Inorganic composition for transferring a fine unevenness
Disclosed is an inorganic composition for transferring a fine unevenness by which a fine unevenness made of an inorganic material capable of controlling a refractive index can be fabricated through a suitable transfer process. The composition according to the present invention contains a silicone compound and at least two types of metal alkoxides, wherein the metal alkoxides include a metal alkoxide having a metal species M1 (where M1 denotes at least one metal element selected from a group consisting of Ti, Zr, Zn, Sn, B, In, and Al) and a metal alkoxide having a metal species Si. In addition, a ratio between a molarity C M1 of the metal alkoxide having the metal species M1 and a molarity C Si of the metal alkoxide having the metal species Si in the inorganic composition for transferring a fine unevenness satisfies a condition of 0.2≤C M1 /C Si ≤24.
1. An inorganic composition for transferring a fine unevenness comprising:
a silicone compound; and
at least two metal alkoxides, wherein
the metal alkoxides comprise a metal alkoxide having a metal species M1, where M1 denotes at least one metal element selected from a group consisting of Ti, Zr, Zn, Sn, B, In, and Al, and a metal alkoxide having a metal species Si,
a ratio (C M1 /C Si ) between a molarity (C M1 ) of the metal alkoxide having the metal species M1 and a molarity (C Si ) of the metal alkoxide having the metal species Si in the inorganic composition for transferring a fine unevenness satisfies a condition of Equation (1): 0.04≤C M1 /C Si ≤4.56, and
the inorganic composition is prepared by mixing said silicone compound and said at least two metal alkoxides.
2. An inorganic composition for transferring a fine unevenness comprising:
a silicone compound;
at least two metal alkoxides; and
an photopolymerization initiator, wherein
the metal alkoxides comprise a metal alkoxide having a metal species M1, where M1 denotes at least one metal element selected from a group consisting of Ti, Zr, Zn, Sn, B, In, and Al, and a metal alkoxide having a metal species Si,
the metal alkoxide having the metal species Si includes a metal alkoxide having any one of an acryl group, a methacryl group, an acryloyl group, a methacryloyl group, an acryloxy group, a methacryloxy group, a vinyl group, an epoxy group, or an oxetane group in a single molecule,
a ratio between a molarity C M1 of the metal alkoxide having the metal species M1 and a molarity C Si of the metal alkoxide having the metal species Si in the inorganic composition for transferring a fine unevenness satisfies a condition of Equation (2): 0.04≤C M1 /C Si ≤4.56, and
the inorganic composition is prepared by mixing said silicone compound and said at least two metal alkoxides.
3. An inorganic composition for transferring a fine unevenness comprising:
a silicone compound;
at least two metal alkoxides; and
a photoacid generator, wherein
the metal alkoxides comprise a metal alkoxide having a metal species M1, where M1 denotes at least one metal element selected from a group consisting of Ti, Zr, Zn, Sn, B, In, and Al, and a metal alkoxide having a metal species Si,
a ratio between a molarity C M1 of the metal alkoxide having the metal species M1 and a molarity C Si , of the metal alkoxide having the metal species Si in the inorganic composition for transferring a fine unevenness satisfies a condition of Equation (3): 0.04≤C M1 /C Si ≤4.56, and
the inorganic composition is prepared by mixing said silicone compound and said at least two metal alkoxides.
4. The inorganic composition for transferring a fine unevenness according to claim 1 , wherein at least any one of the silicone compound or the metal alkoxides includes an aryl group.
5. The inorganic composition for transferring a fine unevenness according to claim 4 , wherein the aryl group is bound with silicon (Si).
6. The inorganic composition for transferring a fine unevenness according to claim 1 , wherein the metal alkoxide is a partially condensed material.
7. The inorganic composition for transferring a fine unevenness according to claim 1 , further containing a fluorine-contained silane coupling agent.
8. The inorganic composition for transferring a fine unevenness according to claim 1 , wherein, when the composition is dissolved in a propylene glycol monomethyl ether solvent at a concentration of 3 weight %, and a small-angle X-ray scattering measurement using X-rays having a wavelength of 0.154 nm is performed for the solution, a radius of inertia computed by applying a Gunier plot to a result of the measurement is 5 nm or shorter.
9. The inorganic composition for transferring a fine unevenness according to claim 1 , wherein the metal alkoxides are condensed in a chain of —O-M1-O-M2-O-M3-O-M4-O—, where M1, M2, M3, and M4 denote metal elements, which are identical to each other or different from each other.
10. The inorganic composition for transferring a fine unevenness according to claim 1 , wherein the metal alkoxides are condensed into a general formula [—O-M-] n , where M =Ti or Si, and n ≥4.