Sizing compositions for glass fibers and sized fiber glass products
Various embodiments of the present invention provide sizing compositions, fiber glass strands, cement boards, and other products incorporating fiber glass. In some embodiments, a sizing composition of the present invention comprises a starch, a nonionic lubricant, a silane comprising at least one amine and at least one aryl or arylene group, and an aminofunctional oligomeric siloxane.
1. A sizing composition for glass fibers, comprising:
a starch in an amount up to about 45 percent by weight on a total solids basis, wherein the starch comprises from about 10 to about 30 percent amylose based on starch weight;
a nonionic lubricant;
a silane comprising at least one secondary or tertiary amine and at least one aryl or arylene group; and
an aminofunctional oligomeric siloxane in an amount of from about 2 to about 12 percent by weight of the sizing composition on a total solids basis, wherein the aminofunctional oligomeric siloxane comprises at least one alkyl group bonded to a first silicon atom and at least one amine bonded to a second silicon atom;
wherein the ratio of silane to siloxane is from 0.4:1 to 7:1.
2. The sizing composition of claim 1 , wherein the silane comprises at least 5 percent by weight of the sizing composition on a total solids basis.
3. The sizing composition of claim 2 , wherein the siloxane comprises at least 10 percent by weight of the sizing composition on a total solids basis.
4. The sizing composition of claim 1 , wherein the siloxane comprises from about 4 to about 10 percent by weight of the sizing composition on a total solids basis.
5. The sizing composition of claim 1 , wherein the siloxane comprises from about 4 and about 12 percent by weight of the sizing composition on a total solids basis.
6. The sizing composition of claim 1 , wherein the silane comprising at least one secondary or tertiary amine and at least one aryl or arylene group comprises a silane comprising at least one amine and at least one benzyl group.
7. The sizing composition of claim 6 , wherein the at least one benzyl group comprises at least one benzylamino group or at least one vinylbenzylamino group.
8. The sizing composition of claim 7 , wherein the silane further comprises a second amine.
9. The sizing composition of claim 1 , wherein the silane comprising at least one secondary or tertiary amine and at least one aryl or arylene group comprises a silane comprising at least one amine and at least one phenyl group.
10. The sizing composition of claim 9 , wherein the at least one phenyl group comprises at least one phenylamino group.
11. The sizing composition of claim 1 , wherein the silane comprises at least one secondary or tertiary amine and at least one arylene group and wherein the silane further comprises terminal unsaturation.
12. The sizing composition of claim 11 , wherein the at least one arylene group comprises a vinylbenzylamino group.
13. The sizing composition of claim 12 , wherein the silane further comprises a second amine.
14. The sizing composition of claim 1 , wherein the silane comprises two or more secondary amines.
15. The sizing composition of claim 1 , wherein the nonionic lubricant comprises wax.
16. The sizing composition of claim 15 , further comprising a second nonionic lubricant and wherein the second nonionic lubricant comprises oil.
17. The sizing composition of claim 1 , wherein the nonionic lubricant comprises oil.
18. A fiber glass strand comprising a plurality of glass fibers at least partially coated with the sizing composition of claim 1 .
19. A forming package comprising at least one fiber glass strand of claim 18 .
20. A cement board comprising at least one fiber glass according to claim 18 .
21. A sizing composition for glass fibers, comprising:
a starch in an amount up to about 45 percent by weight on a total solids basis, wherein the starch comprises from about 10 to about 30 percent amylose based on starch weight;
a nonionic lubricant;
a silane comprising at least one secondary or tertiary amine and at least one aryl or arylene group in an amount up to about 14 percent by weight of the sizing composition on a total solids basis; and
an aminofunctional oligomeric siloxane in an amount of from about 2 to about 12 percent by weight of the sizing composition on a total solids basis, wherein the aminofunctional oligomeric siloxane comprises at least one alkyl group bonded to a first silicon atom and at least one amine bonded to a second silicon atom;
wherein the ratio of silane to siloxane is from 0.4:1 to 7:1.
22. A sizing composition for glass fibers, comprising:
a starch in an amount up to about 45 percent by weight on a total solids basis, wherein the starch comprises from about 10 to about 30 percent amylose based on starch weight;
a nonionic lubricant;
a silane comprising at least one secondary or tertiary amine and at least one aryl or arylene group in an amount from about 2 to about 14 percent by weight of the sizing composition on a total solids basis; and
an aminofunctional oligomeric siloxane in an amount from about 5 to about 12 percent by weight of the sizing composition on a total solids basis, wherein the aminofunctional oligomeric siloxane comprises at least one alkyl group bonded to a first silicon atom and at least one amine bonded to a second silicon atom,
wherein the ratio of silane to siloxane is from 0.4:1 to 7:1.