Aluminum alloy foil for electrode current collectors and manufacturing method thereof
An aluminum alloy foil for an electrode current collectors has a high post-drying strength after application of an active material while keeping a high electrical conductivity. The aluminum alloy foil includes 0.1 to 1.0 mass % of Fe, 0.01 to 0.5% of Si, and 0.01 to 0.2 mass % of Cu, and the rest includes Al and unavoidable impurities. The aluminum alloy foil after final cold rolling has a tensile strength of 220 MPa or higher, a 0.2% yield strength of 180 MPa or higher, and an electrical conductivity of 58% IACS or higher. The aluminum alloy foil has a tensile strength of 190 MPa or higher and a 0.2% yield strength of 160 MPa or higher after the aluminum alloy foil is heat treated at any of 120° C. for 24 hours, 140° C. for 3 hours, and 160° C. for 15 minutes.
1. An electrode current collector formed by the steps of:
applying an active material onto an aluminum alloy foil obtained by final cold rolling of an aluminum alloy obtained by subjecting an aluminum alloy ingot, comprising 0.1 to 1.0 mass % of Fe, 0.01 to 0.5 mass % of Si, and 0.01 to 0.2 mass % of Cu, with the rest consisting of Al and unavoidable impurities, each of the unavoidable impurities being contained by 0.02 mass % or less, and a total amount of the unavoidable impurities being 0.15 mass % or less, to a homogenizing treatment at 550° C. to 620° C. for 3 to 6 hours, followed by a hot rolling, with a starting temperature of 500° C. to 550° C. and an end-point temperature of 255° C. to 300° C., and a cold rolling, wherein the aluminum alloy foil after the final cold rolling has a tensile strength of 220 MPa or higher, a 0.2% yield strength of 180 MPa or higher, and an electrical conductivity of 58% IACS or higher; and the aluminum alloy foil is capable of maintaining a tensile strength of 190 MPa or higher and a 0.2% yield strength of 160 MPa or higher even after the aluminum alloy foil is subjected to heat treatment at 120° C. for 24 hours, at 140° C. for 3 hours, or at 160° C. for 15 minutes.
2. A method for manufacturing the electrode current collector according to claim 1 , comprising: subjecting an aluminum alloy ingot to homogenizing treatment at 550 to 620° C. for 3 to 6 hours; and performing hot rolling at a starting temperature of 500° C. to 550° C. and at an end-point temperature of 255 to 300° C.
3. The electrode current collector of claim 1 , wherein the aluminum alloy foil comprises 0.03 to 0.16 mass % of Cu.
4. The electrode current collector of claim 1 , wherein the aluminum alloy foil comprises 0.05 to 0.3 mass % of Si.
5. The electrode current collector of claim 1 , wherein the aluminum alloy foil comprises 0.3 to 0.8 mass % of Fe.
6. A method for manufacturing the electrode current collector according to claim 3 , comprising: subjecting an aluminum alloy ingot to homogenizing treatment at 550 to 620° C. for 3 to 6 hours; and performing hot rolling at a starting temperature of 500° C. to 550° C. and at an end-point temperature of 255 to 300° C.
7. A method for manufacturing the electrode current collector according to claim 4 , comprising: subjecting an aluminum alloy ingot to homogenizing treatment at 550 to 620° C. for 3 to 6 hours; and performing hot rolling at a starting temperature of 500° C. to 550° C. and at an end-point temperature of 255 to 300° C.
8. A method for manufacturing the electrode current collector according to claim 5 , comprising: subjecting an aluminum alloy ingot to homogenizing treatment at 550 to 620° C. for 3 to 6 hours; and performing hot rolling at a starting temperature of 500° C. to 550° C. and at an end-point temperature of 255 to 300° C.