Continuous Fe(III) production at atmospheric pressures
A method oxidizes ferrous iron to ferric iron. The method includes providing a liquid, which includes the ferrous iron, and a gas, which includes an oxidizing agent, such as oxygen and/or chlorine; providing two separate mixes, with both mixes including the gas and the liquid; and colliding the separate mixes, thereby obtaining the ferric iron.
1. A method for oxidizing ferrous iron to ferric iron, the method comprising:
providing a liquid comprising said ferrous iron and a gas comprising an oxidizing agent;
providing at least two separate mixes, at least a first mix and at least a second mix, wherein each of the first mix and the second mix comprises the liquid and the gas; and
colliding said separate mixes thereby obtaining the ferric iron.
2. The method according to claim 1 , wherein the oxidizing agent comprises oxygen and/or chlorine.
3. The method according to claim 1 , whereby said liquid and/or said gas further comprises a neutralizing agent.
4. The method according to claim 3 , wherein the neutralizing agent comprises chloride or sulphate in acid form.
5. The method according to claim 1 , whereby said oxidizing agent comprises gaseous oxygen O 2 , pure gaseous oxygen O 2 , gaseous chlorine Cl 2 , pure gaseous chlorine Cl 2 , air, air with gaseous Cl 2 and whereby said liquid or said gas comprises hydrochloric acid.
6. The method according to claim 1 , whereby said liquid comprises ferrous chloride or ferrous sulphate and whereby the ferrous iron is oxychlorinated to ferric chloride or ferric chloro-sulphate by reaction with said oxidizing agent and/or neutralizing agent, or whereby said liquid comprises ferrous sulfate and whereby the ferrous iron is oxidized to ferric sulfate by reaction with said oxidizing agent and/or neutralizing agent.
7. The method according to claim 1 , comprising at least one of the following: pickling metal or alloy with hydrochloric acid, thereby obtaining waste pickling liquor (WPL), said WPL comprising ferrous iron; providing said WPL as liquid for further processing according to a method for oxidizing ferrous iron to ferric iron according to claim 1 ; and adding an aqueous solution of hydrochloric acid to said liquid before said liquid is mixed with said gas.
8. The method according to claim 7 , wherein the metal or alloy comprises iron or steel.
9. The method according to claim 1 , whereby said liquid is obtained by adding an iron source to a liquid comprising hydrochloric acid.
10. The method according to claim 9 , wherein the iron source is selected from the group consisting of iron, scrap iron, iron oxide, ferrous oxide, magnetite, and hematite limonite.
11. The method according to claim 1 , whereby said method is performed in a continuous mode.
12. The method according to claim 1 , whereby the collided mixes are kept at a pressure and a temperature, whereby said temperature is kept between 75% and 95% of a boiling temperature of said mixes expressed in degrees centigrade and at said pressure.
13. The method according to claim 12 , wherein said pressure is higher than 80% of atmospheric pressure and lower than 10 bar.
14. The method according to claim 1 , wherein the first mix is produced in a first mixing system comprising an inlet connected to a supply of a liquid which comprises ferrous iron and an inlet connected to a supply of a gas comprising an oxidizing agent, said first mixing system arranged for mixing the gas with the liquid into a first mix, and said first mixing system comprising a first outlet for said first mix;
and the second mix is produced in at least a second mixing system comprising an inlet connected to a supply of a liquid which comprises ferrous iron and an inlet connected to a supply of a gas comprising an oxidizing agent, said second mixing system arranged for mixing the gas with the liquid into a second mix, and said second mixing system comprising a second outlet for said second mix;
whereby the first outlet and said second outlet are in fluid connection with an impact zone and the first and the second outlets are arranged in a facing relationship to each other;
whereby the impact zone is in fluid connection with a container for holding a reaction fluid comprising a reaction gas, a reaction liquid and/or a reaction gas-liquid mixture,
whereby the container comprises: a gas outlet for evacuating at least part of the reaction gas from the container, the gas outlet in fluid connection with at least one of said mixing systems for supplying the first and/or second mixing system with the gas comprising an oxidizing agent; and/or a liquid outlet for extracting the reaction liquid and/or a reaction gas-liquid mixture from the container, the liquid outlet in fluid connection with at least one of said mixing systems for supplying the first and/or second mixing system with the liquid comprising ferrous iron and/or with a gas-liquid mixture comprising ferrous iron.
15. The method according to claim 14 , wherein the oxidizing agent comprises oxygen and/or chlorine.
16. The method according to claim 14 , wherein the reaction gas comprises oxygen and/or chlorine.
17. The method according to claim 16 , wherein the reaction gas comprises O 2 , Cl 2 or HCl.
18. The method according to claim 14 , wherein the liquid and/or the gas comprises chloride or sulphate in acid form.
19. The method according to claim 14 , wherein the liquid and/or the gas comprises chloride or sulphate in acid form.
20. The method according to claim 14 , wherein said first mixing system, said second mixing system and/or said one or more mixing systems is an injection system.
21. The method according to claim 14 , wherein the method is carried out in a closed system.