Hydrogen chloride removal process
A hydrogen chloride removal process includes (i) contacting in a reactor an aqueous solution, which includes one or more Fe 2+ -compounds, with a fluid, which includes an oxidizing agent, hydrochloric acid gas and optionally chlorine gas; and (ii) oxidizing the Fe 2+ -compounds to Fe 3+ -compounds, thereby converting the fluid to an exhaust gas, which has a reduced hydrochloric acid content.
1. A hydrogen chloride removal process, the process comprising:
contacting in a reactor an aqueous solution comprising one or more Fe 2+ -compounds with a reactor feed gas comprising an oxidizing agent, hydrochloric acid gas and optionally chlorine gas; and
oxidizing said Fe 2+ -compounds to Fe 3+ -compounds,
at a temperature lower than 100° C., thereby converting said reactor feed gas comprising an oxidizing agent, hydrochloric acid gas and optionally chlorine gas to an exhaust gas comprising a reduced hydrochloric acid content.
2. The hydrogen chloride removal process according to claim 1 , whereby said hydrochloric acid gas is comprised in said reactor feed gas in an amount of at most 80 vol. %.
3. The hydrogen chloride removal process according to claim 2 wherein the hydrochloric acid gas is comprised in an amount of at most 60 vol. %.
4. The hydrogen chloride removal process according to claim 1 , whereby an oxidizing agent is contacted with an aqueous solution comprising one or more Fe 2+ -compounds.
5. The hydrogen chloride removal process according to claim 1 , whereby said aqueous solution comprising one or more Fe 2+ -compounds comprises non-iron metals in an amount of less than 5.0 wt. % relative to the total metal content.
6. The hydrogen chloride removal process according to claim 5 , wherein the amount of the non-iron metals is less than 2.0 wt. % relative to the total metal content.
7. The hydrogen chloride removal process according to claim 1 , whereby said one or more Fe 2+ -compounds are provided in a stoichiometric excess relative to the amount of hydrochloric acid in said fluid.
8. The hydrogen chloride removal process according to claim 2 , whereby said reactor feed gas comprises nitrogen gas in an amount of at least 5 vol. % relative to the total amount of reactor feed gas.
9. The hydrogen chloride removal process according to claim 8 , wherein the amount of the nitrogen gas is at least 25 vol. % relative to the total amount of reactor feed gas.
10. The hydrogen chloride removal process according to claim 2 , whereby said reactor feed gas comprises air and hydrochloric acid.
11. The hydrogen gas chloride removal process according to claim 10 , wherein said reactor feed gas consists of air and hydrochloric acid.
12. The hydrogen chloride removal process according to claim 2 , whereby said reactor feed gas comprises at least 5 vol. % nitrogen gas and at least 5 vol. % oxygen gas.
13. The hydrogen chloride removal process according to claim 1 , whereby the total concentration of one or more iron compounds in said aqueous solution is sufficiently low to prevent crystallization.
14. The hydrogen chloride removal process according to claim 1 , whereby said Fe 2+ -compounds comprise ferrous chloride and whereby said Fe 3+ -compounds comprise ferric chloride.
15. The hydrogen chloride removal process according to claim 1 , whereby said aqueous solution comprising one or more Fe 2+ -compounds is a waste pickle liquor or an aqueous solution obtained by dissolving iron containing materials in an acid.
16. The hydrogen chloride removal process according to claim 15 , wherein the acid comprises hydrochloric acid.
17. The hydrogen chloride removal process according to claim 15 , wherein said aqueous solution comprises one or more Fe 2+ -compounds in an aqueous solution comprising 5 to 40% wt. of ferrous chloride.
18. The hydrogen chloride removal process according to claim 15 , wherein said reactor feed gas comprises 0.1 to 2.5 vol. % of hydrochloric acid.
19. The hydrogen chloride removal process according to claim 1 , at a temperature lower than 75° C.
20. The hydrogen chloride removal process according to claim 1 , at a temperature between 0 and 50° C.
21. The hydrogen chloride removal process according to claim 1 , further comprising the step of evacuating from said reactor an exhaust gas comprising less than 10 vol. % of hydrochloric acid.