PVP copolymer for harsh chemical packaging
A water soluble film useful in unit-dose chemical packaging is disclosed. The film may include: a water soluble saccharide and a polyvinyl alcohol copolymer consisting essentially of: (a) from 80 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and (b) from 1 to 20 mole percent of a pyrrolidone comonomer. Such compositions may be used to provide a water-soluble film simultaneously satisfying requirements in regard to water solubility, biodegradability, and physical properties, even when used for packaging of harsh, oxidizing chemicals.
1. A water-soluble film having stability with harsh chemicals, the film comprising:
a polyvinyl alcohol copolymer A consisting essentially of:
(a) from 95 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and
(b) from 1 to about 5 mole percent of a pyrrolidone comonomer;
a polyvinyl alcohol copolymer B comprising:
(a) from 94 to 99 mole percent of vinyl alcohol and vinyl ester monomer; and
(b) from 1 to 6 mole percent of a comonomer comprising sulfonic acid groups; and
at least one water-soluble monosaccharide having a solubility in water at 25° C. of at least 0.1 moles per liter;
wherein the water-soluble film comprises from about 20 wt % to about 30 wt % copolymer A and from about 70 wt % to about 80 wt % copolymer B, based on a total amount of copolymers A and B.
2. The film of claim 1 , wherein the film has a % dissolution in water at 21° C. of at least 85% following exposure to an oxidizing chemical and aging at a temperature in the range from about 5° C. to about 54° C. for at least 4 weeks.
3. The film of claim 1 , wherein the film exhibits essentially no yellowing when exposed to an oxidizing chemical and aged at a temperature in the range from about 5° C. to about 54° C. for at least 4 weeks.
4. The film of claim 1 , wherein the polyvinyl alcohol copolymer A contains from 4 to about 5 mole percent of the pyrrolidone comonomer.
5. The film claim 1 , wherein the pyrrolidone comonomer comprises N-vinyl pyrrolidone.
6. The film of claim 1 , wherein the film comprises from about 1 to about 10 weight percent of the water-soluble saccharide.
7. The film of claim 1 , wherein the at least one water-soluble monosaccharide comprises dextrose.
8. The film of claim 1 , further comprising at least one of a plasticizer, a bromine scavenger, and a chlorine scavenger.
9. The film of claim 1 , further comprising at least one of polyethylene glycol, glycerine, ammonium chloride, citric acid, trimethylol propane, alkoxylated trimethylol propane, potassium bicarbonate, and ammonium chloride, polypropylene glycol, starch, and sodium bisulfite.
10. The film of claim 1 , wherein the comonomer comprising sulfonic acid groups comprises 2-acrylamido-2-methylpropanesulfonic acid.
11. A unit dose package comprising:
a polymeric dissolution packet comprising the film of claim 1 ; and
a chemical sealed in the polymeric dissolution packet.
12. The unit dose package of claim 11 , wherein the chemical comprises at least one of a peroxide, a nitrate, a nitrite, a chromate, a persulfate, a borate, a bromate, a chlorate, a periodate, a chlorite, a chlorinated or brominated isocyanurate, an inorganic acid, a peroxy acid, bromine, chorine, iodine, fluorine, potassium superoxide, and salts and hydrates of these compounds.
13. The unit dose package of claim 11 , wherein the polymeric dissolution packet comprises:
from 60 to 95 weight percent of the polyvinyl alcohol copolymer;
from 1 to 40 weight percent dextrose; and
from 0 to 5 weight percent polyethylene glycol.
14. The unit dose package of claim 13 , wherein the chemical comprises at least one of dichloroisocyanuric acid, trichloroisocyanuric acid, and calcium hypochlorite.
15. The unit dose package of claim 11 , wherein the polymeric dissolution packet comprises:
from 60 to 95 weight percent of the polyvinyl alcohol copolymer;
from 1 to 40 weight percent dextrose; and
from 0 to 15 weight percent of at least one of trimethylol propane and alkoxylated trimethylol propane.
16. The unit dose package of claim 15 , wherein the polymeric dissolution packet further comprises from 0.5 to 3 weight percent of at least one of ammonium chloride, citric acid, potassium bicarbonate, starch, and sodium bisulfite.
17. The unit dose package of claim 15 , wherein the polymeric dissolution packet further comprises from 0.5 to 10 weight percent glycerine.
18. The unit dose package of claim 15 , wherein the oxidizing chemical comprises at least one of 1 -bromo-3 -chloro-5 ,5 -dimethylhydantoin, 2-bromo-2-nitro-1,3-propanediol, 1,3 -dibromo-5,5-dimethylhydantoin, 2,3-dibromo-3-nitrilopropionamide, and dibromocyano acetic acid amide.