IP Library › Patent Application 14237170
Patent Application
App. No. 14/237,170

RENEWABLE BIO-BASED (METH) ACRYLATED MONOMERS AS VINYL ESTER CROSS-LINKERS

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Quick Facts
Patent No.
US None
App. No.
14/237,170
Abstract

Anhydrosugar-based monomers prepared from isosorbide, isomannide, and isoidide and resin systems containing these anhydrosugar-based monomers that are partially to fully bio-based, which may produce materials having properties that meet or exceed the properties of similar petroleum derived vinyl ester resins.

Claims (23)

1 . A polymerizable monomer selected from the group consisting of:

2 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

3 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

4 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

5 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

6 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

7 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

8 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

9 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

10 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

11 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

12 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

13 . A polymerizable monomer as claimed in claim 1 , wherein the monomer is:

14 . A method of making a polymer comprising the step of curing a composition comprising at least one monomer selected from the group consisting of the monomers of claim 1 .

15 . The method of claim 14 , wherein the curing is carried out by free-radical curing.

16 . The method of claim 14 , wherein the composition further comprises from 1 to 99% by weight of at least one reactive diluent.

17 . The method of claim 16 , wherein the reactive diluent is selected from the group consisting of: styrene, 2-hydroxymethacrylate, methyl methacrylate, methyl acrylate, furfuryl methacrylate, methacyrlated lauric acid methacrylated fatty acids.

18 . The method of claim 14 , wherein the composition further comprises from 1 to 99% by weight of at least one cross-linking agent.

19 . The method of claim 18 , wherein the crosslinker is selected from the group consisting of: unsaturated polyester, vinyl ester and the structures in claim 1 .

20 . The method of claim 27 , wherein said composition comprises 50-95% by weight of said at least one monomer and 5-50% by weight of said reactive diluent.

21 . A polymer obtained by the process of claim 14 .

22 . A method of making a polymer comprising the step of curing a composition comprising at least one anhydrosugar-based monomer selected from the group consisting of the monomers of claim 1 and at least one vinyl ester resin monomer or unsaturated polyester monomer.

23 - 30 . (canceled)