Packaging material and molded case
A packaging material 1 includes a heat resistant resin stretched film layer 2 as an outer layer, a thermoplastic resin layer 3 as an inner layer, a metal foil layer 4 arranged between these layers, and a colored ink layer 10 arranged between the metal foil layer 4 and the heat resistant resin stretched film layer 2 . As the heat resistant resin stretched film, a heat resistant resin stretched film having a hot water shrinkage rate of 2% to 20% is used, and the heat resistant resin stretched film layer 2 and the colored ink layer 4 are integrally laminated via an easily adhesive layer 30 . In this packaging material, at the time of forming and sealing, and even being used in a somewhat severe environment such as high-temperature and humid environment, the colored ink layer will not be detached from the heat resistant resin stretched film layer.
1. A battery case formed by deep drawing or bulging a packaging material, the battery case comprising:
a heat resistant resin stretched film layer as an outer layer;
a thermoplastic resin layer as an inner layer;
a metal foil layer arranged between the heat resistant resin stretched film layer and the thermoplastic resin layer;
a colored ink layer arranged between the metal foil layer and the heat resistant resin stretched film layer;
an easily adhesive layer located between the heat resistant resin stretched film layer and the colored ink layer; and
a first adhesive agent layer that integrally adheres the colored ink layer and the metal foil layer to each other,
wherein as the heat resistant resin stretched film, a heat resistant resin stretched film having a hot water shrinkage rate of 2% to 20% is used, and
wherein the heat resistant resin stretched film layer and the colored ink layer are integrally laminated to each other via the easily adhesive layer.
2. The battery case as recited in claim 1 , wherein the easily adhesive layer contains one or more kinds of resins selected from the group consisting of an epoxy resin, a urethane resin, an acrylic acid ester resin, a methacrylic acid ester resin, and a polyethylenimine resin.
3. The battery case as recited in claim 1 , wherein the easily adhesive layer contains a urethane resin and an epoxy resin.
4. The battery case as recited in claim 3 , wherein in the easily adhesive layer, a content mass ratio of the urethane resin/the epoxy resin is within a range of 98/2 to 40/60.
5. The battery case as recited in claim 1 , wherein the easily adhesive layer contains one or more kinds of acrylic resins selected from the group consisting of an acrylic acid ester resin and a methacrylic acid ester resin, and an epoxy resin.
6. The battery case as recited in claim 5 , wherein in the easily adhesive layer, a content mass ratio of the acrylic resin/the epoxy resin is within a range of 98/2 to 40/60.
7. The battery case as recited in claim 1 , wherein the easily adhesive layer is an adhesive layer formed by applying a resin-aqueous emulsion on the heat resistant resin stretched film layer.
8. The battery case as recited in claim 1 , wherein as the heat resistant resin stretched film, a biaxially stretched polyamide film having a hot water shrinkage rate of 2% to 20%, a biaxially stretched polyethylene naphthalate film having a hot water shrinkage rate of 2% to 20%, or a biaxially stretched polyethylene terephthalate film having a hot water shrinkage rate of 2% to 20% is used.
9. The battery case as recited in claim 1 , wherein the hot water shrinkage rate of the heat resistant resin stretched film is 2.5% to 10%.
10. The battery case as recited in claim 1 , wherein the colored ink layer is a black ink layer which contains carbon black, diamine, polyol, and a diisocyanate.
11. The battery case as recited in claim 10 , wherein in the black ink layer, a content rate of the carbon black is 15 mass % to 60 mass %, and a total content rate of the diamine, polyol, and the curing agent is 40 mass % to 85 mass %.
12. The battery case as recited in claim 1 , further comprising a matte coat layer laminated on an outer surface of the heat resistant resin stretched film layer.
13. The battery case as recited in claim 12 , wherein the matte coat layer is made of a resin composition containing a two-liquid curing type heat resistant resin and fine inorganic particles having an average particle size of 1 μm to 10 μm, and a content rate of the fine inorganic particles in the resin composition is 0.1 mass % to 60 mass %.
14. A battery case formed by deep drawing or bulging a packaging material, the battery case comprising:
a heat resistant resin stretched film layer as an outer layer;
a thermoplastic resin layer as an inner layer;
a metal foil layer arranged between the heat resistant resin stretched film layer and the thermoplastic resin layer;
a colored ink layer arranged between the metal foil layer and the heat resistant resin stretched film layer;
an easily adhesive layer located between the heat resistant resin stretched film layer and the colored ink layer; and
a first adhesive agent layer that integrally adheres the colored ink layer and the metal foil layer to each other,
wherein as the heat resistant resin stretched film, a heat resistant resin stretched film having a hot water shrinkage rate of 2% to 20% is used,
wherein the heat resistant resin stretched film layer and the colored ink layer are integrally laminated to each other via the easily adhesive layer,
wherein a matte coat layer is laminated on an outer surface of the heat resistant resin stretched film layer,
wherein the colored ink layer contains carbon black, a content rate of the carbon black in the colored ink layer is 20 mass % to 50 mass %, and a thickness of the colored ink layer is 1 μm to 4 μm,
wherein the easily adhesive layer contains one or more acrylic resins selected from the group consisting of an acrylic acid ester resin and a methacrylic acid ester resin, and an epoxy resin, and
wherein in the easily adhesive layer, a content mass ratio of the acrylic resin/the epoxy resin is within a range of 98/2 to 40/60.