Cobalt-base alloy with high heat resistance and high strength and process for producing the same
A process for producing a Co-base alloy which has a basic composition including, in terms of mass proportion, 0.1%-10% Al, 3.0-45% W, and Co as the remainder and has an intermetallic compound of the L1 2 type [Co 3 (Al,W)] dispersed and precipitated therein. Part of the Co may be replaced with Ni, Ir, Fe, Cr, Re, or Ru, while part of the Al and W may be replaced with Ni, Ti, Nb, Zr, V, Ta or Hf. The intermetallic compound [Co 3 (Al, W)] has a high melting point, and this compound and the matrix are mismatched little with respect to lattice constant. Thus, the cobalt-base alloy can have high-temperature strength equal to that of nickel-base alloys and excellent structure stability.
1. A process for producing a cobalt-base alloy with high heat resistance and high strength, the cobalt-base alloy comprising a composition of, in terms of mass proportion: 0.1 to 10% of Al, 3.0 to 45% of W both amounting to less than 50% in total content and Co as a remainder containing indispensable impurities, the process comprising the steps of:
solution-treating the Co base-alloy with the composition in a temperature range of 1100 to 1400° C. for one to two hours after forming the Co base-alloy into a predetermined shape; and
subsequently performing aging treatment on the solution-treated Co base-alloy in a temperature range of 500 to 1100° C. for one to 168 hours so as to form
a matrix phase (γ phase) essentially consisting of Co having an fcc structure and
a precipitation phase (γ′ phase) comprising a L1 2 -type intermetallic compound of Co 3 (Al,W) by atom ratio having an fcc structure, and
wherein the precipitation phase (γ′ phase) is precipitated in particles of the matrix phase, and
a particle diameter of the precipitation phase (γ′ phase) of Co 3 (Al,W) ranges from 50 nm to 1 μm and a precipitation amount thereof ranges from 40 to 85% by volume fraction, and
a lattice mismatch between the matrix phase (γ phase) of the cobalt-base alloy and the precipitation phase (γ′ phase) of Co 3 (Al,W) thereof is 0.5% or less.
2. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 1 ,
wherein a Vickers hardness of the cobalt-base alloy at 800° C. is 250 or higher.
3. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 1 ,
wherein the cobalt-base alloy includes a DO 19 type intermetallic compound of Co 3 W by atom ratio to be precipitated in the matrix phase (γ phase).
4. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 1 ,
wherein the cobalt-base alloy includes a B2 phase intermetallic compound of CoAl by atomic ratio to be precipitated in the matrix phase (γ phase).
5. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 1 ,
wherein the cobalt-base alloy comprises one or more components selected from the following Group (I) in a total of 0.001 to 2.0% by mass, the Group (I) being defined as: 0.001 to 1.0% of B, 0.001 to 2.0% of C, 0.01 to 1.0% of Y, and 0.01 to 1.0% of La or misch metal.
6. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 5 ,
wherein a Vickers hardness of the cobalt-base alloy at 800° C. is 250 or higher.
7. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 5 ,
wherein the cobalt-base alloy includes a DO 19 type intermetallic compound of Co 3 W by atom ratio to be precipitated in the matrix phase (γ phase).
8. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 5 ,
wherein the cobalt-base alloy includes a B2 phase intermetallic compound of CoAl by atomic ratio to be precipitated in the matrix phase (γ phase).
9. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 5 ,
wherein the cobalt-base alloy to which the C component is added includes carbide to be precipitated in the matrix phase (γ phase).
10. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 1 ,
wherein the cobalt-base alloy further comprises one or more components selected from the following Group (II) in a total of 0.1 to 50% by mass,
wherein a L1 2 -type intermetallic compound precipitated is (Co, X) 3 (Al,W, Z) by atom ratio, and the Group (II) being defined as: X being Ir, Fe, Cr, Re, and/or Ru; Z being Mo, Ti, Nb, Zr, V, Ta, and/or Hf; and nickel being comprised in both X and Z.
11. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 10 , wherein a Vickers hardness of the cobalt-base alloy at 800° C. is 250 or higher.
12. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 10 , wherein the cobalt-base alloy includes a DO 19 type intermetallic compound of Co 3 W by atom ratio to be precipitated in the matrix phase (γ phase).
13. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 10 , wherein the cobalt-base alloy includes a B2 phase intermetallic compound of CoAl by atomic ratio to be precipitated in the matrix phase (γ phase).
14. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 5 ,
wherein the cobalt-base alloy further comprises one or more components selected from the following Group (II) in a total of 0.1 to 50% by mass,
wherein a type L1 2 -type intermetallic compound precipitated is (Co, X) 3 (Al,W, Z) by atom ratio, and
the Group (II) being defined as: X being Ir, Fe, Cr, Re, and/or Ru; Z being Mo, Ti, Nb, Zr, V, Ta, and/or Hf; and nickel being comprised in both X and Z.
15. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 14 ,
wherein a Vickers hardness of the cobalt-base alloy at 800° C. is 250 or higher.
16. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 14 ,
wherein the cobalt-base alloy includes a DO 19 type intermetallic compound of Co 3 W by atom ratio to be precipitated in the matrix phase (γ phase).
17. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 14 ,
wherein the cobalt-base alloy includes a B2 phase intermetallic compound of CoAl by atomic ratio to be precipitated in the matrix phase (γ phase).
18. The process for producing a cobalt-base alloy with high heat resistance and high strength according to claim 14 ,
wherein the cobalt-base alloy to which the C component is added includes carbide to be precipitated in the matrix phase (γ phase).