Process for producing silver nanowires and agent for controlling growth of silver nanowires
Provided is a process for silver nanowire production in which the major-axis length of the silver nanowires can be controlled in a wide range and an agent for controlling the growth of silver nanowires. A process for silver nanowire production which is characterized in that an agent for controlling the growth of silver nanowires which comprises a polymer obtained by polymerizing one or more polymerizable monomers comprising an N-substituted (meth)acrylamide is reacted with a silver compound in a polyol at 25-180° C. The agent for controlling the growth of silver nanowires is characterized by comprising a polymer which has units of an N-substituted (meth)acrylamide as a polymerizable monomer.
1. A process for producing silver nanowires comprising reacting an agent for controlling silver nanowire growth with a silver compound in a polyol at a temperature from 25 to 180° C., wherein the agent is a polymer obtained by polymerizing polymerizable monomers containing monomers of a N-substituted (meth)acrylamide,
wherein the N-substituted (meth)acrylamide is expressed by general formula (1), or N-acryloylmorpholine,
wherein R1 denotes a hydrogen atom or methyl group, R2 a hydrogen atom or an alkyl group having 1-6 carbon atoms, and R3 a hydroxyalkyl group having 1-5 carbon atoms.
2. The process for producing silver nanowires according to claim 1 , wherein the reaction is carried out in the presence of chloride ions.
3. The process for producing silver nanowires according to claim 1 , wherein the silver nanowires are produced in an environment shielded from light.
4. The process for producing silver nanowires according to claim 3 , wherein the polymer is produced by polymerizing from 60 to 100% by mass of the monomers of the N-substituted (meth)acrylamide and from 40 to 0% by mass of other polymerizable monomers.
5. The process for producing silver nanowires according to claim 4 , wherein the N-substituted (meth)acrylamide is at least one selected from the group consisting of N-(2-hydroxyethyl)acrylamide, and N-acryloylmorpholine.
6. The process for producing silver nanowires according to claim 3 , wherein the N-substituted (meth)acrylamide is at least one selected from the group consisting of N-(2-hydroxyethyl)acrylamide, and N-acryloylmorpholine.
7. The process for producing silver nanowires according to claim 1 , wherein the polymer is produced by polymerizing from 60 to 100% by mass of the monomers of the N-substituted (meth)acrylamide and from 40 to 0% by mass of other polymerizable monomers.
8. The process for producing silver nanowires according to claim 7 , wherein the N-substituted (meth)acrylamide is at least one selected from the group consisting of N-(2-hydroxyethyl)acrylamide, and N-acryloylmorpholine.
9. The process for producing silver nanowires according to claim 1 , wherein the polymer has a weight average molecular weight in a range of 8,000 to 4,000,000.
10. The process for producing silver nanowires according to claim 1 , wherein the silver nanowires have a length along their major axis from 0.5 to 1000 μm,
wherein the length is an arithmetic mean of the respective length of 100 silver nanowires along their major axis.
11. The process for producing silver nanowires according to claim 1 , wherein the N-substituted (meth)acrylamide is at least one selected from the group consisting of N-(2-hydroxyethyl)acrylamide, and N-acryloylmorpholine.