Effect of Support Oxides on Optimal Performance and Stability of ZPGM Catalyst Systems
The present disclosure relates to selecting support oxide for ZPGM catalyst for optimal performance under TWC condition, for achieving enhanced catalyst activity, and improved thermal stability during aging. The selected active phase material may include a chemical composition that is substantially free from PGM, including a formulation of stoichiometric Cu—Mn spinel structure active phase with Niobium-Zirconium support oxide, which may include a washcoat of pure alumina coated on a suitable ceramic substrate. The disclosed Cu—Mn spinel structure active phase with Niobium-Zirconium support oxide may be applied in overcoat to maximize efficiency of ZPGM catalyst systems, which may exhibit enhanced catalytic activity properties that may increase with temperature, showing optimized performance purifying gases in TWC condition, and enhanced stability during aging.
1 . A catalytic composition, comprising:
stoichiometric Cu—Mn spinel; and
niobium-zirconia support oxide;
wherein the stoichiometric Cu—Mn spinel is in active phase and is calcined at about 600° C.
2 . The composition of claim 1 , wherein the niobium-zirconia support oxide has a general formula of N b 2 O 5 —ZrO 2 .
3 . The composition of claim 1 , wherein the niobium-zirconia support oxide provides a lower NO/CO cross over R value than Pr 6 O 11 —ZrO 2 support oxide.
4 . The composition of claim 3 , wherein the R value is about 1.20.
5 . The composition of claim 1 , wherein the niobium-zirconia support oxide provides a higher NO conversion rate than Pr 6 O 11 —ZrO 2 support oxide.
6 . The composition of claim 1 , wherein the niobium-zirconia support oxide provides a higher HC conversion rate than Pr 6 O 11 —ZrO 2 support oxide.
7 . The composition of claim 1 , wherein the stoichiometric Cu—Mn spinel is aged.
8 . The composition of claim 1 , wherein the catalytic composition is aged.
9 . The composition of claim 1 , wherein the niobium-zirconia support oxide is aged at 900° C.
10 . The composition of claim 9 , wherein the aging is hydrothermal aging.
11 . The composition of claim 9 , wherein the niobium-zirconia support oxide provides a higher NO conversion rate than Pr 6 O 11 —ZrO 2 support oxide.
12 . The composition of claim 1 , wherein the niobium-zirconia support oxide is aged at 1000° C.
13 . The composition of claim 12 , wherein the aging is hydrothermal aging.
14 . The composition of claim 12 , wherein the niobium-zirconia support oxide provides a higher NO conversion rate than Pr 6 O 11 —ZrO 2 support oxide.
15 . The composition of claim 1 , wherein the NO/CO conversion is about 98.7%.
16 . The composition of claim 1 , wherein the NO/HC conversion is about 66.5%.