Method and apparatus for the removal of polyvalent cations from mono ethylene glycol
The invention relates to a method and an apparatus for the removal of polyvalent cations, in particular divalent cations, from mono ethylene glycol. Mono Ethylene Glycol (MEG) is used to prevent hydrate formation in pipelines transporting gas, condensate and water. It may also contribute to pipeline corrosion control. The invention describes a method for the removal of polyvalent cations from mono ethylene glycol, comprising providing a feed of aqueous mono ethylene glycol comprising dissolved gas and salts of divalent cations (rich MEG), heating the aqueous mono ethylene glycol to a heated mixture, causing precipitation of at least part of the salts and release of at least part of the dissolved gas, in particular carbon dioxide, separation of released gas from the mono ethylene glycol, separation of at least part of the precipitated salts from the mono ethylene glycol, distillation of at least part of the water from the heated mixture, to yield hot dewatered mono ethylene glycol (lean MEG), wherein a first part of the hot dewatered mono ethylene glycol is lead back to the aqueous mono ethylene glycol feed to provide at least part of the heat for heating the aqueous mono ethylene glycol.
1. A method for the removal of polyvalent cations from mono ethylene glycol, comprising the steps of:
a) providing a feed of aqueous mono ethylene glycol comprising dissolved carbon dioxide and salts of divalent cations,
b) heating the aqueous mono ethylene glycol to 60° C.-120° C. to produce a heated mixture, causing precipitation of at least part of the salts and release of at least part of the dissolved carbon dioxide,
c) separating the at least part of the released carbon dioxide from the mono ethylene glycol in a flash separator,
d) separating the at least part of the precipitated salts from the mono ethylene glycol, and
e) distilling at least part of the water from the aqueous heated mixture in a reboiler, to yield hot dewatered mono ethylene glycol, wherein the temperature of the liquid in the distillation phase is 120° C.-150° C.,
wherein a first part of the hot dewatered mono ethylene glycol comprising particles of salts of divalent cations is led back to the feed of aqueous mono ethylene glycol provided in step a) to provide at least part of the heat for heating the aqueous mono ethylene glycol in step b), and
wherein the separating of the at least part of the precipitated salts from the mono ethylene glycol in step d) is performed on a second part of the hot dewatered mono ethylene glycol that is not led back to the feed.
2. The method according to claim 1 , wherein the first part of the hot dewatered mono ethylene glycol led back to the feed has a temperature above 100° C.
3. The method according to claim 1 , wherein the amount of the first part of the hot dewatered mono ethylene glycol led back to the feed is controlled to obtain a heated mixture of aqueous mono ethylene glycol having a temperature in the range of 60° C.-120° C. in step b).
4. The method according to claim 1 , wherein in the distilling step e) the hot dewatered mono ethylene glycol is circulated in a distillation loop comprising at least one heater, wherein the first part of the hot dewatered mono ethylene glycol led back to the feed is taken from the distillation loop.
5. The method according to claim 4 , wherein the first part of the hot dewatered mono ethylene glycol is taken from the distillation loop after distillation and before the heater.
6. The method according to claim 4 , wherein the distillation loop further comprises a circulation pump, and wherein the first part of the hot dewatered mono ethylene glycol is taken from the distillation loop after the circulation pump and before the heater.
7. The method according to claim 1 , wherein the salts of polyvalent cations in the mono ethylene glycol are salts of at least one element selected from the group consisting of iron, calcium, barium, strontium and magnesium.
8. The method according to claim 7 , wherein the salts are predominantly iron salts.