Polyester resin for toner, method for producing same and toner
Disclosed is a toner which is excellent in low-temperature fixability, high-temperature offset resistance, storage stability and durability, while having a wide range of fixing temperature. Also disclosed is a polyester resin used for such a toner. The polyester resin is one of the following polyester resin (A)-(E) for toners. (A) A polyester resin for toners having an Mp as determined by GPC of not less than 12,000 and having an unsaturated double bond (B) A polyester resin for toners obtained by crosslinking the polyester resin (A) (C) A polyester resin for toners containing the polyester resin (A) and another polyester resin having an Mp as determined by GPC of less than 12,000 (D) A polyester resin for toners obtained by crosslinking the polyester resin (C) (E) A polyester resin for toners containing a THF soluble fraction and a THF insoluble fraction wherein the Mw/Mn of the THF soluble fraction is not less than 6 and the total of the acid value and the hydroxyl value of the THF insoluble fraction is not more than 40 mgKOH/g.
1. A process for production of a polyester resin for toner comprising blending and crosslinking amorphous polyester resin for toner (1) with a peak molecular weight of at least 12,000 in gel permeation chromatography and containing an unsaturated double bond, and amorphous polyester resin for toner (2) with a peak molecular weight of less than 12,000 in gel permeation chromatography, with the use of a radical reaction initiator.
2. The process according to claim 1 , wherein an upper limit for the peak molecular weight of amorphous polyester resin (2) is 11,000.
3. The process according to claim 1 , wherein an upper limit for the peak molecular weight of amorphous polyester resin (2) is 10,000.
4. The process according to claim 1 , wherein a lower limit for the peak molecular weight of amorphous polyester resin (2) is 2,000.
5. The process according to claim 1 , wherein Mw of amorphous polyester resin (2) is no greater than 12,000.
6. The process according to claim 1 , wherein a lower limit for the Mw of amorphous polyester resin (2) is 4,000.
7. The process according to claim 1 , wherein Mn of amorphous polyester resin (2) is no greater than 4,500.
8. The process according to claim 1 , wherein a lower limit for the Mn of amorphous polyester resin (2) is 1,000.
9. The process according to claim 1 , wherein a softening temperature of amorphous polyester resin (2) is 80-130° C.
10. The process according to claim 1 , wherein Tg of amorphous polyester resin (2) is 40-70° C.
11. The process according to claim 1 , wherein an acid value of amorphous polyester resin (2) is no greater than 50 mgKOH/g.
12. The process according to claim 1 , wherein amorphous polyester resin (2) comprises a constituent component derived from a C 30 or greater monovalent carboxylic acid compound and/or C 30 or greater monohydric alcohol compound.
13. The process according to claim 1 , wherein a difference in softening temperature between amorphous polyester resin (1) and amorphous polyester resin (2) is at least 20° C.
14. The process according to claim 1 , wherein said resin comprise a THF-insoluble fraction comprising a crosslinked fraction that is insoluble in THF and a THF-soluble fraction comprising a crosslinked fraction that is soluble in THF, unreacted amorphous polyester resin (1) and unreacted amorphous polyester resin (2).
15. The process according to claim 1 , wherein amorphous polyester resin (2) contains at least one unsaturated double bond.