Electrically conductive structural adhesive
View Patent ↗The present invention relates to curable compositions which are capable of safely and sufficiently bonding components of electrical devices. In particular, the invention relates to electrically conductive, curable compositions, which are capable of rapidly curing at room temperatures as well as at elevated temperatures.
1. A two-part curable composition comprising:
a. A first part comprising:
i. at least one (meth)acrylate monomer;
ii. an electrically conductive component wherein said electrically conductive component comprises synthetic graphite having a surface area of about 20 m 2 /g to about 24 m 2 /g, present in an amount of about 10% to about 15% by weight of said first part;
iii. an acid catalyst;
iv. a free radical initiator; and
v. a free radical stabilizer; and
b. A second part comprising:
vi. at least one (meth)acrylate monomer;
vii. a catalyst; and
viii. a stabilizer for stabilizing said catalyst;
wherein said first part and said second part are combined together to form a curable composition.
2. The composition of claim 1 , wherein said at least one (meth)acrylate monomer comprises at least one monomer selected from the group consisting of methyl methacrylate, butyl methacrylate, isobornyl acrylate, dibutylene dimethacrylate, tri-propanol trimethacrylate, and combinations thereof.
3. The composition of claim 1 , wherein at least one of said first part or said second part includes a halogen-free elastomer.
4. The composition of claim 3 , wherein said halogen-free elastomer comprises a block copolymer selected from the group consisting of a polystyrene-isoprene-styrene block copolymer, a styrene-butadiene-styrene block copolymer, and combinations thereof.
5. The composition of claim 1 , wherein said acid catalyst comprises at least one organic acid.
6. The composition of claim 1 , wherein said acid catalyst comprises a composition selected from the group consisting of peroxide, acrylic acid, methacrylic acid, saccharin, and combinations thereof.
7. The composition of claim 1 , wherein said free radical initiator comprises at least one component selected from the group consisting of T-butyl peroxide, T-butyl perbenzoate, cyclohexanone peroxide, and combinations thereof.
8. The composition of claim 1 , wherein said free radical stabilizer comprises at least one component selected from the group consisting of hydroquinones, butylated hydroxytoluene, and phosphonates.
9. The composition of claim 1 , wherein said catalyst comprises at least one component selected from the group consisting of amine catalysts, metal catalysts, and combinations thereof.
10. The composition of claim 9 , wherein said catalyst comprises a copper catalyst.
11. A method of preparing a two-part curable composition, comprising the steps of:
a. Providing a first set of components comprising:
i. at least one (meth)acrylate monomer;
ii. an electrically conductive component wherein said electrically conductive component comprises synthetic graphite having a surface area of about 20 m 2 /g to about 24 m 2 /g, present in an amount of about 10% to about 15% by weight of said first part;
iii. an acid catalyst;
iv. a free radical initiator; and
v. a free radical stabilizer;
b. Mixing said first set of components to form a first part;
c. Providing a second set of components comprising:
i. at least one (meth)acrylate monomer;
ii. a metal catalyst; and
iii. a stabilizer for said metal catalyst; and
d. Mixing said second set of components to form a second part; wherein said first part and said second part are capable of being combined together to form a curable composition.
12. A method of adhering components of an electronic device, comprising the steps of:
a. Providing a first part comprising:
i. at least one (meth)acrylate monomer;
ii. an electrically conductive component wherein said electrically conductive component comprises synthetic graphite having a surface area of about 20 m 2 /g to about 24 m 2 /g, present in an amount of about 10% to about 15% by weight of said first part;
iii. an acid catalyst;
iv. a free radical initiator; and
v. a free radical stabilizer;
b. Providing a second part comprising:
i. at least one (meth)acrylate monomer;
ii. a metal catalyst; and
iii. butylaldehyde.aniline; and
c. Mixing said first part and said second part to form a curable composition; and
d. Applying said curable composition to at least one surface of a component of an electrical device and allowing said curable composition to cure.