IP Library Granted Patent US 9,305,677
Granted Patent B2
US 9,305,677 · App. 14/148,508 · Granted Apr 5, 2016

Boron nitride converted carbon fiber

Inventors: Michael Rousseas (Burlingame, CA); William Mickelson (Albany, CA); Alexander K. Zettl (Kensington, CA)
Assignee: The Regents of the University of California
H01B1/04D01F8/18D01F11/124
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Quick Facts
Patent No.
US 9,305,677
App. No.
14/148,508
Granted
Apr 5, 2016
Kind
B2
Abstract

This disclosure provides systems, methods, and apparatus related to boron nitride converted carbon fiber. In one aspect, a method may include the operations of providing boron oxide and carbon fiber, heating the boron oxide to melt the boron oxide and heating the carbon fiber, mixing a nitrogen-containing gas with boron oxide vapor from molten boron oxide, and converting at least a portion of the carbon fiber to boron nitride.

Claims (29)

1. A method comprising:

(a) providing boron oxide and carbon fiber, the carbon fiber having a circular cross-section;

(b) heating the boron oxide to melt the boron oxide and heating the carbon fiber;

(c) mixing a nitrogen-containing gas with boron oxide vapor from molten boron oxide; and

(d) converting a portion of the carbon fiber proximate a perimeter of the circular cross-section of the carbon fiber to boron nitride, the boron nitride having a thickness of about 10 nanometers to 1.5 microns.

2. The method of claim 1 , wherein the boron oxide and the carbon fiber are heated to about 1000° C. to 2000° C.

3. The method of claim 1 , wherein the boron oxide and the carbon fiber are heated to about 1500° C. to 2000° C.

4. The method of claim 1 , wherein the carbon fiber is heated to a higher temperature than the boron oxide.

5. The method of claim 1 , wherein operations (b), (c), and (d) occur over a time period of about 30 minutes to 120 minutes.

6. The method of claim 1 , wherein the nitrogen-containing gas includes nitrogen.

7. The method of claim 1 , wherein the nitrogen-containing gas includes nitrogen, and wherein a ratio of a partial pressure of boron oxide to a partial pressure of nitrogen is about 1 to 2 during operation (d).

8. The method of claim 1 , wherein a pressure is about 1 bar during operation (d).

9. The method of claim 1 , wherein the carbon fiber is in a form comprising a woven cloth including the carbon fiber.

10. The method of claim 1 , wherein the boron oxide and the carbon fiber are separated from one another during operations (b), (c), and (d).

11. A structure

comprising: a carbon fiber core; and

a boron nitride layer surrounding the carbon fiber core, the boron nitride layer having the same surface morphology as the carbon fiber core, the boron nitride layer having a thickness of about 10 nanometers to 1.5 microns.

12. The structure of claim 11 , wherein the boron nitride layer is not coated onto the carbon fiber core.

13. The structure of claim 11 , wherein the carbon fiber core has a diameter of about 5 microns to 20 microns.

14. The structure of claim 11 , wherein the boron nitride layer has a uniform thickness.

15. The structure of claim 11 , wherein the structure has a color selected from a group consisting of red, green, blue, and variations thereof.

16. The structure of claim 11 , wherein the structure has a color other than black.

17. A

structure comprising: a

carbon fiber core; and

a boron nitride layer surrounding the carbon fiber core, the structure having a color selected from a group consisting of red, green, blue, and variations thereof, the color being determined by a thickness of the boron nitride layer.

18. The structure of claim 17 , wherein the boron nitride layer causes constructive interference of visible light between an outer surface of the boron nitride layer and a surface the carbon fiber core.

19. The structure of claim 17 , wherein the boron nitride layer has a thickness of about 10 nanometers to 1.5 microns.

20. The structure of claim 17 , wherein the carbon fiber core has a diameter of about 5 microns to 20 microns.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 11, 2014
From: ROUSSEAS, MICHAEL; MICKELSON, WILLIAM E.; ZETTL, ALEXANDER K.
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 032196/0615 →
CONFIRMATORY LICENSE Recorded Feb 5, 2014
From: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 032167/0102 →
Continuity (2)
Provisional Application 61751641 · Jan 11, 2013
Related Publication 20140197366A1 · Jul 17, 2014