Controllably degradable thermoplastic polyurethane and overgrips made therefrom
Controllably degradable overgrips are provided, as well as methods of producing controllably degradable thermoplastic polyurethane. Methods comprise pre-blending a catalyst on a matrix, dispersing a specified amount of the pre-blended catalyst throughout solid granular thermoplastic polyurethane to yield a polymer component, and determining an onset timing of hydrolytic breakdown of the polymer component by adjusting the specified amount of dispersed catalyst. The thermoplastic polyurethane may be produced by reacting low molecular weight aliphatic diol(s) with aliphatic dicarboxylic acid(s) to produce polyester, and reacting the polyester with organic di-isocyanate(s) and diol chain extender(s) using catalytic amounts of alkali or alkaline earth metal salt(s) of C 10 to C 45 aliphatic carboxylic acid(s). Tackifying resins may be added to adjust an adhesive profile of the overgrips.
1. A method for making a polymer component comprising:
pre-blending a catalyst with an inert, process compatible matrix;
dispersing the pre-blended catalyst on the matrix throughout solid granular thermoplastic polyurethane to yield a polymer component; and
adjusting an onset timing of environmental hydrolytic breakdown of the polymer component by adjusting an amount of the catalyst dispersed throughout the solid granular thermoplastic polyurethane.
2. The method of claim 1 , further comprising producing the solid granular thermoplastic polyurethane by:
reacting low molecular weight aliphatic diols with aliphatic dicarboxylic acid to produce a polyester, the aliphatic diols having a molecular weight in a range of 500 to 3000, and yielding an equivalent weight of 250 to 1500 and a free hydroxyl number of 37 to 224 of the polyester;
reacting the resulting polyester with at least one organic di-isocyanate and at least one diol chain extender using catalytic amounts of at least one alkali or alkaline earth metal salt of at least one C 10 to C 45 aliphatic carboxylic acid to achieve a specified solution viscosity figure, being between 1100-1400 centipoises at 25° C. for a 30% solution of the polymer in dimethyl formamide (DMF), to produce thermoplastic polyurethane; and
solidifying and granulating the produced thermoplastic polyurethane and dispersing catalyst throughout the produced solid granular thermoplastic polyurethane.
3. The method of claim 2 , wherein the low molecular weight aliphatic diols comprise ethylene glycol and 1,4-butane diol at molar ratios between 0.7-1.3:0.7-1.3.
4. The method of claim 2 , wherein the aliphatic dicarboxylic acid is between C 4 -C 10 .
5. The method of claim 2 , wherein the aliphatic dicarboxylic acid comprises adipic acid.
6. The method of claim 2 , wherein the at least one diol chain extender is 1,4-butane diol.
7. The method of claim 1 , wherein the matrix is a talc matrix and the catalyst is dibutyl tin dilaurate.
8. The method of claim 1 , wherein the onset timing of the environmental hydrolytic breakdown of the polymer component is one year.
9. The method of claim 1 , further comprising adding tackifying resin to the polymer component.
10. The method of claim 9 , wherein the tackifying resin is an aromatic hydrocarbon resin having a softening point between 70-120° C. and added within a range of 5-15% from total solids of the thermoplastic polyurethane.
11. The method of claim 9 , further comprising controlling an adhesive profile of an overgrip comprising the polymer component by adjusting resin type and amount within the solid granular thermoplastic polyurethane according to a viscosity of a thermoplastic polyurethane solution which is solidified and granulated to yield the solid granular thermoplastic polyurethane.
12. The method of claim 1 , further comprising using the polymer component in an overgrip.
13. The method of claim 2 , further comprising adjusting at least one of: the molecular weight range of the low molecular weight aliphatic diols and the specified solution viscosity figure, with respect to required dimensions and mechanical and chemical properties related to a use of the overgrip.