Insulating silicone rubber composition
An insulating silicone rubber composition superior in reliability is provided that has excellent antistatic property while being free from bleeding, blooming, and discoloration. The insulating silicone rubber contains silicone rubber, ionic liquid having an alkoxysilyl group, and preferably a crosslinking agent. The content of the ionic liquid is preferably within a range from 0.001 to 5 parts by mass with respect to 100 parts by mass of the total amount of the silicone rubber and the crosslinking agent.
1. An insulating silicone rubber composition, comprising:
a silicone rubber; and
an ionic liquid compound that comprises a heterocycle that comprises a nitrogen cation, and has an —R 2 —Si(OR 3 ) 3 group bonded to the nitrogen atom, where R 2 is a group comprising at least (CH 2 ) n , wherein n represents an integer number; and R 3 is an alkyl group.
2. The insulating silicone rubber composition according to claim 1 having a volume resistivity of 1×10 10 Ω·cm or more.
3. The insulating silicone rubber composition according to claim 1 , wherein the heterocycle is at least one selected from pyrrole, pyrrolidine, imidazole, pyridine, pyrimidine, indole, quinoline, isoquinoline and purine rings.
4. The insulating silicone rubber composition according to claim 1 further comprising a crosslinking agent.
5. The insulating silicone rubber composition according to claim 1 , wherein the heterocycle that comprises the nitrogen cation comprises at least one selected from pyridine, methylpyridine, N-methylpiperidine and N-methylmorpholine.
6. The insulating silicone rubber composition according to claim 1 , wherein R 2 further comprises a functional group selected from urethane, ester, amide, amino, thioether, hydroxyl groups and an aromatic ring.
7. The insulating silicone rubber composition according to claim 4 , wherein the content of the ionic liquid is within a range from 0.001 to 5 parts by mass with respect to 100 parts by mass of the total amount of the silicone rubber and the crosslinking agent.
8. The insulating silicone rubber composition according to claim 4 , wherein the content of the ionic liquid is within a range from 0.01 to 1 parts by mass with respect to 100 parts by mass of the total amount of the silicone rubber and the crosslinking agent.
9. The insulating silicone rubber composition according to claim 8 , having a volume resistivity of 1×10 11 Ω·cm or more.
10. The insulating silicone rubber composition according to claim 1 , wherein the ionic liquid comprises one or more anions selected from AlCl 4 —, Al 2 Cl 7 —, NO 3 —, BF 4 —, PF 6 —, CH 3 COO—, CF 3 COO—, CF 3 SO 3 —, (CF 3 SO 2 ) 3 C—, AsF 6 —, SbF 6 —, F(HF)n-, CF 3 CF 2 CF 2 CF 2 SO 3 —, (CF 3 CF 2 SO 2 ) 2 N—, CF 3 CF 2 CF 2 COO— and (CF 3 SO 2 ) 2 N—.
11. The insulating silicone rubber composition according to claim 1 , wherein the ionic liquid comprises an anion consisting of (CF 3 SO 2 ) 2 N—.
12. An insulating silicone rubber composition, comprising:
a silicone rubber; and
an ionic liquid compound that comprises a structure by formula (2);
wherein R 2 is a group comprising at least (CH 2 ) n , wherein n represent an integer number; R 3 is an alkyl group, R 4 is an aliphatic hydrocarbon group having 1 to 18 carbon atoms; and R 5 and R 6 are alkyl groups each having 1 to 4 carbon atoms,
wherein R 2 further comprises a functional group selected from urethane, ester, amide, amino, thioether, hydroxyl groups and an aromatic ring.
13. The insulating silicone rubber composition according to claim 12 having a volume resistivity of 1×10 10 Ω·cm or more.
14. The insulating silicone rubber composition according to claim 12 , further comprising a crosslinking agent.
15. The insulating silicone rubber composition according to claim 14 , wherein the content of the ionic liquid is within a range from 0.001 to 5 parts by mass with respect to 100 parts by mass of the total amount of the silicone rubber and the crosslinking agent.
16. The insulating silicone rubber composition according to claim 14 , wherein the content of the ionic liquid is within a range from 0.01 to 1 parts by mass with respect to 100 parts by mass of the total amount of the silicone rubber and the crosslinking agent.
17. The insulating silicone rubber composition according to claim 16 , having a volume resistivity of 1×10 11 Ω·cm or more.
18. The insulating silicone rubber composition according to claim 12 , wherein R 4 , R 5 and R 6 are methyl groups.
19. The insulating silicone rubber composition according to claim 12 , wherein the ionic liquid comprises one or more anions selected from AlCl 4 —, Al 2 Cl 7 —, NO 3 —, BF 4 —, PF 6 —, CH 3 COO—, CF 3 COO—, CF 3 SO 3 —, (CF 3 SO 2 ) 3 C—, AsF 6 —, SbF 6 —, F(HF)n-, CF 3 CF 2 CF 2 CF 2 SO 3 —, (CF 3 CF 2 SO 2 ) 2 N—, CF 3 CF 2 CF 2 COO— and (CF 3 SO 2 ) 2 N—.
20. The insulating silicone rubber composition according to claim 12 , wherein the ionic liquid comprises an anion consisting of (CF 3 SO 2 ) 2 N—.