Negative electrode terminal and cover member for lithium ion battery, and lithium ion battery
The present invention relates to a lithium ion battery employed by connecting the positive electrode side to a negative electrode portion made of Cu or a Cu alloy by a bus bar made of Al or an Al alloy and provides a negative electrode terminal for a lithium ion battery capable of providing sufficient bonding strength between the negative electrode portion and the bus bar when the negative electrode portion and the bus bar are metallurgically bonded to each other by resistance welding or the like, for example. This negative electrode terminal for a lithium ion battery is made of a clad material having a first metal layer made of Al or an Al alloy and a second metal layer made of Cu or a Cu alloy bonded to each other through a reaction-suppressing layer suppressing a reaction therebetween.
1. A negative electrode terminal for a lithium ion battery, made of a clad material comprising:
a first metal layer made of Al or an Al alloy;
a second metal layer made of Cu or a Cu alloy disposed under the first metal layer; and
a reaction-suppressing layer interposed between the first metal layer and the second metal layer,
wherein the reaction-suppressing layer suppresses a reaction between the first metal layer and the second metal layer, and
wherein the first metal layer has a thickness larger than a sum of thicknesses of the second metal layer and the reaction-suppressing layer,
the thickness of the first metal layer is uniform,
the thickness of the second metal layer is uniform,
the thickness of the reaction-suppressing layer is uniform, and
the thicknesses are in a direction in which the first metal layer, the second metal layer, and the reaction-suppressing layer are stacked.
2. The negative electrode terminal for a lithium ion battery according to claim 1 , wherein
the reaction-suppressing layer is made of any of Ni or a Ni alloy and Ti or a Ti alloy.
3. The negative electrode terminal for a lithium ion battery according to claim 1 , wherein
the first metal layer and the second metal layer have flat surfaces.
4. The negative electrode terminal for a lithium ion battery according to claim 1 , comprising a bonding layer on a negative electrode side of the second metal layer.
5. The negative electrode terminal for a lithium ion battery according to claim 4 , wherein
the bonding layer is made of any of brazing filler metal containing Cu, Ni or a Ni alloy, and Fe or a Fe alloy.
6. The negative electrode terminal for a lithium ion battery according to claim 1 , wherein
the second metal layer is made of brazing filler metal containing Cu.
7. The negative electrode terminal for a lithium ion battery according to claim 1 , wherein
the second metal layer has a thickness larger than a sum of thicknesses of layers excluding the first metal layer other than the second metal layer.
8. The negative electrode terminal for a lithium ion battery according to claim 1 , having a bonding interface to which exposure prevention processing is applied.
9. A cover member for a lithium ion battery, comprising a negative electrode terminal for a lithium ion battery made of a clad material comprising:
a first metal layer made of Al or an Al alloy;
a second metal layer made of Cu or a Cu alloy disposed under the first metal layer; and
a reaction-suppressing layer interposed between the first metal layer and the second metal layer,
wherein the cover member has a cover member body made of a metal material provided with a hole,
wherein the reaction-suppressing layer suppresses a reaction between the first metal layer and the second metal layer, and
wherein the negative electrode terminal is supported in an electrically insulated state in the hole, and
wherein the first metal layer has a thickness larger than a sum of thicknesses of the second metal layer and the reaction-suppressing layer,
the thickness of the first metal layer is uniform,
the thickness of the second metal layer is uniform,
the thickness of the reaction-suppressing layer is uniform, and
the thicknesses are in a direction in which the first metal layer, the second metal layer, and the reaction-suppressing layer are stacked.
10. The cover member for a lithium ion battery according to claim 9 , wherein
the negative electrode terminal is supported in the hole while protruding from a surface of the cover member body.
11. A lithium ion battery employing a cover member for the lithium ion battery comprising
a negative electrode terminal for a lithium ion battery made of a clad material comprising:
a first metal layer made of Al or an Al alloy
a second metal layer made of Cu or a Cu alloy disposed under the first metal layer; and
a reaction-suppressing layer interposed between the first metal layer and the second metal layer,
the lithium ion battery comprising a housing member housing at least a negative electrode portion made of Cu or a Cu alloy, a positive electrode portion made of Al or an Al alloy, and an electrolyte,
wherein the cover member has a cover member body made of a metal material provided with a hole in which the negative electrode terminal is supported in an electrically insulated state,
wherein the reaction-suppressing layer suppresses a reaction between the first metal layer and the second metal layer,
wherein the first metal layer has a thickness larger than a sum of thicknesses of the second metal layer and the reaction-suppressing layer,
the thickness of the first metal layer is uniform,
the thickness of the second metal layer is uniform,
the thickness of the reaction-suppressing layer is uniform, and
the thicknesses are in a direction in which the first metal layer, the second metal layer, and the reaction-suppressing layer are stacked, and
wherein the housing member is hermetically sealed by the cover member, and the negative electrode portion is connected with the negative electrode terminal.
12. The lithium ion battery according to claim 11 , wherein
positive electrode sides of a plurality of lithium ion batteries are electrically connected to the negative electrode terminal in series by a bus bar made of Al or an Al alloy.