Thermoplastic toughening material and related method
View Patent ↗A non-fibrous, apertured membrane comprises at least one thermoplastic polymeric material and has a discrete porous structure. The membrane is soluble in the thermoset matrix polymer of a composite material.
1. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material, said method comprising the steps of:
a) dissolving polyethersulfone or polyetherimide in a solvent to form a solution of thermoplastic polymer;
b) dispersing said polyamide particles or copolyamide particles in said solution of thermoplastic polymer to form a dope solution;
c) casting said dope solution onto a substrate surface, said substrate surface being stippled to provide a plurality of discrete embossed areas;
d) removing a portion said dope solution from said substrate surface to expose said plurality of discrete embossed areas to form an openwork film of said dope solution, said openwork film having discrete openings therein which match said discrete embossed areas;
e) removing the solvent from said openwork film to form an openwork membrane comprising said polyamide particles or copolyamide particles dispersed in said polyethersulfone or polyetherimide; and
f) locating said openwork membrane on the surface of said fibrous layer to thereby locate said polyamide particles or copolyamide particles on the surface of said fibrous layer.
2. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 wherein said solvent is removed from said openwork film by washing.
3. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 wherein said composite material comprises a thermosetting resin selected from the group consisting of epoxy resins and bismaleimide resins.
4. A method for locating polyamide particles or copolyamide on the surface of a fibrous layer of a composite material according to claim 1 wherein said dope solution comprises an insoluble moiety selected from the group consisting of toughening particles, intumescents, pigments, mould release agents, nano-sized particles and conducting particles.
5. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 2 wherein said openwork film is washed with water to remove said solvent.
6. A method for locating polyamide articles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 3 wherein said dope solution comprises an insoluble moiety selected from the group consisting of toughening particles, intumescents, pigments, mould release agents, nano-sized particles and conducting particles.
7. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 wherein said solvent comprises a liquid selected from the group consisting of dimethyl sulfoxide, dimethyl formamide, dimethylacetamide, N-methylpyrrolidone, tetramethylurea, gamma-butyrolactone, propylene carbonate and ethylene carbonate.
8. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 which includes the step of adding a soluble additive to said solvent, said soluble additive being selected from the group consisting of lithium chloride, potassium chloride, calcium chloride, sodium acetate and sodium dodecylsulfate.
9. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 8 wherein said soluble additive is dissolved in water prior to being added to said solvent.
10. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 9 wherein said solvent comprises N-methylpyrrolidone and soluble additive is lithium chloride.
11. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 9 wherein said solvent comprises dimethylsulfoxide and said soluble additive is calcium chloride.
12. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 wherein said fibrous layers comprise fibers selected from the group consisting of aramid fibers, glass fibers, carbon fibers, hemp fibers and polyolefin fibers.
13. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 3 wherein said fibrous layers comprise carbon fibers.
14. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 wherein said discrete openings in said openwork membrane make up from 5 to 50 percent of the surface area of said openwork membrane.
15. A method for locating polyamide particles or copolyamide particles on the surface of a fibrous layer of a composite material according to claim 1 wherein the areal weight of said openwork membrane is from 3 to 50 grams per square meter.