Method for preparing high purity isobutene using glycolether
Disclosed is a method of preparing isobutene in which high-purity isobutene is separated (prepared) from a C 4 mixture by cracking glycol ether prepared from a C 4 mixture (in particular, C 4 raffinate-1) containing isobutene and a glycol. The method includes cracking glycol ether into isobutene and glycol at a temperature between 50° C. and 300° C. in the presence of a strongly acidic catalyst. The glycol ether may be prepared by reaction between a C 4 mixture containing isobutene and glycol in the presence of an acid catalyst.
1. A method of preparing isobutene, comprising the sequential steps of:
a) reacting a C 4 mixture containing isobutene with glycol in the presence of an acid catalyst to provide a glycol ether, wherein said glycol ether comprises glycol di-t-butyl ether and glycol mono-t-butyl ether, and wherein an amount of glycol di-t-butyl ether is larger than an amount of glycol mono-t-butyl ether;
b) separating said glycol ether from the unreacted C 4 mixture and glycol; and
c) cracking said glycol ether into isobutene and glycol at a temperature between 50° C. and 300° C. in the presence of a strongly acidic catalyst, wherein the glycol di-t-butyl ether of said glycol ether is completely decomposed.
2. The method according to claim 1 , wherein the cracking is performed in a glycol ether cracking reactor or a reactive distillation column.
3. The method according to claim 1 , wherein the acid catalyst is a strongly acidic solid ion exchange resin containing a sulfonic acid group.
4. The method according to claim 1 , wherein the glycol is a compound represented by Formula 1 below:
wherein R 1 and R 2 are each independently a hydrogen atom or a C 1 -C 5 alkyl group, and n is an integer of 0 to 4.
5. The method according to claim 1 , wherein the cracking is continuously or non-continuously performed.
6. The method according to claim 1 , wherein the C 4 mixture of step (a) comprises isobutene in an amount of between 30 wt % and 50 wt %.
7. The method according to claim 1 , wherein a molar ratio of glycol to isobutene in step (a) is from 1:1 to 5:1.