NUCLEOPHILIC POROUS CARBON MATERIALS FOR REVERSIBLE CO2 CAPTURE
In some embodiments, the present disclosure pertains to methods of capturing CO 2 from an environment by associating the environment (e.g., a pressurized environment) with a porous carbon material that comprises a plurality of pores and a plurality of nucleophilic moieties. In some embodiments, the associating results in sorption of CO 2 to the porous carbon materials. In some embodiments, the sorption of CO 2 to the porous carbon materials occurs selectively over hydrocarbons in the environment. In some embodiments, the methods of the present disclosure also include a step of releasing captured CO 2 from porous carbon materials. In some embodiments, the releasing occurs without any heating steps by decreasing environmental pressure. In some embodiments, the methods of the present disclosure also include a step of disposing released CO 2 and reusing porous carbon materials. Additional embodiments of the present disclosure pertain to porous carbon materials that are used for CO 2 capture.
1 . A method of capturing CO 2 from an environment, wherein the method comprises:
associating the environment with a porous carbon material,
wherein the porous carbon material comprises a plurality of pores and a plurality of nucleophilic moieties, and
wherein the associating results in sorption of the CO 2 to the porous carbon material.
2 . The method of claim 1 , wherein the environment is selected from the group consisting of industrial gas streams, natural gas streams, natural gas wells, industrial gas wells, oil and gas fields, and combinations thereof.
3 . The method of claim 1 , wherein the environment is a pressurized environment.
4 . The method of claim 3 , wherein the environment has a total pressure higher than atmospheric pressure.
5 . The method of claim 3 , wherein the environment has a total pressure of about 5 bar to about 500 bar.
6 . The method of claim 1 , wherein the associating occurs by placing the porous carbon material at or near the environment.
7 . The method of claim 1 , wherein the associating occurs by flowing the environment through a structure that contains the porous carbon materials.
8 . The method of claim 1 , wherein the sorption of the CO 2 to the porous carbon material occurs by at least one of absorption, adsorption, ionic interactions, physisorption, chemisorption, covalent bonding, non-covalent bonding, hydrogen bonding, van der Waals interactions, and combinations thereof.
9 . The method of claim 1 , wherein the sorption of the CO 2 to the porous carbon material occurs above atmospheric pressure.
10 . The method of claim 1 , wherein the sorption of the CO 2 to the porous carbon material occurs at total pressures ranging from about 5 bar to about500 bar.
11 . The method of claim 1 , wherein the sorption of the CO 2 to the porous carbon material occurs at a partial CO 2 pressure of about 0.1 bar to about 100 bar.
12 . The method of claim 1 , wherein the sorption of the CO 2 to the porous carbon material occurs without heating the porous carbon material.
13 . The method of claim 1 , wherein the sorption of the CO 2 to the porous carbon material occurs selectively over hydrocarbons in the environment.
14 . The method of claim 13 , wherein the molecular ratio of sorbed CO 2 to sorbed hydrocarbons in the porous carbon material is greater than about 2
15 . The method of claim 1 , wherein the CO 2 is converted to poly(CO 2 ) within the pores of the porous carbon materials
16 . The method of claim 1 , further comprising a step of releasing the captured CO 2 from the porous carbon material.
17 . The method of claim 16 , wherein the releasing occurs by decreasing the pressure of the environment.
18 . The method of claim 16 , wherein the releasing occurs by placing the porous carbon material in a second environment, wherein the second environment has a lower pressure than the environment where CO 2 capture occurred.
19 . The method of claim 16 , wherein the releasing occurs at or below atmospheric pressure.
20 . The method of claim 16 , wherein the releasing occurs at total pressures ranging from about 0 bar to about 100 bar.
21 . The method of claim 16 , wherein the releasing occurs at the same temperature at which CO 2 sorption occurred.
22 . The method of claim 16 , wherein the releasing occurs without heating the porous carbon material.
23 . The method of claim 16 , wherein the releasing occurs through depolymerization of formed poly(CO 2 ).
24 . The method of claim 16 , further comprising a step of disposing the released CO 2 .
25 . The method of claim 16 , further comprising a step of reusing the porous carbon material after the releasing step to capture additional CO 2 from an environment.
26 . The method of claim 1 , wherein the porous carbon material is selected from the group consisting of nucleophilic polymers, polypeptides, proteins, waste materials, nitrogen-containing porous carbon materials, sulfur-containing porous carbon materials, metal-containing porous carbon materials, metal-oxide containing porous carbon materials, metal sulfide-containing porous carbon materials, phosphorus containing porous carbon materials, and combinations thereof.
27 . The method of claim 1 , wherein the porous carbon material comprises a nucleophilic polymer.
28 . The method of claim 27 , wherein the nucleophilic polymer is selected from the group consisting of nitrogen-containing polymers, sulfur-containing polymers, polythiophene (PTH), polythiophene-methanol (2-(hydroxymethyl)thiophene), polyacrylonitrile (PAN), polypyrrole, and combinations thereof.
29 . The method of claim 27 , wherein the nucleophilic polymer is carbonized.
30 . The method of claim 27 , wherein the nucleophilic polymer is reduced.
31 . The method of claim 1 , wherein the nucleophilic moieties are part of the porous carbon material.
32 . The method of claim 1 , wherein the nucleophilic moieties are embedded within the plurality of the pores of the porous carbon material.
33 . The method of claim 1 , wherein the nucleophilic moieties are selected from the group consisting of primary nucleophiles, secondary nucleophiles, tertiary nucleophiles and combinations thereof.
34 . The method of claim 1 , wherein the nucleophilic moieties are selected from the group consisting of oxygen-containing moieties, sulfur-containing moieties, metal-containing moieties, metal oxide-containing moieties, metal sulfide-containing moieties, nitrogen-containing moieties, phosphorus-containing moieties, and combinations thereof.
35 . The method of claim 1 , wherein the nucleophilic moieties comprise nitrogen-containing moieties.
36 . The method of claim 35 , wherein the nitrogen-containing moieties are selected from the group consisting of primary amines, secondary amines, tertiary amines, nitrogen oxides, and combinations thereof.
37 . The method of claim 1 , wherein the nucleophilic moieties comprise sulfur-containing moieties.
38 . The method of claim 37 , wherein the sulfur-containing moieties are selected from the group consisting of primary sulfurs, secondary sulfurs, sulfur oxides, and combinations thereof.
39 . The method of claim 1 , wherein the porous carbon material has surface areas ranging from about 1,000 m 2 /g to about 3,000 m 2 /g.
40 . The method of claim 1 , wherein the plurality of pores in the porous carbon material comprise diameters ranging from about 5 nm to about 100 nm.
41 . The method of claim 1 , wherein the plurality of pores in the porous carbon material comprise volumes ranging from about 1 cm 3 /g to about 10 cm 3 /g.
42 . The method of claim 1 , wherein the porous carbon material has a density ranging from about 0.3 g/cm 3 to about 4 g/cm 3 .
43 . The method of claim 1 , wherein the porous carbon material has a CO 2 sorption capacity ranging from about 10% to about 200% of the porous carbon material weight.
44 . The method of claim 1 , wherein the porous carbon material has a CO 2 sorption capacity of about 55% to about 90% of the porous carbon material weight.
45 . A porous carbon material for CO 2 capture, wherein the porous carbon material comprises a plurality of pores and a plurality of nucleophilic moieties.
46 . The porous carbon material of claim 45 , wherein the porous carbon material is selected from the group consisting of nucleophilic polymers, polypeptides, proteins, waste materials, nitrogen-containing porous carbon materials, sulfur-containing porous carbon materials, metal-containing porous carbon materials, metal-oxide containing porous carbon materials, metal sulfide containing porous carbon materials, phosphorus containing porous materials, and combinations thereof.
47 . The porous carbon material of claim 45 , wherein the porous carbon material comprises a nucleophilic polymer.
48 . The porous carbon material of claim 47 , wherein the nucleophilic polymer is selected from the group consisting of nitrogen-containing polymers, sulfur-containing polymers, polythiophene (PTH), polythiophene-methanol (2-(hydroxymethyl)thiophene), polyacrylonitrile (PAN), polypyrrole, and combinations thereof.
49 . The porous carbon material of claim 48 , wherein the nucleophilic polymer is carbonized.
50 . The porous carbon material of claim 48 , wherein the nucleophilic polymer is reduced.
51 . The porous carbon material of claim 45 , wherein the nucleophilic moieties are part of the porous carbon material.
52 . The porous carbon material of claim 45 , wherein the nucleophilic moieties are embedded within the plurality of the pores of the porous carbon material.
53 . The porous carbon material of claim 45 , wherein the nucleophilic moieties are selected from the group consisting of primary nucleophiles, secondary nucleophiles, tertiary nucleophiles and combinations thereof.
54 . The porous carbon material of claim 45 , wherein the nucleophilic moieties are selected from the group consisting of oxygen-containing moieties, sulfur-containing moieties, metal-containing moieties, metal oxide-containing moieties, metal sulfide-containing moieties, phosphorus containing moieties, nitrogen-containing moieties, and combinations thereof.
55 . The porous carbon material of claim 45 , wherein the nucleophilic moieties comprise nitrogen-containing moieties.
56 . The porous carbon material of claim 45 , wherein the nitrogen-containing moieties are selected from the group consisting of primary amines, secondary amines, tertiary amines, nitrogen oxides, and combinations thereof.
57 . The porous carbon material of claim 45 , wherein the nucleophilic moieties comprise sulfur-containing moieties.
58 . The porous carbon material of claim 45 , wherein the sulfur-containing moieties are selected from the group consisting of primary sulfurs, secondary sulfurs, sulfur oxides, and combinations thereof.
59 . The porous carbon material of claim 45 , wherein the porous carbon material has surface areas ranging from about 1,000 m 2 /g to about 3,000 m 2 /g.
60 . The porous carbon material of claim 45 , wherein the plurality of pores in the porous carbon material comprise diameters ranging from about 5 nm to about 100 nm.
61 . The porous carbon material of claim 45 , wherein the plurality of pores in the porous carbon material comprise volumes ranging from about 1 cm 3 /g to about 10 cm 3 /g.
62 . The porous carbon material of claim 45 , wherein the porous carbon material has a density ranging from about 0.3 g/cm 3 to about 4 g/cm 3 .
63 . The porous carbon material of claim 45 , wherein the porous carbon material has a CO 2 sorption capacity ranging from about 10% to about 200% of the porous carbon material weight.
64 . The porous carbon material of claim 45 , wherein the porous carbon material has a CO 2 sorption capacity of about 55% to about 90% of the porous carbon material weight.