Composite electrode material
View Patent ↗A composite electrode material consisting of a carbon coated complex oxide, fibrous carbon and a binder. Said material is prepared by a method which includes co-grinding an active electrode material and fibrous carbon, and adding a binder to the co-grinded mixture to lower the viscosity of the mixture. The fibrous carbon is preferably vapor grown carbon fibers.
1. An electrode comprising a composite electrode material on a current collector, said composite electrode material consisting of carbon coated oxide nanoparticles, fibrous carbon and a binder, wherein:
the fibrous carbon comprises vapor grown carbon fibers, each of which comprises fiber filaments, said filaments having a diameter of 5 to 500 nm and an aspect ratio (length/diameter) of 20 to 10000;
the carbon coating on the oxide nanoparticles is obtained by pyrolysis of a carbonaceous material and the fibrous carbon is bonded to the carbon coating via carbon-carbon chemical bonding;
the composite material consists of 0.5-5 wt % vapor grown carbon fibers, 70-95 wt % oxide nanoparticles and 1-25 wt % polymer binder, the total being 100%.
2. The electrode according to claim 1 , wherein the oxide nanoparticles are selected from the group consisting of sulfate, phosphate, silicate, oxysulfate, oxyphosphate or oxysilicate of a transition metal and lithium, and a mixture thereof.
3. The electrode according to claim 1 , wherein the oxide nanoparticles are selected from the group consisting of LiFePO 4 , LiMnPO 4 , LiFeSiO 4 , SiO, and SiO 2 .
4. The electrode according to claim 1 , wherein the binder is selected from the group consisting of PVDF, PTFE, styrene butadiene rubber SBR, and natural rubber.