Recyclable organic solar cells on substrates comprising cellulose nanocrystals (CNC)
Recyclable organic solar cells are disclosed herein. Systems and methods are further disclosed for producing, improving performance, and for recycling the solar cells. In certain example embodiments, the recyclable organic solar cells disclosed herein include: a first electrode; a second electrode; a photoactive layer disposed between the first electrode and the second electrode; an interlayer comprising a Lewis basic oligomer or polymer disposed between the photoactive layer and at least a portion of the first electrode or the second electrode; and a substrate disposed adjacent to the first electrode or the second electrode. The interlayer reduces the work function associated with the first or second electrode. In certain example embodiments, the substrate comprises cellulose nanocrystals that can be recycled. In certain example embodiments, one or more of the first electrode, the photoactive layer, and the second electrode may be applied by a film transfer lamination method.
1. A recyclable organic solar cell comprising:
a first electrode;
a second electrode;
a photoactive layer disposed between the first electrode and the second electrode;
an interlayer comprising a Lewis basic oligomer or polymer disposed between the photoactive layer and at least a portion of the first electrode or the second electrode; and
a substrate comprising cellulose nanocrystals disposed adjacent to the first electrode or the second electrode;
wherein one or more of the first electrode, the second electrode, the photoactive layer, the interlayer, and the substrate of the organic solar cell comprise recyclable material.
2. The recyclable organic solar cell of claim 1 , wherein the interlayer comprises polyethylenimine (PEI) and wherein the interlayer reduces the work function associated with the first or second electrode.
3. The recyclable organic solar cell of claim 1 , wherein the first electrode comprises one or more of an organic material, a polymer, a metal, a transparent conductive metal-oxide, graphene, metal nanorods, metal particles, metal oxide particles, carbon nanotubes, or a mixture thereof.
4. The recyclable organic solar cell of claim 1 , wherein the second electrode comprises one or more of an organic material, a polymer, a metal, a transparent conductive metal-oxide, graphene, metal nanorods, metal particles, metal oxide particles, carbon nanotubes, or a mixture thereof.
5. The recyclable organic solar cell of claim 1 , wherein the second electrode comprises a conducting polymer comprising poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS).
6. The recyclable organic solar cell of claim 1 , wherein the photoactive layer comprises poly(3-hexylthiophene):Indene-C 60 Bis-Adduct (P3HT:ICBA).
7. The recyclable organic solar cell of claim 1 , wherein the substrate is water-soluble.
8. The recyclable organic solar cell of claim 1 , wherein interlayer reduces the work function associated with the first electrode or the second electrode by greater than 0.5 eV.
9. A recyclable organic solar cell module comprising:
a plurality of solar cell elements, each solar cell element including:
a first electrode;
a second electrode;
a photoactive layer disposed between the first electrode and the second electrode;
an interlayer comprising a Lewis basic oligomer or polymer disposed between the photoactive layer and at least a portion of the first electrode or the second electrode; and
a substrate comprising cellulose nanocrystals disposed adjacent to the first electrode or the second electrode;
each solar cell element having an associated polarity based at least in part on an arrangement and orientation of the interlayer.
10. The recyclable organic solar cell module of claim 9 , wherein the first electrodes of adjacent solar cell elements x(N) and x(N+1) are connected in a first plane, and wherein the second electrodes of adjacent solar cell elements x(N+1) and x(N+2) are connected in a second plane, wherein x and N are integers.
11. The recyclable organic solar cell module of claim 9 , wherein the interlayer comprises polyethylenimine (PEI) and wherein the interlayer reduces the work function associated with the first or second electrode.
12. The recyclable organic solar cell module of claim 9 , wherein the first electrode comprises one or more of an organic material, a polymer, a metal, a transparent conductive metal-oxide, graphene, metal nanorods, metal particles, metal oxide particles, carbon nanotubes, or a mixture thereof.
13. The recyclable organic solar cell module of claim 9 , wherein the second electrode comprises one or more of an organic material, a polymer, a metal, a transparent conductive metal-oxide, graphene, metal nanorods, metal particles, metal oxide particles, carbon nanotubes, or a mixture thereof.
14. The recyclable organic solar cell module of claim 9 , wherein the second electrode comprises a conducting polymer comprising poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS).
15. The recyclable organic solar cell module of claim 9 , wherein the photoactive layer comprises poly(3-hexylthiophene) Indene-C 60 Bis-Adduct (P3HT:ICBA).
16. The recyclable organic solar cell module of claim 9 , wherein the substrate is water-soluble.
17. The recyclable organic solar cell module of claim 9 , wherein interlayer reduces the work function associated with the first electrode or the second electrode by greater than 0.5 eV.