Nanophotonic production, modulation and switching of ions by silicon microcolumn arrays
The production and use of silicon microcolumn arrays that harvest light from a laser pulse to produce ions are described. The systems of the present invention seem to behave like a quasi-periodic antenna array with ion yields that show profound dependence on the plane of laser light polarization and the angle of incidence. By providing photonic ion sources, this enables enhanced control of ion production on a micro/nano scale and direct integration with miniaturized analytical devices.
1. A device for controlling fragmentation and ion production from a sample, the device comprising:
an array for receiving the sample, the array being made from a semiconductor material and having quasi-periodic columnar structures;
wherein the array is configured to retain the sample and receive plane polarized radiation from a laser source; and
wherein the columnar structures are configured so that when the angle of the plane polarization of the laser source approaches the angle of p-polarized radiation, the fragmentation and ion production from the sample is increased, and when the angle of the plane polarization of the laser source approaches the angle of s-polarized radiation, the fragmentation and ion production from the sample is decreased.
2. The device of claim 1 , wherein the semiconductor material is selected from the group consisting of: p-type or n-type silicon, germanium and gallium arsenide at various doping levels.
3. The device of claim 1 , wherein the array is a laser-induced silicon microcolumn array.
4. The device of claim 1 , wherein the columnar structures have a height of about 1 to 5 times the wavelength of the radiation, a diameter equal to about one wavelength of the radiation, and a lateral periodicity of about 1.5 times the wavelength of the radiation.
5. The device of claim 1 , wherein the radiation is selected from the group consisting of: ultraviolet radiation, visible radiation, and infrared radiation.
6. The device of claim 1 , wherein the dynamic range of the device is greater than about 4 magnitude and wherein the limit of detection of the device is about 1 attomole.
7. The device of claim 5 , wherein the columnar structures have a height of about 1 to 5 times the wavelength of the radiation.
8. The device of claim 7 , wherein the columnar structures have a height of about 2 times to 5 times the wavelength of the radiation.
9. The device of claim 5 , wherein the columnar structures have a diameter of about the wavelength of the radiation.
10. The device of claim 5 , wherein the columnar structures have a lateral periodicity of about 1.5 times the wavelength of the radiation.
11. The device of claim 5 , wherein the columnar structures have a lateral periodicity of about equal to the wavelength of the radiation.
12. The device of claim 5 , wherein the columnar structures have an aspect ratio according to the Formula (1):
height of the columnar structures( h )/diameter of the columnar structures( d ) (Formula 1)
wherein h is about 1 to 5 times the wavelength of the radiation and d is about the wavelength of the radiation.
13. The device of claim 5 , wherein the columnar structures have an aspect ratio according to the Formula (2):
height of the columnar structures( h )/λ (Formula 2)
wherein h is about 1 to 5 times the wavelength of the radiation and the λ is selected from the group consisting of: ultraviolet radiation, visible radiation, and infrared radiation.
14. The device of claim 5 , wherein the columnar structures have an aspect ratio according to the Formula (3):
height of the columnar structures( h )/width of troughs between the columnar structures( t ) (Formula 3)
wherein h is about 1 to 5 times the wavelength of the radiation and t is about 200 nm.