Biomass pre-treatment for co-production of high-concentration C5- and C6-carbohydrates and their derivatives
Described is a method of processing biomass to separate it into a liquid fraction enriched in solubilized C5-sugar-containing oligomers and C-5 sugar monomers and a solid fraction enriched in substantially insoluble cellulose and C6-sugar-containing oligomers. The method includes the steps of reacting biomass with a solvent system comprising water, at least one lactone, or at least one furan, or at least one cyclic ether, and at least one acid, for a time and at a temperature to yield the liquid and solid fractions. The liquid and solid fractions may then be separated. Gamma-valeroloactone is a preferred lactone for use in the solvent system. Tetrahydrofuran is a preferred furan species for use in the solvent system.
1. A method of processing biomass, the method comprising reacting biomass with a solvent system comprising water, at least one acid selected from the group consisting of mineral acids and heterogeneous acids, and at least one organic compound selected from a lactone, for a time and at a temperature to yield a liquid fraction enriched in solubilized C5-sugar-containing oligomers and C-5 sugar monomers and a solid fraction enriched in substantially insoluble cellulose and C6-sugar-containing oligomers.
2. The method of claim 1 , further comprising separating the liquid fraction from the solid fraction.
3. The method of claim 1 , wherein the solvent system comprises (i) a lactone selected from the group consisting of beta-, gamma-, and delta-lactones, and combinations thereof, and (ii) at least about 5 wt % water.
4. The method of claim 1 , wherein the lactone is gamma-valerolactone (GVL).
5. The method of claim 1 , wherein the at least one organic compound is present in a mass ratio with water of about 70:30 to about 95:5.
6. The method of claim 1 , wherein the at least one acid is heterogeneous.
7. The method of claim 1 , wherein the at least one acid is a mineral acid.
8. The method of claim 1 , wherein the at least one acid is present in the solvent system in concentration sufficient to yield a [H + ] concentration selected from the group consisting of about 0.05M to about 0.5M.
9. The method of claim 1 , wherein the biomass is present in a concentration range selected from the group consisting of from about 5 wt % to about 70 wt %, based on the total weight of the biomass and solvent system.
10. The method of claim 1 , wherein the biomass and the solvent system are reacted at a temperature of from about 90° C. to about 250° C. and for a time of from about 1 minute to about 24 hours.
11. The method of claim 10 , wherein the biomass and the solvent system are reacted at a single temperature, a dynamic temperature range or a combination thereof.
12. The method of claim 11 , wherein the dynamic temperature range ramps from a first temperature to a second temperature that is higher than the first temperature.
13. The method of claim 11 , wherein the dynamic temperature range changes from a first temperature to a second temperature in a non-linear fashion or a linear fashion.
14. A method of processing biomass, the method comprising reacting biomass with a solvent system comprising water, a mineral acid, and gamma-valerolactone (GVL), for a time of from about 1 min to about 12 hrs, and at a temperature of from about 100° C. to about 200° C., wherein the reaction yields a liquid fraction enriched in solubilized C5-sugar-containing oligomers and C-5 sugar monomers and a solid fraction enriched in substantially insoluble cellulose and C6-sugar-containing oligomers.
15. The method of claim 14 , further comprising separating the liquid fraction from the solid fraction.
16. The method of claim 14 , wherein the solvent system comprises water, a mineral acid, and GVL, wherein the GVL is present in a mass ratio with water of about 70:30 to about 95:5.
17. The method of claim 14 , wherein the at least one acid is present in the solvent system in a concentration sufficient to yield a [H + ] concentration of about 0.05M to about 0.5M.
18. The method of claim 14 , wherein the biomass is present in a concentration ranging from about 5 wt % to about 70 wt % based on the total weight of the biomass and solvent system.
19. The method of claim 14 , comprising reacting the biomass with the solvent system for about 1 min to about 1 hr, and at a temperature of from about 100° C. to about 140° C.
20. The method of claim 14 , wherein the biomass is present in a concentration range from about 5 wt % to about 50 wt %, based on the total weight of the biomass and solvent system.