IP Library Granted Patent US 9,502,150
Granted Patent B2
US 9,502,150 · App. 14/241,658 · Granted Nov 22, 2016

Graphene oxide polymer with nonlinear resistivity

Inventors: Zepu Wang (Albany, NY); Linda S. Schadler (Niskayuna, NY); Henrik Hillborg (Vasteras, SE); Su Zhao (Vasteras, SE)
Assignees: Rensselaer Polytechnic Institute; ABB AB
H01B1/125B82Y30/00B82Y40/00C01B31/043C01B31/0476H01B1/04H01B1/124H01B3/004
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Quick Facts
Patent No.
US 9,502,150
App. No.
14/241,658
Granted
Nov 22, 2016
Kind
B2
Abstract

The invention relates generally to field grading materials and, more particularly, to field grading materials including graphene oxide, reduced graphene oxide, or both, exhibiting non-linear resistivity. In one embodiment, the invention provides a composite material comprising: a polymer material; and reduced graphene oxide distributed within the polymer material.

Claims (16)

1. A method of reducing electric field stress at a joint or termination of an electric cable, the method comprising:

applying to the joint or termination a field grading material, the field grading material comprising reduced graphene oxide, distributed within a polymer material.

2. The method of claim 1 , wherein the field grading material exhibits non-linear resistivity.

3. The method of claim 1 , wherein the field grading material includes thermally-reduced graphene oxide reduced at a temperature between about 70° C. and about 160° C.

4. The method of claim 1 , wherein the polymer material includes at least one polymer material selected from a group consisting of: natural rubbers, silicone, poly(dimethyl siloxane), ethylene propylene diene rubber, ethylene propylene rubber, epoxy, polyester, polyesterimide, and polyamidimide.

5. A method of preparing a graphene oxide polymer material, the method comprising:

thermally reducing a quantity of graphene oxide by increasing an ambient temperature of an atmosphere containing the quantity of graphene oxide to between about 70° C. and about 160° C.;

admixing the thermally-reduced quantity of graphene oxide with at least one polymer material; and

curing the admixture.

6. The method of claim 5 , wherein the thermally-reduced graphene oxide is admixed with the at least one polymer material at a concentration between about 2 parts and about 5 parts per hundred parts of the at least one polymer material.

7. The method of claim 5 , wherein the at least one polymer material is selected from a group consisting of: natural rubbers, silicone, such as poly(dimethyl siloxane), EPDM rubber (ethylene propylene diene rubber), EPR (ethylene propylene rubber), epoxy, polyester, polyesterimide, and PAI (polyamidimide).

8. A graphene oxide polymer material prepared according to the method of claim 5 .

9. A field grading material exhibiting non-linear resistivity comprising a quantity of reduced graphene oxide distributed within at least one polymer material.

10. The field grading material of claim 9 , wherein the at least one polymer material is selected from a group consisting of: natural rubbers, silicone, poly(dimethyl siloxane), ethylene propylene diene rubber, ethylene propylene rubber, epoxy, polyester, polyesterimide, and polyamidmide.

11. The field grading material of claim 9 , wherein the reduced graphene oxide has a concentration greater than about 2 parts per hundred parts of polymer.

12. The field grading material of claim 11 , wherein the reduced graphene oxide has a concentration between about 3 parts and about 5 parts per hundred parts of polymer.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME TO ABB POWER GRIDS SWEDEN AB AND THE ASSIGNEE ADDRESS TO KOPPARBERGSVAGEN 2, VASTERAS, SWEDEN 721 83 PREVIOUSLY RECORDED AT REEL: 055598 FRAME: 0866. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded May 10, 2021
From: ABB AB
To: ABB POWER GRIDS SWEDEN AB
Reel/Frame 056185/0519 →
CHANGE OF NAME Recorded Mar 15, 2021
From: ABB AB
To: ABB POWER GRIDS SWITZERLAND AG
Reel/Frame 055598/0866 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2014
From: HILLBORG, HENRIK; ZHAO, SU
To: ABB AB
Reel/Frame 033185/0818 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2014
From: SCHADLER, LINDA S.; WANG, ZEPU
To: RENSSELAER POLYTECHNIC INSTITUTE
Reel/Frame 033185/0888 →
Continuity (3)
Provisional Application 61573209 · Sep 1, 2011
Provisional Application 61546636 · Oct 13, 2011
Related Publication 20150001448A1 · Jan 1, 2015