Method for producing anode for lithium secondary battery and anode composition, and lithium secondary battery
View Patent ↗The invention relates to an anode for lithium secondary battery comprising vapor grown carbon fiber uniformly dispersed without forming an agglomerate of 10 μm or larger in an anode active material using natural graphite or artificial graphite, which anode is excellent in long cycle life and large current characteristics. Composition used for production for the anode can be produced, for example, by mixing a thickening agent solution containing an anode active material, a thickening agent aqueous solution and styrene butadiene rubber as binder with a composition containing carbon fiber dispersed in a thickening agent with a predetermined viscosity or by mixing an anode active material with vapor grown carbon fiber in dry state and then adding polyvinylidene difluoride thereto.
1. A method for producing an anode composition for lithium secondary battery, comprising mixing an anode active material which uses natural graphite or artificial graphite having d(002) of 0.335 to 0.337 nm in the graphite structure as measured by powder X-ray diffraction method and can absorb, store and discharge lithium and vapor grown carbon fiber having a hollow structure inside, having a structure consisting of graphene sheets laminated vertically against the fiber axis and having d(002) of 0.336 to 0.345 nm in the graphite structure as measured by powder X-ray diffraction method in a dry state and then adding thereto polyvinylidene difluoride, followed by mixing while stirring, wherein the polyvinylidene difluoride is in liquid state dissolved in N-methyl-2-pyrrolidone.