IP Library Granted Patent US 8,853,867
Granted Patent B2
US 8,853,867 · App. 14/170,067 · Granted Oct 7, 2014

Encapsulant for a semiconductor device

Inventors: Sheila F. Chopin (Round Rock, TX); Varughese Mathew (Austin, TX); Leo M. Higgins, III (Austin, TX); Chu-Chung Lee (Round Rock, TX)
Assignee: Freescale Semiconductor, Inc.
H01L23/295H01L23/48H01L23/28
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,853,867
App. No.
14/170,067
Granted
Oct 7, 2014
Kind
B2
Abstract

A mold compound is provided for encapsulating a semiconductor device ( 101 ). The mold compound comprises at least approximately 70% by weight silica fillers, at least approximately 10% by weight epoxy resin system, and beneficial ions that are beneficial with respect to copper ball bond corrosion. A total level of the beneficial ions in the mold compound is at least approximately 100 ppm.

Claims (48)

1. A mold compound for encapsulating an electronic device, the mold compound comprising:

silica fillers;

epoxy resin system; and

beneficial ions that are beneficial with respect to copper ball bond corrosion,

wherein a total level of the beneficial ions in the mold compound is at least approximately 500 ppm, and

the beneficial ions are ions selected from the group consisting of formate (HCOO) − , acetate (CH 3 CO 2 ) − , and nitrite (NO 2 ) − .

2. The mold compound of claim 1 , wherein the total level of the beneficial ions in the mold compound is less than or equal to approximately 2000 ppm.

3. The mold compound of claim 1 , wherein the total level of the beneficial ions in the mold compound is over 600 ppm.

4. The mold compound of claim 3 , wherein the total level of the beneficial ions in the mold compound is less than or equal to approximately 2000 ppm.

5. The mold compound of claim 1 , wherein the beneficial ions are a combination of formate (HCOO) − and acetate (CH 3 CO 2 ) − ions.

6. The mold compound of claim 5 , wherein the total level of the beneficial ions in the mold compound is less than or equal to approximately 2000 ppm.

7. The mold compound of claim 1 , wherein the beneficial ions are nitrite (NO 2 ) − ions.

8. The mold compound of claim 1 ,

wherein a pH level of the mold compound is 6.0-8.0,

a level of chloride ions in the mold compound is less than or equal to 5 ppm, and

an operating voltage level of the electronic device is less than or equal to 65V.

9. The mold compound of claim 1 , wherein at least one of:

a moisture absorption level of the mold compound is less than 0.3% by weight,

an oxalate ion level of the mold compound is less than or equal to 50 ppm, and

a magnesium ion level of the mold compound is at least 200 ppm.

10. A semiconductor device package comprising:

an electronic device that includes an aluminum bond pad;

a copper wire bonded to the aluminum bond pad; and

an encapsulant, the electronic device and the copper wire being encapsulated by the encapsulant,

wherein the encapsulant comprises:

epoxy resin system, and

beneficial ions that are beneficial with respect to copper ball bond corrosion, a total level of the beneficial ions in the encapsulant being less than or equal to approximately 2000 ppm.

11. The semiconductor device package of claim 10 , wherein the total level of the beneficial ions in the encapsulant is at least approximately 500 ppm.

12. The semiconductor device package of claim 10 , wherein the beneficial ions are ions selected from the group consisting of formate, acetate, carbonate, and nitrite.

13. The semiconductor device package of claim 12 , wherein the total level of the beneficial ions in the encapsulant is at least approximately 500 ppm.

14. The semiconductor device package of claim 12 , wherein the beneficial ions are a combination of formate (HCOO) − and acetate (CH 3 CO 2 ) − ions.

15. The semiconductor device package of claim 12 , wherein the beneficial ions are nitrite (NO 2 ) − ions.

16. A mold compound for encapsulating an electronic device, the mold compound comprising:

silica fillers;

epoxy resin system; and

beneficial ions that are beneficial with respect to copper ball bond corrosion,

wherein a total level of the beneficial ions in the mold compound is at least approximately 200 ppm, and

the beneficial ions are ions selected from the group consisting of phosphate (PO 4 ) 3− and nitrite (NO 2 ) − .

17. The mold compound of claim 16 , wherein the total level of phosphate (PO 4 ) 3− ions in the mold compound is at least approximately 200 ppm.

18. The mold compound of claim 16 , wherein the total level of nitrite (NO 2 ) − ions in the mold compound is at least approximately 200 ppm.

19. The mold compound of claim 16 ,

wherein a pH level of the mold compound is 6.0-8.0,

a level of chloride ions in the mold compound is less than or equal to 5 ppm, and

an operating voltage level of the electronic device is less than or equal to 65V.

20. The mold compound of claim 16 , wherein at least one of:

a moisture absorption level of the mold compound is less than 0.3% by weight,

an oxalate ion level of the mold compound is less than or equal to 50 ppm, and

a magnesium ion level of the mold compound is at least 200 ppm.

Assignments (26)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE PREVIOUSLY RECORDED AT REEL: 040632 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Sep 21, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 044209/0047 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 040632/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT APPLICATION NUMBERS 12222918, 14185362, 14147598, 14185868 & 14196276 PREVIOUSLY RECORDED AT REEL: 037458 FRAME: 0479. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded May 12, 2016
From: CITIBANK, NA
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038665/0498 →
CORRECTIVE ASSIGNMENT TO CORRECT THE APPLICATION NUMBERS PREVIOUSLY RECORDED AT REEL: 037458 FRAME: 0438. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded May 12, 2016
From: CITIBANK, NA
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038665/0136 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 7, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037458/0438 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 7, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037458/0479 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0763 →
SUPPLEMENT TO SECURITY AGREEMENT Recorded May 7, 2014
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 032845/0442 →
SUPPLEMENT TO SECURITY AGREEMENT Recorded May 7, 2014
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 032845/0522 →
SUPPLEMENT TO SECURITY AGREEMENT Recorded May 7, 2014
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 032845/0497 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 31, 2014
From: CHOPIN, SHEILA F.; MATHEW, VARUGHESE; HIGGINS, LEO M., III; LEE, CHU-CHUNG
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 032109/0193 →
Continuity (2)
Continuation 13651995 · Oct 15, 2010
Related Publication 20140145339A1 · May 29, 2014