Nanoparticle formulations of active ingredients
The present invention provides a composition including a polymer nanoparticle and at least one agricultural active compound incorporated with the nanoparticle, wherein the nanoparticle are less than 100 nm in diameter, and the polymer includes a polyelectrolyte.
1. A composition comprising a polymer nanoparticle and at least one organic, neutral, non-ionic agricultural compound associated with the polymer nanoparticle, wherein the polymer nanoparticle is less than 100 nm in diameter and cross-linked; wherein the polymer nanoparticle comprises a collapsed water-soluble polyelectrolyte; wherein the polymer has a molecular weight of at least about 100,000 Dalton prior to collapse and cross-linking; and wherein the at least one organic, neutral, non-ionic agricultural compound is selected from the group consisting of a pyrethroid, a neonicotinoid, and combinations thereof.
2. The composition of claim 1 , wherein the neonicotinoid is selected from the group consisting of imidacloprid, thiamethoxam, acetamiprid, and combinations thereof.
3. The composition of claim 2 , wherein the neonicotinoid is imidacloprid.
4. The composition of claim 1 , wherein the at least one organic, neutral, non-ionic agricultural compound comprises a combination of a pyrethroid and a neonicotinoid.
5. The composition of claim 4 , wherein the at least one organic, neutral, non-ionic agricultural compound comprises a combination of bifenthrin and imidacloprid.
6. A composition comprising a polymer nanoparticle and a combination of at least two organic, neutral, non-ionic agricultural compounds associated with the polymer nanoparticle, wherein the polymer nanoparticle is less than 100 nm in diameter and cross-linked; wherein the polymer nanoparticle comprises a collapsed water-soluble polyelectrolyte; wherein the polymer has a molecular weight of at least about 100,000 Dalton prior to collapse and cross-linking; and wherein the combination of at least two organic, neutral, non-ionic agricultural compounds comprises a combination of an insecticide and a fungicide.
7. The composition of claim 6 , wherein the fungicide is a quinone-outside inhibitor selected from the group consisting of azoxystrobin, pyraclostrobin, trifloxystrobin, fluoxastrobin and combinations thereof and the insecticide is a pyrethroid or a neonicotinoid selected from the group consisting of lambda-cyhalothrin, bifenthrin, imidacloprid, and combinations thereof.