Artificial polypeptide fiber and method for producing the same
An artificial polypeptide fiber of the present invention is an artificial fiber containing a polypeptide as a main component, and has a stress of 350 MPa or more and a toughness of 138 MJ/m 3 or more. A method for producing an artificial polypeptide fiber of the present invention is a method for producing the artificial polypeptide fiber obtained by spinning a spinning solution ( 6 ) containing a polypeptide derived from natural spider silk proteins and performing drawing of at least two stages. The drawing of at least two stages includes a first-stage drawing ( 3 ) in wet heat and a second-stage drawing ( 4 ) in dry heat. Thereby, the present invention provides high-toughness artificial polypeptide fibers having favorable stress and rupture elongation, and a method for producing the same.
1. A method for producing an artificial polypeptide fiber that is obtained by spinning a spinning solution containing a polypeptide derived from natural spider silk proteins and performing drawing of at least two stages, wherein the drawing of at least two stages includes a first-stage drawing in wet heat and a second-stage drawing in dry heat, and
an ambient temperature at the time of the second-stage drawing is in a range from 170 to 270° C.
2. The method for producing an artificial polypeptide fiber according to claim 1 , wherein drawing conditions for the first-stage drawing include a temperature of hot water of 70-90° C. and a draw ratio of 2 to 8 times.
3. The method for producing an artificial polypeptide fiber according to claim 1 , wherein drawing conditions for the second-stage drawing include an ambient temperature of 170 to 230° C. and a draw ratio of 1.25 to 3 times.
4. The method for producing an artificial polypeptide fiber according to claim 1 , wherein the spinning is performed by extruding the spinning solution containing a polypeptide in a coagulation liquid so as to obtain an undrawn yarn, and the undrawn yarn is subjected to the first-stage drawing in the coagulation liquid.
5. The method for producing an artificial polypeptide fiber according to claim 1 , wherein a total draw ratio of the fiber is more than 5 times and 20 times or less.
6. The method for producing an artificial polypeptide fiber according to claim 1 , wherein a draw ratio of the second-stage drawing is in a range from 1.25 to 3 times.