Method to Improve Charge Trap Flash Memory Top Oxide Quality
A semiconductor processing method to provide a high quality top oxide layer in charged-trapping NAND and NOR flash memory. The top oxide layer of NAND and NOR flash memory determines array device performance and reliability. The method described overcomes the corner thinning issue and the poor top oxide quality that results from the traditional oxidation approach of using pre-deposited silicon-rich nitride.
1 . A method comprising:
disposing a first region comprising a plurality of trench isolation regions on a substrate,
wherein each trench isolation region includes mesas having sidewalls and tops;
disposing a tunneling dielectric layer on the first region;
disposing a charge trapping layer over the tunneling dielectric layer;
disposing a first sacrificial layer over the charge trapping layer;
first selective removing the first sacrificial layer and the charge trapping layer from the tops of the mesas to thereby result in wings in the charge trapping layer adjacent to the mesas;
recessing the wings down to a level commensurate with a remainder of the charge trapping layer;
removing the first sacrificial layer;
disposing a standard silicon-nitride (SiN) layer over the charge trapping layer and exposed mesas;
oxidizing portions of the standard SiN layer to form a blocking dielectric layer on the charge trapping layer; and
disposing a gate region on the blocking dielectric layer.
2 . The method of claim 1 , further comprising prior to the oxidizing:
disposing a second sacrificial layer over the standard SiN layer;
second selective removing the second sacrificial layer and the standard SiN layer to result in a flat structure; and
removing remaining portions of the second sacrificial layer.
3 . The method of claim 1 , wherein the tunneling dielectric layer comprises silicon dioxide.
4 . The method of claim 1 , wherein the charge trapping layer comprises silicon-rich nitride (SiRN).
5 . The method of claim 4 , wherein the SiRN has an extinction coefficient in the range of approximately 0.9 through 1.19.
6 . The method of claim 1 , wherein the blocking dielectric layer comprises silicon oxide.
7 . The method of claim 1 , wherein the first sacrificial layer comprises a high temperature oxide layer.
8 . The method of claim 1 , wherein the first selective removing includes using dry etching.
9 . The method of claim 1 , wherein the recessing includes using wet etching.
10 . The method of claim 1 , wherein the removing the first sacrificial layer includes using wet etching.
11 . A charge trapping flash memory device, comprising:
a semiconductor substrate comprising a plurality of trench isolation regions, wherein each trench isolation region includes mesas having sidewalls and tops;
a tunneling dielectric layer having a lower surface, wherein the tunneling dielectric layer is formed on the upper surface of the substrate;
a charge trapping layer over the tunneling dielectric layer, wherein the charge trapping layer comprises one or more wings adjacent to the mesas;
a blocking dielectric layer formed over the charge trapping layer; and
a gate formed on the blocking dielectric layer.
12 . The charge trapping flash memory device of claim 11 , wherein the tunneling dielectric layer comprises silicon dioxide.
13 . The charge trapping flash memory device of claim 11 , wherein the charge trapping layer comprises silicon-rich nitride (SiRN).
14 . The charge trapping flash memory device of claim 13 , wherein the SiRN has an extinction coefficient in the range of approximately 0.9 through 1.19.
15 . The charge trapping flash memory device of claim 11 , wherein the blocking dielectric layer comprises silicon oxide.
16 . The charge trapping flash memory device of claim 11 , wherein the gate comprises polysilicon.
17 . A charge trapping flash memory apparatus, comprising:
an array of semiconductor device cells, wherein each semiconductor device cell comprises:
a semiconductor substrate comprising a plurality of trench isolation regions, wherein each trench isolation region includes mesas having sidewalls and tops;
a tunneling dielectric layer having a lower surface, wherein the tunneling dielectric layer is formed on the upper surface of the substrate;
a charge trapping layer over the tunneling dielectric layer, wherein the charge trapping layer comprises one or more wings adjacent to the mesas;
a blocking dielectric layer formed over the charge trapping layer; and
a gate formed on the blocking dielectric layer.
18 . The charge trapping flash memory apparatus of claim 17 , wherein the tunneling dielectric layer comprises silicon dioxide.
19 . The charge trapping flash memory apparatus of claim 17 , wherein the charge trapping layer comprises silicon-rich nitride (SiRN).
20 . The charge trapping flash memory apparatus of claim 19 , wherein the SiRN has an extinction coefficient in the range of approximately 0.9 through 1.19.
21 . The charge trapping flash memory apparatus of claim 17 , wherein the blocking dielectric layer comprises silicon oxide.
22 . The charge trapping flash memory device of claim 17 , wherein the gate comprises polysilicon.