Dual-cure dental resins and adhesives with increased cure and color-stability and low color
Various embodiments of the present invention generally relate to a light-cure and dual-cure resin that have low color and is color stable over conventional light, self and dual-cured resins. Additionally, the light-cure resin has enhanced degree of cure over conventional light-cure resins. Finally, due to the low color and enhanced color stability of the dual-cure resins, their inherent property of having lower shrinkage stress as compared to light-cure resins can now be utilized in various dental applications and other resin applications.
1. A method for forming a low color and color stable hardenable composition, said method comprising:
providing a light-curable component comprising:
an onium compound,
a photosensitizer,
an amine co-initiator having strong proton-donating capacity,
and a resin monomer comprising a free radically active functional group and having no cationically active functional group, wherein said light-curable component is not miscible in water;
providing a self-curable component comprising a reducing agent and an oxidizing agent, wherein the reducing agent is selected from the group consisting of a urea reducing agent and a thiourea reducing agent,
exposing said light-curable component and said self-curable component to a source of electromagnetic radiation, and
curing the light curable component and the self curable component to form a hardenable composition, wherein the hardenable composition is formed by free radical polymerization, and wherein the hardenable composition has an initial b* color value of less than 20 and a ΔE of less than 10, wherein ΔE represents the color change of the composition upon curing and is calculated using the equation ΔE=[(ΔL*) 2 +(Δa*) 2 +(Δb*) 2 ] 1/2 , and L* represents the lightness variable of the composition's color and a* and b* represent the chromatic characteristics of the composition's color in the CIE color system.
2. The method of claim 1 , wherein the light-curable component and the self curable component are exposed to the source of electromagnetic radiation for a period of time ranging from 5 seconds to 30 seconds.
3. The method of claim 1 , further comprising the step of measuring the degree of conversion of the resin monomer to a polymer.
4. The method of claim 1 , further comprising the step of applying the hardenable composition on a tooth of a subject.
5. The method of claim 4 , further comprising applying a primer layer on said tooth prior to applying said hardenable composition.