Production of battery grade materials via an oxalate method

1. An active electrode material comprising:

a lithium transition metal oxide prepared by calcining a mixture of a lithium precursor and a transition metal oxalate;

wherein:

the lithium transition metal oxide comprises a compound of formula Li x [M 1 α M 2 β M 3 γ ]O z ;

the transition metal oxalate comprises a compound of formula [M 1 α′ M 2 β′ M 3 γ′ ]C 2 O 4 ;

M 1 , M 2 , and M 3 are different and are selected from the group consisting of Ni, Co, Mn, Fe, Cr, V, Ti, Cu, Zn, Mo, W, Zr, Nb, and Ru; and

0<x≦2; 0<α≦1; 0<β≦1; 0<γ≦1; and 0<z≦3; and

0<α′≦1; 0<β′≦1; and 0<γ′≦1.

2. The active electrode material of claim 1 , wherein M 1 is Ni, Fe, Cu, Zn, Mg, Ca, Sr, or Ba; M 2 is Co, Cr, V, Y, La, Ce or Al; and M 3 is Mn, Ti, Zr, Nb, Mo, or Ru.

3. The active electrode material of claim 1 , wherein M 1 is Ni; M 2 is Co; and M 3 is Mn.

4. The active electrode material claim 1 , wherein 1<x≦2; 0<α≦0.33; 0<β≦0.5; 0<γ≦0.8; and 2<z≦3; and the sum of α, β, and γ is 1.

5. The active electrode material of claim 1 , wherein the lithium transition metal oxide exhibits a capacity of greater than 200 mAh/g when used as a positive electrode in a Li coin cell.

6. The active electrode material of claim 1 , wherein the lithium precursor comprises lithium carbonate, lithium hydroxide, lithium nitrate, lithium acetate, lithium oxalate, lithium hydride, lithium oxide, lithium peroxide, lithium sulfate, or lithium fluoride.

7. The active electrode material of claim 1 , wherein M 1 is Ni; M 2 is Co; and M 3 is Mn.

8. The active electrode material of claim 1 , wherein 0<α′≦0.33; 0<β′≦0.5; and 0<γ′≦0.8; the sum of α′, β′, and γ′ is 1, and the sum of α, β, and γ is 1.

9. The active electrode material of claim 1 , wherein the calcining is conducted at a temperature of from about 400° C. to about 1200° C.

10. The active electrode material of claim 1 , wherein the lithium transition metal oxide exhibits a capacity of greater than 200 mAh/g in a Li coin cell.

11. The active electrode material of claim 1 , wherein

1<x≦2; 0<α≦0.33; 0<γ≦0.8; and 2<z≦3; and

the sum of α, and γ is 1; and 0<α′≦0.33; and 0<γ′≦0.8; and the sum of α′, and γ′ is 1.

12. The active electrode material of claim 11 , wherein the lithium precursor comprises lithium carbonate, lithium hydroxide, lithium nitrate, lithium acetate, lithium oxalate, lithium hydride, lithium oxide, lithium peroxide, lithium sulfate, or lithium fluoride.

13. An electrode comprising the active electrode material of claim 1 .

14. An electrochemical device comprising the electrode of claim 13 .