IP Library Granted Patent US 9,246,171
Granted Patent B2
US 9,246,171 · App. 14/050,459 · Granted Jan 26, 2016

Cathode active material, and cathode and lithium battery including the material

Inventors: Byung-jin Choi (Seoul, KR); Jae-gu Yoon (Suwon-si, KR); Myung-hoon Kim (Seoul, KR); Jin-hwan Park (Seoul, KR); David Keogh (San Diego, CA); Steven Kaye (San Diego, CA); Wei Tong (San Diego, CA)
Assignee: SAMSUNG SDI CO., LTD.
H01M4/505C01G53/50H01M4/525C01G45/1228C01G45/1235C01G51/50C01G51/54C01G53/54C01P2002/50C01P2002/52H01M4/131H01M10/0525Y02E60/122Y02T10/7011
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Quick Facts
Patent No.
US 9,246,171
App. No.
14/050,459
Granted
Jan 26, 2016
Kind
B2
Abstract

A cathode active material including a lithium metal oxide represented by Formula 1: Li[Li x Me y M′ z ]O (2+d)   Formula 1 wherein x+y+z=1, 0<x<0.33, 0<z≦0.1, and 0≦d≦0.1, Me is at least one metal selected from Mn, V, Cr, Fe, Co, Ni, Al, and B, and M′ is at least one metal selected from Sc, Y, and La.

Claims (26)

1. A cathode active material comprising a lithium metal oxide represented by Formula 1:

Li[Li x Me y M′ z ]O (2+d)   Formula 1

wherein

x+y+z=1, 0<x<0.33, 0<z≦0.1, and 0≦d≦0.1,

Me is at least one metal selected from Mn, V, Cr, Fe, Co, Ni, Al and B, and

M′ is [at least one metal selected from] Sc[, and Y].

2. The cathode active material of claim 1 , wherein z satisfies the inequality 0.005≦z≦0.05.

3. The cathode active material of claim 1 , wherein Me comprises:

at least one metal selected from V, Cr, Fe, Co, Ni, Al, and B; and

Mn.

4. The cathode active material of claim 1 , wherein an amount of Mn is in a range of about 20 to about 80 mole percent, based on a total number of moles of [Li x Me y M′ z ] in the lithium metal oxide of Formula 1.

5. The cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 3:

Li[Li x Ni a Co b Mn c M′ z ]O (2+d)   Formula 3

wherein x+a+b+c+z=1, 0<x<0.33, 0<z≦0.1,0<a≦0.5, 0<b≦0.5, 0.2≦c≦0.8, and 0≦d≦0.1, and

M′ is Sc [or Y].

6. The cathode active material of claim 5 , wherein z satisfies the inequality 0.005≦z≦0.05.

7. The cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 4:

Li[Li x Ni a Co b Mn c M′ z ]O (2+d)   Formula 4

wherein x+a+b+c+z=1, 0.1<x<0.2, 0<z≦0.1,0<a≦0.3, 0<b≦0.3, 0.4≦c≦0.6, and 0≦d≦0.1, and

M′ is Sc [or Y].

8. The cathode active material of claim 7 , wherein z satisfies the condition of 0.005≦z≦0.05.

9. The cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 5:

Li[Li x Ni a Co b Mn c Sc z ]O (2+d)   Formula 5

wherein x+a+b+c+z=1, 0.1<x<0.2, 0.005≦z≦0.1, 0<a≦0.3, 0<b≦0.3, 0.4≦c≦0.6, and 0≦d≦0.1.

10. A cathode comprising the cathode active material of claim 1 .

11. A lithium battery comprising the cathode of claim 10 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 18, 2015
From: SAMSUNG FINE CHEMICALS CO., LTD
To: SAMSUNG SDI CO., LTD
Reel/Frame 036599/0620 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 10, 2013
From: CHOI, BYUNG-JIN; YOON, JAE-GU; KIM, MYUNG-HOON; PARK, JIN-HWAN; KEOGH, DAVID; KAYE, STEVEN; TONG, WEI
To: SAMSUNG SDI CO., LTD.; SAMSUNG FINE CHEMICALS CO., LTD.
Reel/Frame 031395/0021 →
Priority Claims (1)
KR 10-2012-0113041 · Oct 11, 2012 · national
Continuity (1)
Related Publication 20140103252A1 · Apr 17, 2014