ·K or less.
11. A heat-insulating material as claimed in claim 6 , wherein volumetric specific heat of the heat-insulating material is 1.2 J/cm 3 ·K or less.
12. A heat-insulating material as claimed in claim 7 , wherein volumetric specific heat of the heat-insulating material is 1.2 J/cm 3 ·K or less.
13. A heat-insulating material as claimed in claim 8 , wherein volumetric specific heat of the heat-insulating material is 1.2 J/cm 3 ·K or less.
14. A heat-insulating material as claimed in claim 9 , wherein volumetric specific heat of the heat-insulating material is 1.2 J/cm 3 ·K or less.