Process for increasing the hydrophilicity of silicon surfaces following HF treatment
View Patent ↗A method for performing an oxide removal process is described. The method includes providing a substrate having an oxide layer, and preparing a patterned mask layer on the oxide layer, wherein the patterned mask layer has a pattern exposing at least a portion of the oxide layer. An HF treatment of the substrate is performed to transfer the pattern at least partially through the oxide layer, wherein the HF treatment exposes a silicon surface. Following the performing of the HF treatment, a surface property of the silicon surface is modified, wherein the modifying includes administering at least one oxidizing agent to contact the silicon surface to cause chemical oxidation of the silicon surface. And, following the modifying of the surface property, at least a portion of the patterned mask layer or a residual portion of the patterned mask layer is removed.
1. A method for performing an oxide removal process, comprising:
providing a substrate having an oxide layer;
preparing a patterned mask layer on said oxide layer, said patterned mask layer comprising a pattern exposing at least a portion of said oxide layer;
performing an HF treatment of said substrate to transfer said pattern at least partially through said oxide layer, said HF treatment exposing a silicon surface;
following said performing said HF treatment, modifying a surface property of said silicon surface, said modifying including administering at least one oxidizing agent to contact said silicon surface to cause chemical oxidation of said silicon surface; and
following said modifying said surface property, removing at least a portion of said patterned mask layer or a residual portion of said patterned mask layer.
2. The method of claim 1 , wherein said oxide layer comprises a thermally grown silicon dioxide layer.
3. The method of claim 1 , wherein said oxidizing agent comprises a peroxide.
4. The method of claim 1 , wherein said oxidizing agent comprises hydrogen peroxide.
5. The method of claim 4 , wherein said oxidizing agent further comprises an aqueous base.
6. The method of claim 5 , wherein said aqueous base comprises aqueous ammonium hydroxide, or tetramethylammonium hydroxide (TMAH), or a combination thereof.
7. The method of claim 1 , further comprising: introducing a basic solution to said oxidizing agent.
8. The method of claim 1 , wherein said preparing step comprises lithographically forming a patterned photoresist layer.
9. The method of claim 1 , wherein said HF treatment comprises exposing said masked substrate to a dilute HF solution (dHF), or a buffered HF solution (BHF).
10. The method of claim 1 , wherein said removing step includes exposing said substrate to a mixture containing sulfuric acid and hydrogen peroxide.
11. The method of claim 1 , further comprising: following said removing said patterned mask layer, performing a cleaning process.
12. The method of claim 11 , wherein said cleaning process comprises exposing said substrate to an aqueous solution comprising ammonium hydroxide and hydrogen peroxide.
13. The method of claim 1 , wherein said performing said HF treatment, said modifying said surface property, and said removing said patterned mask layer are performed sequentially in a wet chemical processing system.
14. The method of claim 1 , wherein said removing step includes exposing said substrate to a mixture containing sulfuric acid and hydrogen peroxide in the presence of water vapor.
15. The method of claim 14 , wherein said mixture containing sulfuric acid and hydrogen peroxide is dispensed from a first array of injection openings located above said substrate, and said water vapor is dispensed from a second array of openings.
16. The method of claim 15 , wherein said first array of openings and said second array of openings are oriented relative to one another to allow said mixture of sulfuric acid and hydrogen peroxide and said water vapor to mix in a space above said substrate.
17. The method of claim 15 , wherein said first array of openings and said second array of openings are distributed radially along a spray aim that extends above said substrate from approximately a central region of said substrate to approximately a peripheral region of said substrate.
18. The method of claim 17 , wherein said substrate is rotated while dispensing said mixture of sulfuric acid and hydrogen peroxide and said water vapor.
19. The method of claim 1 , further comprising:
thermally growing said oxide layer to a first gate oxide thickness for a first gate structure in a multi-gate device; and
performing said HF treatment to reduce the thickness of said oxide layer on at least a portion of said substrate to a second gate oxide thickness for a second gate structure in said multi-gate device.
20. The method of claim 1 , wherein the oxidizing agent is administered in a composition comprising NH 4 OH/H 2 O 2 /H 2 O in a ratio of about 1:50:200 by volume.