IP Library Granted Patent US 10,338,000
Granted Patent B2
US 10,338,000 · App. 14/035,933 · Granted Jul 2, 2019

Fiber sensor

Inventors: Alexander Gumennik (Brookline, MA); Alexander Mark Stolyarov (Belmont, MA); Brent Richard Schell (Stoughton, MA); Chong Hou (Cambridge, MA); Guillaume Romain Lestoquoy (Cambridge, MA); Fabien Sorin (Saintj-Sulpice, FR); William Richard McDaniel, II (Worcester, MA); Yoel Fink (Brookline, MA); Aimee Rose (Cambridge, MA); John Dimitris Joannopoulos (Belmont, MA)
Assignees: Massachusetts Institute of Technology; FLIR Systems, Incorporated
G01N21/84B29D11/00721G01N21/76G01N21/7703G02B6/4283C03B2201/86G01N2021/7753G01N2021/7786G02B6/02314G02B6/4291
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Quick Facts
Patent No.
US 10,338,000
App. No.
14/035,933
Granted
Jul 2, 2019
Kind
B2
Abstract

There is provided a sensor fiber including an electrically insulating material having a fiber length. At least one transduction element is disposed along at least a portion of the fiber length and is arranged for exposure to an intake species. A photoconducting element is in optical communication with the transduction element. At least one pair of electrically conducting electrodes are in electrical connection with the photoconducting element. The pair of electrodes extend the fiber length.

Claims (43)

1. A sensor fiber comprising:

An elongated, unsupported three-dimensional fiber body comprising an electrically insulating polymeric material, the fiber body having a fiber length and an outer fiber body surface along the fiber length, with at least one intake aperture disposed in the fiber body for accepting an intake species into the fiber body;

at least one transduction element comprising a chemiluminescent material disposed within the fiber body along at least a portion of the to fiber length and arranged for exposure to an intake species provided through an intake aperture in the fiber body, the chemiluminescent material emitting chemiluminescent light upon exposure to a target intake species with a wavelength of chemiluminescence indicative of the target intake species;

at least one photoconducting element comprising a semiconducting material arranged in the fiber body in optical communication with the transduction element to receive chemiluminescent light produced by the chemiluminescent material upon reaction of the chemiluminescent material with the target species to produce a corresponding electrical sensing signal indicative of the target intake species; and

at least one pair of electrically conducting electrodes in electrical connection with the photoconducting element in the fiber body, the pair of electrodes extending the fiber length to transmit the electrical sensing signal to an end of the fiber body.

2. The sensor fiber of claim 1 wherein the chemiluminescent material extends the fiber length.

3. The sensor fiber of claim 1 wherein the chemiluminescent material is disposed at an end of the fiber.

4. The sensor fiber of claim 1 wherein the at least one transduction element comprises a plurality of transduction elements, each transduction element in the plurality disposed at a different site along the fiber length.

5. The sensor fiber of claim 1 wherein the chemiluminescent material comprises a layer of chemiluminescent material.

6. The sensor fiber of claim 1 wherein the chemiluminescent material comprises a layer of chemiluminescent material that is disposed on an internal wall of the fiber body.

7. The sensor fiber of claim 1 wherein the at least one transduction element comprises a plurality of transduction elements, each transduction element in the plurality emitting light upon exposure to a different intake species.

8. The sensor fiber of claim 1 wherein the at least one transduction element comprises a plurality of different chemiluminescent materials.

9. The sensor fiber of claim 1 wherein the target intake species comprises one of peroxide vapor and liquid peroxide.

10. The sensor fiber of claim 1 wherein the target intake species comprises 2,4,6-trinitrotoluene.

11. The sensor fiber of claim 1 wherein the target intake species comprises an explosive species.

12. The sensor fiber of claim 1 wherein the at least one transduction element includes a scintillation transduction element that scintillates upon exposure to a radioactive species.

13. The sensor fiber of claim 1 wherein the chemiluminescent material comprises a material selected from the group consisting of fluorescein and naphthofluorescein.

14. A sensor fiber comprising:

an elongated, unsupported three-dimensional fiber body comprising an electrically insulating polymeric material, the fiber body having a fiber length and an outer fiber body surface along the fiber length;

at least one transduction element comprising a chemiluminescent material disposed within the fiber body along at least a portion of the fiber, the chemiluminescent material emitting chemiluminescent light upon exposure to a target intake species with a wavelength of chemiluminescence indicative of the target intake species;

at least one intake microcapillary disposed within the fiber body and extending the fiber length for intake of species to be sensed, the chemiluminescent material being in communication with a microcapillary for exposure of the chemiluminescent material to an intake species;

at least one photoconducting element comprising a semiconducting material arranged in the fiber body in optical communication with the transduction element to receive chemiluminescent light produced by the chemiluminescent material upon reaction of the chemiluminescent material with the target species to produce a corresponding electrical sensing signal indicative of the target intake species; and

at least one pair of electrically conducting electrodes in electrical connection with the photoconducting element in the fiber body, the pair of electrodes extending the fiber length to transmit the electrical sensing signal to an end of the fiber body.

15. The sensor fiber of claim 14 wherein the at least one intake microcapillary comprises a plurality of spaced-apart intake microcapillaries.

16. The sensor fiber of claim 14 wherein the intake microcapillary comprises a hollow fiber core.

17. The sensor fiber of claim 14 wherein the intake microcapillary has a cross section that is generally circular.

18. The sensor fiber of claim 14 wherein the intake microcapillary has a cross section that is generally rectangular.

19. The sensor fiber of claim 1 wherein the electrically insulating material is substantially transparent to a wavelength of light that is generated by the chemiluminescent material.

20. The sensor fiber of claim 1 further comprising at least one microcapillary disposed within the fiber body, extending the fiber length and in fluidic communication with at least one intake aperture and the chemiluminescent material for exposure of the chemiluminescent material to the intake species.

21. The sensor fiber of claim 1 wherein at least one transduction element is disposed in the fiber body at a site adjacent to an intake aperture.

22. The sensor fiber of claim 1 wherein the semiconducting element comprises a chalcogenide glass.

23. The sensor fiber of claim 1 wherein the semiconducting element comprises a chalcogenide glass selected from the group consisting of Se 97 S 3 , As 24 S 38 Se 38 , and As 30 Se 63 Sb 4 Sn 3 .

24. The sensor fiber of claim 1 wherein the photoconducting element comprises a layer of the semiconducting material, extending the fiber length.

25. The sensor fiber of claim 1 wherein the photoconducting element comprises a layer of the semiconducting material, extending the fiber length and including portions of semiconducting material that are crystalline, separated by portions of semiconducting material that are amorphous.

26. The sensor fiber of claim 1 wherein the photoconducting element comprises a semiconducting material having a bandgap energy that is less than about 3 eV.

27. The sensor fiber of claim 1 wherein the photoconducting element comprises a layer of the semiconducting material, disposed in the fiber body, along the fiber length.

28. The sensor fiber of claim 1 wherein the photoconducting element comprises a layer of the semiconducting material disposed in the fiber body adjacent to the transduction element.

29. The sensor fiber of claim 1 wherein the at least one photoconducting element comprises a plurality of different semiconducting materials, each semiconducting material being sensitive to a different wavelength of chemiluminescent light.

30. The sensor fiber of claim 1 wherein the electrodes comprise a material selected from the group of metals and metal alloys.

31. The sensor fiber of claim 1 wherein the electrodes are connected in a photodetector circuit that includes a voltage source connected to apply a bias voltage to the photoconducting element.

32. The sensor fiber of claim 1 wherein the electrodes are connected to deliver an electrical signal from an end of the sensor fiber to an output circuit that includes a current measurement element to measure an indication of photogenerated charge produced by the photoconducting element.

33. The sensor fiber of claim 1 wherein the electrodes are connected to deliver an electrical signal from an end of the sensor fiber to an output circuit that produces an electrical indication of exposure of the transduction element to an intake species.

34. The sensor fiber of claim 1 wherein each electrode is geometrically confined within the fiber body by the electrically insulating material of the fiber body.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 24, 2019
From: FLIR SYSTEMS, INCORPORATED
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 048979/0445 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 6, 2018
From: GUMENNIK, ALEXANDER; STOLYAROV, ALEXANDER MARK; HOU, CHONG; LESTOQUOY, GUILLAUME ROMAIN; SORIN, FABIEN; FINK, YOEL; JOANNOPOULOS, JOHN DIMITRIS
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 047692/0322 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 24, 2018
From: SCHELL, BRENT RICHARD
To: FLIR SYSTEMS, INCORPORATED
Reel/Frame 047288/0257 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 31, 2017
From: ROSE, AIMEE; MCDANIEL, WILLIAM RICHARD
To: FLIR SYSTEMS, INCORPORATED
Reel/Frame 043460/0774 →
CONFIRMATORY LICENSE Recorded May 15, 2015
From: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 035704/0618 →
Continuity (2)
Provisional Application 61704857 · Sep 24, 2012
Related Publication 20140212084A1 · Jul 31, 2014
Cited By (2)
US 12,583,850 US 12,655,548