Method for preparing a diorganodihalosilane
View Patent ↗A method of preparing a diorganodihalosilane, the method comprising the following separate and consecutive steps: (a) treating a metal catalyst comprising a metal selected from the groups consisting of i) gold, ii) gold and copper, iii) gold, copper and magnesium, iv) copper, rhodium and gold, v) copper, rhodium, and rhenium, vi) rhenium and palladium, vii) copper, and viii) copper and magnesium with a mixture comprising hydrogen gas and an organotrihalosilane at a temperature from 500 to 1400° C. to form a silicon-containing metal intermediate; and (b) reacting the silicon-containing metal intermediate with an organohalide according to the formula RX, wherein R is C 1 -C 10 hydrocarbyl and X is halo, at a temperature from 100 to 600° C. to form a diorganodihalosilane and a depleted silicon-containing metal intermediate.
1. A method of preparing a diorganodihalosilane, the method comprising the following separate and consecutive steps:
(a) treating a metal catalyst comprising a metal selected from the group consisting of i) gold, ii) gold and copper, iii) gold, copper and magnesium, iv) copper, rhodium and gold, v) copper, rhodium, and rhenium, vi) rhenium and palladium, vii) copper, and viii) copper and magnesium with a mixture comprising hydrogen gas and an organotrihalosilane at a temperature from 500 to 1400° C. to form a silicon-containing metal intermediate; and
(b) reacting the silicon-containing metal intermediate with an organohalide according to the formula RX, wherein R is C 1 -C 10 hydrocarbyl and X is halo, at a temperature from 100 to 600° C. to form a diorganodihalosilane and a depleted silicon-containing metal intermediate.
2. The method according to claim 1 , further comprising (c) contacting the depleted silicon-containing metal intermediate formed in step (b) with the hydrogen gas and the organotrihalosilane at a temperature of from 500 to 1400° C. to reform the silicon-containing metal intermediate comprising at least 0.1% (w/w) silicon; and (d) contacting the reformed silicon-containing metal intermediate with the organohalide at a temperature of from 100 to 600° C. to form a diorganodihalosilane.
3. The method according to claim 2 , further comprising repeating steps (c) and (d) at least 1 time.
4. The method according to claim 2 , further comprising purging prior to the contacting of the reformed silicon-containing metal intermediate with the organohalide in step (d).
5. The method according to claim 4 , wherein the purging is conducted with argon or organotrihalosilane.
6. The method according to any claim 1 , further comprising purging prior to contacting the silicon-containing metal intermediate with the organohalide in step (b).
7. The method according to claim 6 , wherein the purging is conducted with argon or organotrihalosilane.
8. The method according to claim 1 , wherein the metal catalyst further comprises a support.
9. The method according to claim 8 , wherein the metal catalyst comprises from 0.1 to 35% (w/w) of the metal and the metal comprises copper, gold and magnesium.
10. The method according to claim 8 , wherein the support is activated carbon.
11. The method according to claim 1 , wherein the silicon-containing metal intermediate comprises from 1 to 5% (w/w) of silicon.
12. The method according to claim 1 , wherein mole ratio of hydrogen to silicon tetrahalide in step (a) is from 20:1 to 5:1.
13. The method according to claim 1 , wherein the organohalide is methyl chloride, and the organotrihalosilane is CH 3 SiCl 3 .
14. The method according to claim 1 , further comprising recovering the diorganodihalosilane.
15. The method according to claim 1 , wherein the residence time of the hydrogen and organotrihalosilane is from 1 to 10 s in step (a) and the residence time of the organohalide is from 1 to 10 s in step (b).
16. The method according to claim 1 , wherein step (b) is at a pressure from 7 to 1000 kPag.
17. The method according to claim 1 , wherein step (a) is at a pressure from 7 to 1000 kPag.
18. The method according to claim 1 , wherein the diorganodihalosilane is dimethyldichlorosilane.
19. The method according to claim 1 , wherein the method further comprises the step of hydrolyzing the diorganodihalosilane to form a polyorganosiloxane.