IP Library Granted Patent US 10,714,271
Granted Patent B2
US 10,714,271 · App. 14/131,666 · Granted Jul 14, 2020

High temperature energy storage device

Inventors: Riccardo Signorelli (Boston, MA); John J. Cooley (Boston, MA); Christopher John Sibbald Deane (Boston, MA); James Epstein (Sharon, MA); Padmanaban Sasthan Kuttipillai (Malden, MA); Fabrizio Martini (Boston, MA); Lindsay A. Wilhelmus (Lexington, KY)
Assignee: FASTCAP SYSTEMS CORPORATION
H01G11/14H01G11/18H01G11/32H01G11/58H01G11/60H01G11/78H01G11/84Y02E60/13
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Quick Facts
Patent No.
US 10,714,271
App. No.
14/131,666
Granted
Jul 14, 2020
Kind
B2
Abstract

An ultracapacitor that includes an energy storage cell immersed in an electrolyte and disposed within an hermetically sealed housing, the cell electrically coupled to a positive contact and a negative contact, wherein the ultracapacitor is configured to output electrical energy within a temperature range between about 80 degrees Celsius to about 210 degrees Celsius. Methods of fabrication and use are provided.

Claims (20)

1. An ultracapacitor comprising:

a positive electrode,

a negative electrode,

a separator, and

an electrolyte within a hermetically sealed housing,

wherein the ultracapacitor has less than 200 ppm of halides and a water content of less than 100 ppm,

wherein the ultracapacitor exhibits an equivalent series resistance (ESR) increase of less than about 300 percent while held at a constant voltage for at least 20 hours while held at a substantially constant temperature within a temperature range of between about 80 degrees Celsius and 210 degrees Celsius, and

wherein:

the ultracapacitor is configured to operate at a temperature between 80 degrees Celsius and 210 degrees Celsius with a volumetric leakage current of less than 1,000 mAmp per Liter, and/or

the ultracapacitor exhibits a volumetric leakage current of less than 10 mA/cc while held at a substantially constant temperature between 100 degrees Celsius and 150 degrees Celsius.

2. The ultracapacitor of claim 1 , wherein the ESR increase is less than about 100 percent.

3. The ultracapacitor of claim 1 , wherein at least one of the positive electrode and the negative electrode comprises a carbonaceous energy storage media comprising at least one of activated carbon, carbon fibers, rayon, graphene, aerogel, carbon cloth, and carbon nanotubes.

4. The ultracapacitor of claim 1 , wherein the electrolyte comprises an ionic liquid comprising:

a cation selected from the group consisting of ammonium cations, imidazolium cations, functionalized imidazolium cations, oxazolium cations, phosphonium cations, piperidinium cations, pyrazinium cations, pyrazolium cations, pyridazinium cations, pyridinium cations, pyrimidinium cations, pyrrolidinium cations, sulfonium cations, thiazolium cations, triazolium cations, guanidium cations, isoquinolinium cations, benzotriazolium cations, and viologen-type cations; and

an anion selected from the group consisting of bis(trifluoromethanesulfonate)imide, tris(trifluoromethanesulfonate)methide, dicyanamide, tetra-fluoroborate, hexafluorophosphate, trifluoromethanesulfonate, bis(pentafluoroethanesulfonate)-imide, thiocyanate, and trifluoro(trifluoromethyl)borate.

5. The ultracapacitor of claim 4 , wherein the electrolyte further comprises a solvent selected from the group consisting of acetonitrile, amides, benzonitrile, butyrolactone, cyclic ether, diethylether, dimethoxyethane, dimethylformamide, dimethylsulfone, dioxane, dioxolane, ethyl formate, ethylene carbonate, ethylmethyl carbonate, dimethyl carbonate, diethyl carbonate, propylene carbonate, dibutyl carbonate, lactone, methyl formate, methyl propionate, methyltetrahydrofuran, tetrahydrofuran, nitrobenzene, nitromethane, N-methylpyrrolidone, sulfolane, tetramethylene sulfone, thiophene, ethyleneglycol, diethylene glycol, triethylene glycol, polyethylene glycols, carbonic acid ester, γ-butyrolactone, and tricyanohexane.

6. The ultracapacitor of claim 1 , wherein the hermetically sealed housing exhibits a leakage rate of helium that is between about 10 −5 standard He cc/second and about 10 −9 standard He cc/second.

7. The ultracapacitor of claim 1 , wherein the hermetically sealed housing exhibits a leakage rate of helium that is between about 10 −7 standard He cc/second and about 10 −10 standard He cc/second.

8. The ultracapacitor of claim 1 , wherein the temperature range is between about 100 degrees Celsius and about 210 degrees Celsius.

9. The ultracapacitor of claim 1 , wherein the temperature range is between about 150 degrees Celsius and about 210 degrees Celsius.

Assignments (8)
SECURITY INTEREST Recorded Dec 9, 2024
From: FASTCAP ULTRACAPACITORS LLC
To: WINDSAIL CAPITAL FUND, L.P.
Reel/Frame 069547/0440 →
CHANGE OF NAME Recorded Dec 4, 2024
From: FASTCAP SYSTEMS CORPORATION
To: FASTCAP ULTRACAPACITORS LLC
Reel/Frame 069495/0394 →
TERMINATION OF SECURITY AGREEMENT Recorded Dec 4, 2024
From: WINDSAIL CAPITAL FUND, L.P.
To: FASTCAP SYSTEMS CORPORATION; BR CHROM LLC
Reel/Frame 070946/0799 →
SECURITY INTEREST Recorded Oct 18, 2022
From: FASTCAP SYSTEMS CORPORATION
To: WINDSAIL CREDIT FUND, L.P.
Reel/Frame 062738/0152 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2019
From: WILHELMUS, LINDSAY A.
To: FASTCAP SYSTEMS CORPORATION
Reel/Frame 050772/0163 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 25, 2018
From: SIGNORELLI, RICCARDO; COOLEY, JOHN J.; DEANE, CHRISTOPHER JOHN SIBBALD; EPSTEIN, JAMES; KUTTIPILLAI, PADMANABAN SASTHAN; MARTINI, FABRIZIO
To: FASTCAP SYSTEMS CORPORATION
Reel/Frame 045634/0317 →
CONFIRMATORY LICENSE Recorded Oct 19, 2017
From: FASTCAP SYSTEMS CORPORATION
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 043899/0268 →
SECURITY INTEREST Recorded Mar 24, 2014
From: FASTCAP SYSTEMS CORPORATION; BR CHROM LLC
To: WINDSAIL CREDIT FUND, L.P., AS AGENT
Reel/Frame 032508/0072 →
Continuity (7)
Provisional Application 61505715 · Jul 8, 2011
Provisional Application 61512090 · Jul 27, 2011
Provisional Application 61560888 · Nov 17, 2011
Provisional Application 61569010 · Dec 9, 2011
Provisional Application 61602713 · Feb 24, 2012
Provisional Application 61619203 · Apr 2, 2012
Related Publication 20150002987A1 · Jan 1, 2015
Cited By (3)
US 12,406,815 US 12,633,486 US 12,695,094