IP Library › Granted Patent US 9,269,775
Granted Patent B2
US 9,269,775 · App. 14/188,862 · Granted Feb 23, 2016

Tunneling devices and methods of manufacturing the same

Inventors: Jun-hee Choi (Seongnam-si, KR); Won-jong Yoo (Suwon-si, KR); Seung-hwan Lee (Suwon-si, KR); Min-sup Choi (Suwon-si, KR); Xiao Chi Liu (Suwon-si, KR); Ji-a Lee (Suwon-si, KR)
Assignees: SAMSUNG ELECTRONICS CO., LTD.; SUNGKYUNKWAN UNIVERSITY FOUNDATION FOR CORPORATE COLLABORATION
H01L29/1606H01L29/6603H01L29/7311H01L29/7376H01L29/88
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Quick Facts
Patent No.
US 9,269,775
App. No.
14/188,862
Granted
Feb 23, 2016
Kind
B2
Abstract

A tunneling device may include a tunnel barrier layer, a first material layer including a first conductivity type two-dimensional material on a first surface of the tunnel barrier layer and a second material layer including a second conductivity type two-dimensional material on a second surface of the tunnel barrier layer. The tunneling device may use a tunneling current through the tunnel barrier layer between the first material layer and the second material layer.

Claims (65)

1. A tunneling device comprising:

a tunnel barrier layer;

a first material layer on a first surface of the tunnel barrier layer, the first material layer including a P-type two-dimensional (2D) material; and

a second material layer on a second surface of the tunnel barrier layer, the second material layer including an N-type 2D material,

wherein the tunneling device uses a tunneling current through the tunnel barrier layer between the first material layer and the second material layer, and

wherein the first material layer has a work function of about 5.0 eV to about 5.9 eV, and the second material layer has a work function of about 3.2 eV to about 4.0 eV.

2. The tunneling device of claim 1 , wherein

the P-type 2D material comprises graphene doped with a P-type dopant, and

the N-type 2D material comprises graphene doped with an N-type dopant.

3. The tunneling device of claim 1 , wherein the tunnel barrier layer comprises a 2D material.

4. The tunneling device of claim 3 , wherein the tunnel barrier layer comprises one of hexagonal boron nitride (h-BN), MoS 2 , MoSe 2 , MoTe 2 , WS 2 , WSe 2 , WTe 2 , GaS, and GaSe.

5. The tunneling device of claim 3 , wherein the tunnel barrier layer comprises a transition metal dichalcogenide (TMDC) material.

6. The tunneling device of claim 1 , wherein the tunneling device has rectification characteristics.

7. The tunneling device of claim 1 , wherein the tunneling device has a two-terminal structure.

8. The tunneling device of claim 1 , further comprising:

a first electrode contacting the first material layer; and

a second electrode contacting the second material layer.

9. The tunneling device of claim 1 , further comprising one of:

(i) a substrate including the first material layer on a surface thereof, wherein the tunnel barrier layer is on a first region of the first material layer and extends over a region of the substrate adjacent to the first region of the first material layer, and the second material layer is on a first region of the tunnel barrier layer,

a first electrode on a second region of the first material layer and extends over a second region of the tunnel barrier layer adjacent to the second region of the first material layer, and

a second electrode on the second material layer; and

(ii) a substrate including the second material layer on a surface thereof, wherein the tunnel barrier layer is on a first region of the second material layer and extends over a region of the substrate adjacent to the first region of the second material layer, and the first material layer is on a first region of the tunnel barrier layer,

a first electrode on a second region of the second material layer and extends over a second region of the tunnel barrier layer adjacent to the second region of the second material layer; and

a second electrode on the first material layer.

10. A tunneling device comprising:

a tunnel barrier layer;

a first material layer on a first surface of the tunnel barrier layer, the first material layer including a P-type two-dimensional (2D) material; and

a second material layer on a second surface of the tunnel barrier layer, the second material layer including an N-type 2D material,

wherein the tunneling device uses a tunneling current through the tunnel barrier layer between the first material layer and the second material layer,

the P-type 2D material comprises a P-type transition metal dichalcogenide (TMDC) material, and

the N-type 2D material comprises an N-type transition metal dichalcogenide (TMDC) material.

11. A tunneling device comprising:

a tunnel barrier layer;

a first material layer on a first surface of the tunnel barrier layer, the first material layer including a P-type two-dimensional (2D) material; and

a second material layer on a second surface of the tunnel barrier layer, the second material layer including an N-type 2D material,

wherein the tunneling device uses a tunneling current through the tunnel barrier layer between the first material layer and the second material layer,

the P-type 2D material comprises one of WSe 2 , NbSe 2 , and GaSe, and

the N-type 2D material comprises one of MoS 2 , MoSe 2 , MoTe 2 , WS 2 , WSe 2 , WTe 2 , and GaS.

12. The tunneling device of claim 11 , wherein the tunnel barrier layer comprises one of h-BN and an oxide having a bandgap of more than about 1.0 eV.

13. A method of manufacturing a tunneling device, comprising:

forming a first material layer on a substrate, the first material layer including a first conductivity type two-dimensional (2D) material;

forming a tunnel barrier layer on the first material layer; and

forming a second material layer on the tunnel barrier layer, the second material layer including a second conductivity type 2D material,

wherein the forming a first material layer forms the first material layer to have a work function of about 5.0 eV to about 5.9 eV, and

the forming a second material layer forms the second material layer to have a work function of about 3.2 eV to about 4.0 eV.

14. The method of claim 13 , wherein the forming a first material layer comprises:

forming a first graphene layer on the substrate; and

doping the first graphene layer with a first conductivity type dopant by a chemical doping process.

15. The method of claim 14 , wherein

the doping dopes the first graphene layer with a P-type dopant,

the P-type dopant has at least one of AuCl 3 and diazonium salt as a source.

16. The method of claim 13 , wherein the forming a second material layer comprises:

forming a second graphene layer on the tunnel barrier layer; and

doping the second graphene layer with a second conductivity type dopant by a chemical doping process.

17. The method of claim 16 , wherein

the doping dopes the second graphene layer with an N-type dopant,

the N-type dopant has at least one of benzyl-viologen (BV) and polyethylenimine (PEI) as a source.

18. The method of claim 13 , wherein the forming a tunnel barrier layer forms a 2D material.

19. The method of claim 18 , wherein the forming a tunnel barrier layer forms one of hexagonal boron nitride (h-BN), MoS 2 , MoSe 2 , MoTe 2 , WS 2 , WSe 2 , WTe 2 , GaS, and GaSe.

20. The method of claim 13 , wherein

the forming a first material layer forms one of WSe 2 , NbSe 2 , and GaSe, and

the forming a second material layer forms one of MoS 2 , MoSe 2 , MoTe 2 , WS 2 , WSe 2 , WTe 2 , and GaS.

21. The method of claim 13 , further comprising:

forming a first electrode contacting the first material layer; and

forming a second electrode contacting the second material layer.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2014
From: CHOI, JUN-HEE
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 032293/0048 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2014
From: YOO, WON-JONG; LEE, SEUNG-HWAN; CHOI, MIN-SUP; LIU, XIAO CHI; LEE, JI-A
To: SUNGKYUNKWAN UNIVERSITY FOUNDATION FOR CORPORATE COLLABORATION
Reel/Frame 032293/0184 →
Priority Claims (1)
KR 10-2013-0083154 · Jul 15, 2013 · national
Continuity (1)
Related Publication 20150014630A1 · Jan 15, 2015