Methods of forming phase change materials and methods of forming phase change memory circuitry
View Patent ↗A method of forming a phase change material which having germanium and tellurium therein includes depositing a germanium-containing material over a substrate. Such material includes elemental-form germanium. A gaseous tellurium-comprising precursor is flowed to the germanium-comprising material and tellurium is removed from the gaseous precursor to react with the elemental-form germanium in the germanium-comprising material to form a germanium and tellurium-comprising compound of a phase change material over the substrate. Other implementations are disclosed.
1. A method of depositing a tellurium-comprising phase change material onto a substrate, comprising:
forming a monolayer comprising Te(OR) t onto a substrate from gaseous Te(OR) 4 , where R is alkyl and t is less than 4; and
providing a reducing agent to the monolayer to remove (OR) t ligand from the Te and forming there-from a tellurium-comprising phase change material on the substrate, the phase change material having no greater than 10 atomic percent oxygen and comprising another metal in addition to tellurium.
2. The method of claim 1 wherein the providing produces the phase change material to have no greater than 5 atomic percent oxygen.
3. The method of claim 1 wherein the providing produces the phase change material to have no greater than 1 atomic percent oxygen.
4. The method of claim 1 wherein the providing produces the phase change material to have no detectable oxygen therein.
5. The method of claim 1 wherein the reducing agent comprises at least one of NH 3 , H 2 , CH 2 O, and CH 2 O 2 .
6. The method of claim 5 wherein the reducing agent comprises NH 3 .
7. The method of claim 1 wherein the another metal comprises Ge.
8. The method of claim 1 wherein the another metal comprises Ge and Sb.
9. The method of claim 1 comprising forming the monolayer to also comprise Te(OR) w Q z from gaseous Te(OR) x Q y , where Q is a halogen, x is less than 4, and y is 4−x; and where at least one of w is less than x, or z is less than y.
10. A method of forming phase change memory circuitry, comprising:
forming inner electrode material over a substrate;
forming phase change material over the inner electrode material, the forming of phase change material comprising:
forming a monolayer comprising Te(OR) t onto a substrate from gaseous Te(OR) 4 , where R is alkyl and t is less than 4; and
providing a reducing agent to the monolayer to remove (OR) t ligand from the Te and forming there-from a tellurium-comprising phase change material on the substrate, the tellurium-comprising phase change material having no greater than 10 atomic percent oxygen and comprising another metal in addition to tellurium; and
forming outer electrode material over the tellurium-comprising phase change material.
11. The method of claim 10 comprising forming the monolayer to also comprise Te(OR) w Q z from gaseous Te(OR) x Q y , where Q is a halogen, x is less than 4, and y is 4−x; and where at least one of w is less than x, or z is less than y.
12. A method of depositing a tellurium-comprising phase change material onto a substrate, comprising:
forming a monolayer comprising Te(OR) w Q z onto a substrate from gaseous Te(OR) x Q y , where R is alkyl, Q is a halogen, x is less than 4, and y is 4−x; and where at least one of w is less than x, or z is less than y; and
providing a reducing agent to the monolayer to remove (OR) w ligand and Q from the Te and forming there-from a tellurium-comprising phase change material on the substrate, the phase change material having no greater than 10 atomic percent oxygen and comprising another metal in addition to tellurium.
13. The method of claim 12 wherein both of w is less than x and z is less than y.
14. The method of claim 12 wherein only one of w is less than x and z is less than y.
15. The method of claim 14 wherein w is less than x.
16. The method of claim 14 wherein z is less than y.
17. A method of forming phase change memory circuitry, comprising:
forming inner electrode material over a substrate;
forming phase change material over the inner electrode material, the forming of phase change material comprising:
forming a monolayer comprising Te(OR) w Q z onto a substrate from gaseous Te(OR) x Q y , where R is alkyl, Q is a halogen, x is less than 4, and y is 4−x; and where at least one of w is less than x, or z is less than y; and
providing a reducing agent to the monolayer to remove (OR) w ligand and Q from the Te and forming there-from a tellurium-comprising phase change material on the substrate, the tellurium-comprising phase change material having no greater than 10 atomic percent oxygen and comprising another metal in addition to tellurium; and
forming outer electrode material over the tellurium-comprising phase change material.