IP Library › Granted Patent US 9,722,083
Granted Patent B2
US 9,722,083 · App. 14/056,711 · Granted Aug 1, 2017

Source/drain junction formation

Inventors: Chun Hsiung Tsai (Xinpu Township, TW); Sheng-Wen Yu (New Taipei, TW); Ziwei Fang (Baoshan Township, TW)
Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
H01L29/785H01L21/26506H01L21/26513H01L29/0847H01L29/165H01L29/66636H01L29/66795H01L29/66803H01L29/665
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,722,083
App. No.
14/056,711
Granted
Aug 1, 2017
Kind
B2
Abstract

An embodiment method of forming a source/drain region for a transistor includes forming a recess in a substrate, epitaxially growing a semiconductor material in the recess, amorphizing the semiconductor material, and doping the semiconductor material to form a source/drain region. In an embodiment, the doping utilizes either phosphorus or boron as the dopant. Also, the amorphizing and the doping may be performed simultaneously. The amorphizing may be performed at least in part by doping with helium.

Claims (45)

1. A method of forming a source/drain region for a transistor, comprising:

forming a first recess in a substrate;

epitaxially growing a first semiconductor material in the first recess;

performing a first plasma implant comprising a pre-amorphization implant to the first semiconductor material;

following the first plasma implant, performing a second plasma doping comprising doping the first semiconductor material with phosphorus to form a first ultra-shallow junction in a first source/drain region, wherein the second plasma doping of the phosphorous is performed at a continuously decreasing energy level;

after the second plasma doping, forming a silicide layer over the first source/drain region; and

performing a microwave anneal on the first source/drain region at a first temperature between 300 and 600 degrees Celsius, wherein the microwave anneal substantially repairs damaged portions of a crystalline structure of the first source/drain region, wherein a concentration of the phosphorus at the first ultra-shallow junction is between about 2.0×10 21 atoms per centimeter cubed and about 4.0×10 21 atoms per centimeter cubed at a junction depth of about 8 to 10 nanometers.

2. The method of claim 1 , wherein the pre-amorphization implant is performed at least in part by implanting helium into the first semiconductor material.

3. The method of claim 1 , wherein the first semiconductor material comprises silicon phosphorous having a phosphorous concentration of less than about 1×10 20 atoms per centimeter cubed to about 7×10 20 atoms per centimeter cubed.

4. The method of claim 1 , wherein a collective process time of the first plasma implant and the second plasma doping is less than about thirty seconds.

5. The method of claim 1 , wherein the first plasma implant includes implanting helium at a continuously decreasing energy level.

6. The method of claim 1 , wherein a part of the first ultra-shallow junction is higher than a top surface of the substrate.

7. The method of claim 1 , wherein the microwave anneal uses free carrier absorption and dipole resonance heating.

8. The method of claim 1 , further comprising:

performing a third plasma doping/implant comprising doping a semiconductor material with boron simultaneously with implanting helium to form a second ultra-shallow junction in a second source/drain region, wherein the third plasma doping/implant is performed at a continuously decreasing energy;

after the third doping/implant, forming a second silicide over the second source/drain region; and

wherein a concentration of the boron in the second source/drain region beneath the second silicide is between about 3.0×10 15 atoms per centimeter cubed and about 1.0×10 16 atoms per centimeter cube at a depth of about 8 to 12 nanometers, and wherein an abruptness of boron at the second ultra-shallow junction is less than about 0.5 nanometers per decade.

9. The method of claim 1 , wherein the continuously decreasing energy level of the second plasma doping is in a range of about 6 kiloelectron-volts (keV) to about 4 kiloelectron-volts (keV), wherein a decreasing phosphorous concentration of 5.0×10 18 atoms per centimeter cube is between a depth of about 25 and 28 nm, wherein an abruptness of the decreasing concentration is about 5.5 to about 7.5 nanometers per decade, and wherein a resistance of the first source/drain region is reduced between about 30% to about 70%.

10. A method of forming a source/drain region for a transistor, comprising:

forming a recess in a substrate;

epitaxially growing a semiconductor material in the recess;

performing a doping of the semiconductor material with boron simultaneously with an implant of helium using a simultaneous plasma doping/implant to form an ultra-shallow function in the source/drain region;

after the doping the semiconductor material, forming a silicide over the source/drain region; and

performing a microwave anneal on the source/drain region at a first temperature between 300 and 600 degrees Celsius to substantially repair a damaged crystalline structure of the source/drain region, wherein a part of the ultra-shallow junction is higher than a top surface of the substrate, wherein a concentration of the boron in the source/drain region beneath the silicide is between about 3.0×10 15 atoms per centimeter cubed and about 1.0×10 16 atoms per centimeter cube at a depth of about 8 to 12 nanometers, and wherein an abruptness of boron at the ultra-shallow junction is less than about 0.5 nanometers per decade.

11. The method of claim 10 , wherein semiconductor material comprises silicon germanium boron (SiGeB).

12. The method of claim 10 , wherein the doping utilizes B 2 H 6 and a dose of the boron is about 4.5×10 16 atoms per centimeter squared.

13. The method of claim 10 , wherein the simultaneous plasma doping/implant comprises utilizing about 0.5% B 2 H 6 and about 99.5% helium.

14. The method of claim 10 , wherein a process time of the plasma doping/implant is less than fifteen seconds.

15. A method of forming a source/drain region for a transistor, comprising:

forming first recesses adjacent a first dummy gate in a substrate;

forming second recesses adjacent a second dummy gate in the substrate;

epitaxially growing a first semiconductor material in the first recesses;

epitaxially growing a second semiconductor material in the second recesses;

after the epitaxially growing the first semiconductor material, performing a pre-amorphization implant of the first semiconductor material using a first plasma helium implant;

after the performing the pre-amorphization implant, doping the first semiconductor material with an n-type dopant using a second plasma doping to form first source/drain regions, the first source/drain regions having ultra-shallow junctions, wherein the second plasma doping is performed at a continuously decreasing energy in a range of about 6 kiloelectron-volts (keV) to about 4 kiloelectron-volts (keV) during the second plasma doping, wherein a part of each of the ultra-shallow junctions is higher than a top surface of the substrate;

after the second plasma doping, forming a silicide over the first source/drain regions;

performing an anneal on the first source/drain region to substantially repair a damaged crystalline structure of the first source/drain regions;

after the epitaxially growing the second semiconductor material, doping the second semiconductor material with a p-type dopant and simultaneously implanting helium using a third plasma doping/implanting to form second source/drain regions, the second source/drain regions having ultra-shallow junctions;

after the simultaneous doping/implanting, forming a silicide over the second source/drain regions; and

performing an anneal on the second source/drain regions to substantially repair a damaged crystalline structure of the second source/drain regions.

16. The method of claim 15 , wherein the first plasma helium implant is performed at least in part by continuously decreasing an energy level during the first plasma implant and wherein a concentration of helium of the helium implant is about 1.0×10 16 to about 2.0×10 16 atoms per centimeter cubed.

17. The method of claim 15 , wherein the second semiconductor material comprises silicon germanium boron (SiGeB).

18. The method of claim 15 , wherein the anneal is a a microwave anneal using free carrier absorption and dipole resonance heating.

19. The method of claim 15 , wherein a concentration of boron in the first source/drain region beneath the silicide is between about 3.0×10 15 atoms per centimeter cubed and about 1.0×10 16 atoms per centimeter cube at a depth of about 8 to 12 nanometers, and wherein an abruptness of boron at the ultra-shallow junctions is less than about 0.5 nanometers per decade.

20. The method of claim 15 , wherein a peak doping concentration of phosphorous in the first source/drain region beneath the silicide is between about 2.0×10 21 atoms per centimeter cubed and about 4.0×10 21 atoms per centimeter cube at a depth of about 8 to 10 nanometers, wherein a decreasing phosphorous concentration of 5.0×10 18 atoms per centimeter cube is between a depth of about 25 and 28 nm, and wherein an abruptness of the decreasing phosphorous concentration is about 5.5 to about 7.5 nanometers per decade.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 23, 2013
From: TSAI, CHUN HSIUNG; YU, SHENG-WEN; FANG, ZIWEI
To: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD. (TSMC)
Reel/Frame 031459/0169 →
Continuity (1)
Related Publication 20150111359A1 · Apr 23, 2015