Anion transport membrane
An anion transport membrane is provided enabling efficient anion exchange across the membrane, which could be used in applications like fuel cells, water electrolyzers, or water filtration systems. The structural membrane morphology is based on a hydrophobic polysulfone membrane backbone and co-grafted thereon hydrophilic poly(ethylene glycol) grafts and anion conducting quaternary ammonium species. This structure defines a bi-continuous morphology with locally phase-separated hydrophobic-hydrophilic domains, and a co-localization of the anion conducting quaternary ammonium species with respect to the hydrophilic poly(ethylene glycol) grafts enabling efficient and continuous ion transport channels for facilitating anion transport.
1. An anion transport membrane, comprising:
a hydrophobic polysulfone membrane backbone with co-grafted thereon hydrophilic poly(ethylene glycol) grafts and anion conducting quaternary ammonium species, wherein the membrane has a top surface and a bottom surface, and wherein the membrane comprises:
(i) a bi-continuous morphology with locally phase-separated hydrophobic-hydrophilic domains, and
(ii) a co-localization of the anion conducting quaternary ammonium species with respect to the hydrophilic poly(ethylene glycol) grafts, therewith having defined ion transport channels for facilitating anion transport, wherein the ion transport channels are continuous hydrophilic water-attracting ion transport channels across the membrane and between the top and bottom surfaces of the membrane, and wherein the ion transport channels have a diameter of from 3 to 30 nm defined by a width of the hydrophilic region separating hydrophobic regions.
2. The anion transport membrane as set forth in claim 1 , wherein the anion is hydroxide, chloride, bromide, carbonate, or bicarbonate.
3. The anion transport membrane as set forth in claim 1 , wherein the hydrophilic poly(ethylene glycol) grafts each have a molecular weight ranging from 350 to 5000 Da.
4. The anion transport membrane as set forth in claim 1 , wherein the anion transport membrane is part of an anion exchange membrane fuel cell, a water electrolyzer, or a water filtration system.