IP Library Granted Patent US 10,160,847
Granted Patent B2
US 10,160,847 · App. 13/988,703 · Granted Dec 25, 2018

Tyre tread

Inventors: Pierre Lesage (Clermont-Ferrand, FR); Philippe Labrunie (Clermont-Ferrand, FR); Didier Vasseur (Clermont-Ferrand, FR); Xavier Saintigny (Clermont-Ferrand, FR)
Assignee: COMPAGNIE GENERALE DES ETABLISSMENTS MICHELIN
C08L9/06B60C1/0016C08L19/006C08K3/34C08K5/0016C08L7/00C08L9/04C08L45/00C08L47/00C08L2666/04C08L2666/08
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Quick Facts
Patent No.
US 10,160,847
App. No.
13/988,703
Granted
Dec 25, 2018
Kind
B2
Abstract

A tire, which has an improved grip on wet ground, includes a tread formed of at least a rubber composition. The rubber composition includes: 20 to 100 phr of a first diene elastomer bearing at least one SiOR function, with R being hydrogen or a hydrocarbon radical, and with phr referring to parts by weight per hundred parts of elastomer; 100 to 160 phr of a reinforcing inorganic filler; and a plasticizing system. The plasticizing system includes: a content A of between 5 and 60 phr of a hydrocarbon resin having a Tg above 20° C.; and a content B of between 5 and 60 phr of a liquid plasticizing agent. A total content A+B is greater than 45 phr. The rubber composition optionally includes 0 to 80 phr of a second diene elastomer.

Claims (53)

1. A tire comprising a tread formed of at least a rubber composition, wherein the rubber composition includes:

50 to 100 phr of a first diene elastomer bearing a single SiOR function, R being hydrogen or a hydrocarbon radical;

105 to 150 phr of silica;

less than 8 phr of carbon black;

a plasticizing system that includes:

a content A of between 5 and 60 phr of a hydrocarbon resin having a Tg above 20° C., and

a content B of between 5 and 60 phr of a liquid plasticizing agent,

wherein a total content A+B is between 50 and 80 phr.

2. The tire according to claim 1 , wherein the first diene elastomer is a butadiene-styrene copolymer.

3. The tire according to claim 1 , wherein R is hydrogen.

4. The tire according to claim 1 , wherein R is an alkyl.

5. The tire according to claim 1 , wherein the rubber composition further includes:

0 to 80 phr of a second diene elastomer.

6. The tire according to claim 5 , wherein the second diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers, and blends thereof.

7. The tire according to claim 5 , wherein the second diene elastomer bears at least one tin function.

8. The tire according to claim 1 , wherein a ratio of the content A to the content B is between 1:5 and 5:1.

9. The tire according to claim 1 , wherein the hydrocarbon resin is selected from the group consisting of cyclopentadiene homopolymer or copolymer resins, dicyclopentadiene homopolymer or copolymer resins, terpene homopolymer or copolymer resins, C 5 -cut homopolymer or copolymer resins, C 9 -cut homopolymer or copolymer resins, α-methylstyrene homopolymer or copolymer resins, and blends thereof.

10. The tire according to claim 1 , wherein the liquid plasticizing agent is selected from the group consisting of liquid diene polymers, polyolefin oils, naphthenic oils, paraffinic oils, distillate aromatic extract oils, medium extracted solvate oils, treated distillate aromatic extract oils, residual aromatic extract oils, treated residual aromatic extract oils, safety residual aromatic extract oils, mineral oils, vegetable oils, ether plasticizers, ester plasticizers, phosphate plasticizers, sulphonate plasticizers, and mixtures thereof.

11. The tire according to claim 1 , wherein a weight ratio of a weight of the total content A+B to a weight of the reinforcing inorganic filler is between 35% and 70%.

12. A tire comprising a tread formed of at least a rubber composition, wherein the rubber composition includes:

50 to 100 phr of a first diene elastomer bearing a single SiOR function, R being hydrogen or a hydrocarbon radical;

105 to 150 phr of silica;

less than 10 phr of carbon black;

a plasticizing system that includes:

a content A of between 5 and 60 phr of a hydrocarbon resin having a Tg above 20° C., and

a content B of between 5 and 60 phr of a liquid plasticizing agent,

wherein a total content A+B is between 50 and 80 phr, and

wherein the composition comprises no elastomer other than the first diene elastomer and an optional second diene elastomer, the optional second diene elastomer being a polybutadiene or butadiene copolymer.

13. The tire according to claim 12 , wherein the first diene elastomer is a butadiene-styrene copolymer.

14. The tire according to claim 12 , wherein R is hydrogen.

15. The tire according to claim 12 , wherein R is an alkyl.

16. The tire according to claim 12 , wherein the optional second diene elastomer bears at least one tin function.

17. The tire according to claim 12 , wherein a ratio of the content A to the content B is between 1:5 and 5:1.

18. The tire according to claim 12 , wherein the hydrocarbon resin is selected from the group consisting of cyclopentadiene homopolymer or copolymer resins, dicyclopentadiene homopolymer or copolymer resins, terpene homopolymer or copolymer resins, C 5 -cut homopolymer or copolymer resins, C 9 -cut homopolymer or copolymer resins, α-methylstyrene homopolymer or copolymer resins, and blends thereof.

19. The tire according to claim 12 , wherein the liquid plasticizing agent is selected from the group consisting of liquid diene polymers, polyolefin oils, naphthenic oils, paraffinic oils, distillate aromatic extract oils, medium extracted solvate oils, treated distillate aromatic extract oils, residual aromatic extract oils, treated residual aromatic extract oils, safety residual aromatic extract oils, mineral oils, vegetable oils, ether plasticizers, ester plasticizers, phosphate plasticizers, sulphonate plasticizers, and mixtures thereof.

20. The tire according to claim 12 , wherein a weight ratio of a weight of the total content A+B to a weight of the reinforcing inorganic filler is between 35% and 70%.

21. A tire comprising a tread formed of at least a rubber composition, wherein the rubber composition includes:

50 to 100 phr of a first diene elastomer bearing a single SiOR function, R being hydrogen or a hydrocarbon radical;

105 to 150 phr of silica;

less than 8 phr of carbon black;

a plasticizing system that includes:

a content A of between 5 and 60 phr of a hydrocarbon resin having a Tg above 20° C., and

a content B of between 5 and 60 phr of a liquid plasticizing agent,

wherein a total content A+B is between 50 and 80 phr, and

wherein the composition comprises no elastomer other than the first diene elastomer and an optional second diene elastomer, the optional second diene elastomer being a polybutadiene or butadiene copolymer.

22. The tire according to claim 21 , wherein the first diene elastomer is a butadiene-styrene copolymer.

23. The tire according to claim 21 , wherein R is hydrogen.

24. The tire according to claim 21 , wherein R is an alkyl.

25. The tire according to claim 21 , wherein the optional second diene elastomer bears at least one tin function.

26. The tire according to claim 21 , wherein a ratio of the content A to the content B is between 1:5 and 5:1.

27. The tire according to claim 21 , wherein the hydrocarbon resin is selected from the group consisting of cyclopentadiene homopolymer or copolymer resins, dicyclopentadiene homopolymer or copolymer resins, terpene homopolymer or copolymer resins, C 5 -cut homopolymer or copolymer resins, C 9 -cut homopolymer or copolymer resins, α-methylstyrene homopolymer or copolymer resins, and blends thereof.

28. The tire according to claim 21 , wherein the liquid plasticizing agent is selected from the group consisting of liquid diene polymers, polyolefin oils, naphthenic oils, paraffinic oils, distillate aromatic extract oils, medium extracted solvate oils, treated distillate aromatic extract oils, residual aromatic extract oils, treated residual aromatic extract oils, safety residual aromatic extract oils, mineral oils, vegetable oils, ether plasticizers, ester plasticizers, phosphate plasticizers, sulphonate plasticizers, and mixtures thereof.

29. The tire according to claim 21 , wherein a weight ratio of a weight of the total content A+B to a weight of the reinforcing inorganic filler is between 35% and 70%.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2017
From: MICHELIN RECHERCHE ET TECHNIQUE S.A.
To: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Reel/Frame 044049/0310 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2013
From: LESAGE, PIERRE; LABRUNIE, PHILIPPE; VASSEUR, DIDIER; SAINTIGNY, XAVIER
To: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN; MICHELINE RECHERCHE ET TECHNIQUE S.A.
Reel/Frame 030688/0746 →
Priority Claims (1)
FR 10 59810 · Nov 26, 2010 · national
Continuity (1)
Related Publication 20130296471A1 · Nov 7, 2013
Cited By (13)
US 12,215,231 US 12,251,965 US 12,286,529 US 12,325,797 US 12,365,202 US 12,365,787 US 12,370,830 US 12,370,831 US 12,371,552 US 12,371,553 US 12,466,214 US 12,698,382 US 12,729,288